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(515363, 18835, '5', 'CH', 57.9, 5, NULL, NULL),
(515364, 18835, '6', 'C', 211.4, 6, NULL, NULL),
(515365, 18835, '7', 'CH2', 41.6, 7, NULL, NULL),
(515366, 18835, '8', 'CH', 42.7, 8, NULL, NULL);
INSERT INTO `carbons` (`id`, `molecularId`, `numeration`, `carbonType`, `shift`, `num2`, `created_at`, `updated_at`) VALUES
(515367, 18835, '9', 'C', 21.8, 9, NULL, NULL),
(515368, 18835, '10', 'C', 30.1, 10, NULL, NULL),
(515369, 18835, '11', 'CH2', 26.7, 11, NULL, NULL),
(515370, 18835, '12', 'CH2', 33.2, 12, NULL, NULL),
(515371, 18835, '13', 'C', 45.9, 13, NULL, NULL),
(515372, 18835, '14', 'C', 47.8, 14, NULL, NULL),
(515373, 18835, '15', 'CH2', 46, 15, NULL, NULL),
(515374, 18835, '16', 'CH', 71.4, 16, NULL, NULL),
(515375, 18835, '17', 'CH', 56.6, 17, NULL, NULL),
(515376, 18835, '18', 'CH3', 15.7, 18, NULL, NULL),
(515377, 18835, '19', 'CH2', 22.7, 19, NULL, NULL),
(515378, 18835, '20', 'CH', 28.8, 20, NULL, NULL),
(515379, 18835, '21', 'CH3', 18.4, 21, NULL, NULL),
(515380, 18835, '22', 'CH2', 32.9, 22, NULL, NULL),
(515381, 18835, '23', 'CH2', 28, 23, NULL, NULL),
(515382, 18835, '24', 'CH', 77.3, 24, NULL, NULL),
(515383, 18835, '25', 'C', 72.5, 25, NULL, NULL),
(515384, 18835, '26', 'CH3', 25.7, 26, NULL, NULL),
(515385, 18835, '27', 'CH3', 26.4, 27, NULL, NULL),
(515386, 18835, '28', 'CH3', 27, 28, NULL, NULL),
(515387, 18835, '29', 'CH3', 19.1, 29, NULL, NULL),
(515388, 18835, '30', 'CH3', 15.4, 30, NULL, NULL),
(515389, 18835, '1''', 'CH', 106.9, 101, NULL, NULL),
(515390, 18835, '2''', 'CH', 75.8, 102, NULL, NULL),
(515391, 18835, '3''', 'CH', 78.7, 103, NULL, NULL),
(515392, 18835, '4''', 'CH', 71.8, 104, NULL, NULL),
(515393, 18835, '5''', 'CH', 78.3, 105, NULL, NULL),
(515394, 18835, '6''', 'CH2', 63.1, 106, NULL, NULL),
(515395, 18836, '1', 'CH2', 32, 1, NULL, NULL),
(515396, 18836, '2', 'CH2', 28.9, 2, NULL, NULL),
(515397, 18836, '3', 'CH', 77.7, 3, NULL, NULL),
(515398, 18836, '4', 'C', 41.4, 4, NULL, NULL),
(515399, 18836, '5', 'CH', 52, 5, NULL, NULL),
(515400, 18836, '6', 'CH', 79.4, 6, NULL, NULL),
(515401, 18836, '7', 'CH2', 34.4, 7, NULL, NULL),
(515402, 18836, '8', 'CH', 45.7, 8, NULL, NULL),
(515403, 18836, '9', 'C', 20.8, 9, NULL, NULL),
(515404, 18836, '10', 'C', 28.9, 10, NULL, NULL),
(515405, 18836, '11', 'CH2', 25.7, 11, NULL, NULL),
(515406, 18836, '12', 'CH2', 32.8, 12, NULL, NULL),
(515407, 18836, '13', 'C', 44.5, 13, NULL, NULL),
(515408, 18836, '14', 'C', 45.7, 14, NULL, NULL),
(515409, 18836, '15', 'CH2', 45.5, 15, NULL, NULL),
(515410, 18836, '16', 'CH', 72.9, 16, NULL, NULL),
(515411, 18836, '17', 'CH', 57.7, 17, NULL, NULL),
(515412, 18836, '18', 'CH3', 20.7, 18, NULL, NULL),
(515413, 18836, '19', 'CH2', 30.5, 19, NULL, NULL),
(515414, 18836, '20', 'C', 86.8, 20, NULL, NULL),
(515415, 18836, '21', 'CH3', 26.5, 21, NULL, NULL),
(515416, 18836, '22', 'CH2', 34.4, 22, NULL, NULL),
(515417, 18836, '23', 'CH2', 25.9, 23, NULL, NULL),
(515418, 18836, '24', 'CH', 81.1, 24, NULL, NULL),
(515419, 18836, '25', 'C', 70.9, 25, NULL, NULL),
(515420, 18836, '26', 'CH3', 27.6, 26, NULL, NULL),
(515421, 18836, '27', 'CH3', 28.1, 27, NULL, NULL),
(515422, 18836, '28', 'CH3', 28.6, 28, NULL, NULL),
(515423, 18836, '29', 'CH3', 19.4, 29, NULL, NULL),
(515424, 18836, '30', 'CH3', 15.7, 30, NULL, NULL),
(515425, 18836, '1''', 'CH', 104.6, 101, NULL, NULL),
(515426, 18836, '2''', 'CH', 74.9, 102, NULL, NULL),
(515427, 18836, '3''', 'CH', 78.4, 103, NULL, NULL),
(515428, 18836, '4''', 'CH', 71.1, 104, NULL, NULL),
(515429, 18836, '5''', 'CH', 77.5, 105, NULL, NULL),
(515430, 18836, '6''', 'CH2', 62.3, 106, NULL, NULL),
(515431, 18837, '1', 'CH2', 32.3, 1, NULL, NULL),
(515432, 18837, '2', 'CH2', 30.5, 2, NULL, NULL),
(515433, 18837, '3', 'CH', 88.9, 3, NULL, NULL),
(515434, 18837, '4', 'C', 42.4, 4, NULL, NULL),
(515435, 18837, '5', 'CH', 53.8, 5, NULL, NULL),
(515436, 18837, '6', 'CH', 67.9, 6, NULL, NULL),
(515437, 18837, '7', 'CH2', 38.9, 7, NULL, NULL),
(515438, 18837, '8', 'CH', 46.6, 8, NULL, NULL),
(515439, 18837, '9', 'C', 20.8, 9, NULL, NULL),
(515440, 18837, '10', 'C', 29.3, 10, NULL, NULL),
(515441, 18837, '11', 'CH2', 26.4, 11, NULL, NULL),
(515442, 18837, '12', 'CH2', 33.5, 12, NULL, NULL),
(515443, 18837, '13', 'C', 46.3, 13, NULL, NULL),
(515444, 18837, '14', 'C', 46.6, 14, NULL, NULL),
(515445, 18837, '15', 'CH2', 48.6, 15, NULL, NULL),
(515446, 18837, '16', 'CH', 72.7, 16, NULL, NULL),
(515447, 18837, '17', 'CH', 56.2, 17, NULL, NULL),
(515448, 18837, '18', 'CH3', 21, 18, NULL, NULL),
(515449, 18837, '19', 'CH2', 30, 19, NULL, NULL),
(515450, 18837, '20', 'C', 86.5, 20, NULL, NULL),
(515451, 18837, '21', 'CH3', 26.1, 21, NULL, NULL),
(515452, 18837, '22', 'CH2', 37.3, 22, NULL, NULL),
(515453, 18837, '23', 'CH2', 24.1, 23, NULL, NULL),
(515454, 18837, '24', 'CH', 85.5, 24, NULL, NULL),
(515455, 18837, '25', 'C', 70.2, 25, NULL, NULL),
(515456, 18837, '26', 'CH3', 27.8, 26, NULL, NULL),
(515457, 18837, '27', 'CH3', 26.6, 27, NULL, NULL),
(515458, 18837, '28', 'CH3', 28.8, 28, NULL, NULL),
(515459, 18837, '29', 'CH3', 20.3, 29, NULL, NULL),
(515460, 18837, '30', 'CH3', 16.5, 30, NULL, NULL),
(515461, 18837, '1''', 'CH', 106.7, 101, NULL, NULL),
(515462, 18837, '2''', 'CH', 75.6, 102, NULL, NULL),
(515463, 18837, '3''', 'CH', 78.4, 103, NULL, NULL),
(515464, 18837, '4''', 'CH', 71.5, 104, NULL, NULL),
(515465, 18837, '5''', 'CH', 77.9, 105, NULL, NULL),
(515466, 18837, '6''', 'CH2', 62.7, 106, NULL, NULL),
(515467, 18838, '1', 'CH2', 32.41, 1, NULL, NULL),
(515468, 18838, '2', 'CH2', 30.16, 2, NULL, NULL),
(515469, 18838, '3', 'CH', 88.96, 3, NULL, NULL),
(515470, 18838, '4', 'C', 42.58, 4, NULL, NULL),
(515471, 18838, '5', 'CH', 53.93, 5, NULL, NULL),
(515472, 18838, '6', 'CH', 67.97, 6, NULL, NULL),
(515473, 18838, '7', 'CH2', 38.54, 7, NULL, NULL),
(515474, 18838, '8', 'CH', 47.06, 8, NULL, NULL),
(515475, 18838, '9', 'C', 20.84, 9, NULL, NULL),
(515476, 18838, '10', 'C', 29.5, 10, NULL, NULL),
(515477, 18838, '11', 'CH2', 26.37, 11, NULL, NULL),
(515478, 18838, '12', 'CH2', 33.31, 12, NULL, NULL),
(515479, 18838, '13', 'C', 44.97, 13, NULL, NULL),
(515480, 18838, '14', 'C', 45.91, 14, NULL, NULL),
(515481, 18838, '15', 'CH2', 46.09, 15, NULL, NULL),
(515482, 18838, '16', 'CH', 73.43, 16, NULL, NULL),
(515483, 18838, '17', 'CH', 58.26, 17, NULL, NULL),
(515484, 18838, '18', 'CH3', 21.51, 18, NULL, NULL),
(515485, 18838, '19', 'CH2', 30.55, 19, NULL, NULL),
(515486, 18838, '20', 'C', 87.17, 20, NULL, NULL),
(515487, 18838, '21', 'CH3', 28.41, 21, NULL, NULL),
(515488, 18838, '22', 'CH2', 34.88, 22, NULL, NULL),
(515489, 18838, '23', 'CH2', 26.37, 23, NULL, NULL),
(515490, 18838, '24', 'CH', 81.64, 24, NULL, NULL),
(515491, 18838, '25', 'C', 71.26, 25, NULL, NULL),
(515492, 18838, '26', 'CH3', 27.04, 26, NULL, NULL),
(515493, 18838, '27', 'CH3', 28.53, 27, NULL, NULL),
(515494, 18838, '28', 'CH3', 28.91, 28, NULL, NULL),
(515495, 18838, '29', 'CH3', 20.09, 29, NULL, NULL),
(515496, 18838, '30', 'CH3', 16.66, 30, NULL, NULL),
(515497, 18838, '1''', 'CH', 106.82, 101, NULL, NULL),
(515498, 18838, '2''', 'CH', 75.82, 102, NULL, NULL),
(515499, 18838, '3''', 'CH', 78.66, 103, NULL, NULL),
(515500, 18838, '4''', 'CH', 71.78, 104, NULL, NULL),
(515501, 18838, '5''', 'CH', 78.06, 105, NULL, NULL),
(515502, 18838, '6''', 'CH2', 62.87, 106, NULL, NULL),
(515503, 18839, '1', 'CH2', 32.8, 1, NULL, NULL),
(515504, 18839, '2', 'CH2', 30.6, 2, NULL, NULL),
(515505, 18839, '3', 'CH', 89.5, 3, NULL, NULL),
(515506, 18839, '4', 'C', 43, 4, NULL, NULL),
(515507, 18839, '5', 'CH', 54.2, 5, NULL, NULL),
(515508, 18839, '6', 'CH', 68.4, 6, NULL, NULL),
(515509, 18839, '7', 'CH2', 38.7, 7, NULL, NULL),
(515510, 18839, '8', 'CH', 47.5, 8, NULL, NULL),
(515511, 18839, '9', 'C', 21.5, 9, NULL, NULL),
(515512, 18839, '10', 'C', 29.6, 10, NULL, NULL),
(515513, 18839, '11', 'CH2', 26.6, 11, NULL, NULL),
(515514, 18839, '12', 'CH2', 33.5, 12, NULL, NULL),
(515515, 18839, '13', 'C', 46, 13, NULL, NULL),
(515516, 18839, '14', 'C', 47.1, 14, NULL, NULL),
(515517, 18839, '15', 'CH2', 48.6, 15, NULL, NULL),
(515518, 18839, '16', 'CH', 71.9, 16, NULL, NULL),
(515519, 18839, '17', 'CH', 57.6, 17, NULL, NULL),
(515520, 18839, '18', 'CH3', 19.4, 18, NULL, NULL),
(515521, 18839, '19', 'CH2', 30.5, 19, NULL, NULL),
(515522, 18839, '20', 'CH', 29.2, 20, NULL, NULL),
(515523, 18839, '21', 'CH3', 18.7, 21, NULL, NULL),
(515524, 18839, '22', 'CH2', 33.6, 22, NULL, NULL),
(515525, 18839, '23', 'CH2', 28.4, 23, NULL, NULL),
(515526, 18839, '24', 'CH', 77.9, 24, NULL, NULL),
(515527, 18839, '25', 'C', 72.3, 25, NULL, NULL),
(515528, 18839, '26', 'CH3', 26.3, 26, NULL, NULL),
(515529, 18839, '27', 'CH3', 26.3, 27, NULL, NULL),
(515530, 18839, '28', 'CH3', 29.3, 28, NULL, NULL),
(515531, 18839, '29', 'CH3', 20.5, 29, NULL, NULL),
(515532, 18839, '30', 'CH3', 17.1, 30, NULL, NULL),
(515533, 18839, '1''', 'CH', 107.1, 101, NULL, NULL),
(515534, 18839, '2''', 'CH', 76, 102, NULL, NULL),
(515535, 18839, '3''', 'CH', 78.7, 103, NULL, NULL),
(515536, 18839, '4''', 'CH', 72.3, 104, NULL, NULL),
(515537, 18839, '5''', 'CH', 78.3, 105, NULL, NULL),
(515538, 18839, '6''', 'CH2', 63.1, 106, NULL, NULL),
(515539, 18840, '1', 'CH2', 32.16, 1, NULL, NULL),
(515540, 18840, '2', 'CH2', 32.91, 2, NULL, NULL),
(515541, 18840, '3', 'CH', 88.81, 3, NULL, NULL),
(515542, 18840, '4', 'C', 42.36, 4, NULL, NULL),
(515543, 18840, '5', 'CH', 53.83, 5, NULL, NULL),
(515544, 18840, '6', 'CH', 67.7, 6, NULL, NULL),
(515545, 18840, '7', 'CH2', 38.16, 7, NULL, NULL),
(515546, 18840, '8', 'CH', 46.76, 8, NULL, NULL),
(515547, 18840, '9', 'C', 21.02, 9, NULL, NULL),
(515548, 18840, '10', 'C', 29.91, 10, NULL, NULL),
(515549, 18840, '11', 'CH2', 26.06, 11, NULL, NULL),
(515550, 18840, '12', 'CH2', 32.91, 12, NULL, NULL),
(515551, 18840, '13', 'C', 45.45, 13, NULL, NULL),
(515552, 18840, '14', 'C', 46.64, 14, NULL, NULL),
(515553, 18840, '15', 'CH2', 48.43, 15, NULL, NULL),
(515554, 18840, '16', 'CH', 71.47, 16, NULL, NULL),
(515555, 18840, '17', 'CH', 56.99, 17, NULL, NULL),
(515556, 18840, '18', 'CH3', 18.51, 18, NULL, NULL),
(515557, 18840, '19', 'CH2', 29.14, 19, NULL, NULL),
(515558, 18840, '20', 'CH', 31.35, 20, NULL, NULL),
(515559, 18840, '21', 'CH3', 18.69, 21, NULL, NULL),
(515560, 18840, '22', 'CH2', 34.58, 22, NULL, NULL),
(515561, 18840, '23', 'CH2', 29.7, 23, NULL, NULL),
(515562, 18840, '24', 'CH', 80.29, 24, NULL, NULL),
(515563, 18840, '25', 'C', 72.46, 25, NULL, NULL),
(515564, 18840, '26', 'CH3', 25.62, 26, NULL, NULL),
(515565, 18840, '27', 'CH3', 25.86, 27, NULL, NULL),
(515566, 18840, '28', 'CH3', 28.66, 28, NULL, NULL),
(515567, 18840, '29', 'CH3', 19.95, 29, NULL, NULL),
(515568, 18840, '30', 'CH3', 16.44, 30, NULL, NULL),
(515569, 18840, '1''', 'CH', 106.66, 101, NULL, NULL),
(515570, 18840, '2''', 'CH', 75.66, 102, NULL, NULL),
(515571, 18840, '3''', 'CH', 78.48, 103, NULL, NULL),
(515572, 18840, '4''', 'CH', 71.61, 104, NULL, NULL),
(515573, 18840, '5''', 'CH', 77.89, 105, NULL, NULL),
(515574, 18840, '6''', 'CH2', 62.79, 106, NULL, NULL),
(515575, 18841, '1', 'CH2', 32.25, 1, NULL, NULL),
(515576, 18841, '2', 'CH2', 30.08, 2, NULL, NULL),
(515577, 18841, '3', 'CH', 89.01, 3, NULL, NULL),
(515578, 18841, '4', 'C', 42.24, 4, NULL, NULL),
(515579, 18841, '5', 'CH', 53.8, 5, NULL, NULL),
(515580, 18841, '6', 'CH', 68.09, 6, NULL, NULL),
(515581, 18841, '7', 'CH2', 38.66, 7, NULL, NULL),
(515582, 18841, '8', 'CH', 47.14, 8, NULL, NULL),
(515583, 18841, '9', 'C', 20.95, 9, NULL, NULL),
(515584, 18841, '10', 'C', 29.43, 10, NULL, NULL),
(515585, 18841, '11', 'CH2', 26.1, 11, NULL, NULL),
(515586, 18841, '12', 'CH2', 33.3, 12, NULL, NULL),
(515587, 18841, '13', 'C', 44.96, 13, NULL, NULL),
(515588, 18841, '14', 'C', 46.05, 14, NULL, NULL),
(515589, 18841, '15', 'CH2', 46.61, 15, NULL, NULL),
(515590, 18841, '16', 'CH', 73.4, 16, NULL, NULL),
(515591, 18841, '17', 'CH', 58.32, 17, NULL, NULL),
(515592, 18841, '18', 'CH3', 21.54, 18, NULL, NULL),
(515593, 18841, '19', 'CH2', 30.7, 19, NULL, NULL),
(515594, 18841, '20', 'C', 87.18, 20, NULL, NULL),
(515595, 18841, '21', 'CH3', 28.63, 21, NULL, NULL),
(515596, 18841, '22', 'CH2', 34.86, 22, NULL, NULL),
(515597, 18841, '23', 'CH2', 26.35, 23, NULL, NULL),
(515598, 18841, '24', 'CH', 81.67, 24, NULL, NULL),
(515599, 18841, '25', 'C', 71.22, 25, NULL, NULL),
(515600, 18841, '26', 'CH3', 27.03, 26, NULL, NULL),
(515601, 18841, '27', 'CH3', 28.08, 27, NULL, NULL),
(515602, 18841, '28', 'CH3', 28.47, 28, NULL, NULL),
(515603, 18841, '29', 'CH3', 20.12, 29, NULL, NULL),
(515604, 18841, '30', 'CH3', 16.39, 30, NULL, NULL),
(515605, 18841, '1''', 'CH', 104.79, 101, NULL, NULL),
(515606, 18841, '2''', 'CH', 76.15, 102, NULL, NULL),
(515607, 18841, '3''', 'CH', 75.63, 103, NULL, NULL),
(515608, 18841, '4''', 'CH', 71.27, 104, NULL, NULL),
(515609, 18841, '5''', 'CH2', 67.02, 105, NULL, NULL),
(515610, 18841, '2''a', 'C', 170.09, 102001, NULL, NULL),
(515611, 18841, '2''b', 'CH3', 21.21, 102002, NULL, NULL),
(515612, 18842, '1', 'CH2', 32.2, 1, NULL, NULL),
(515613, 18842, '2', 'CH2', 30, 2, NULL, NULL),
(515614, 18842, '3', 'CH', 89.3, 3, NULL, NULL),
(515615, 18842, '4', 'C', 42.6, 4, NULL, NULL),
(515616, 18842, '5', 'CH', 54, 5, NULL, NULL),
(515617, 18842, '6', 'CH', 67.9, 6, NULL, NULL),
(515618, 18842, '7', 'CH2', 38.7, 7, NULL, NULL),
(515619, 18842, '8', 'CH', 47.1, 8, NULL, NULL),
(515620, 18842, '9', 'C', 21, 9, NULL, NULL),
(515621, 18842, '10', 'C', 29.4, 10, NULL, NULL),
(515622, 18842, '11', 'CH2', 26.2, 11, NULL, NULL),
(515623, 18842, '12', 'CH2', 33.4, 12, NULL, NULL),
(515624, 18842, '13', 'C', 45, 13, NULL, NULL),
(515625, 18842, '14', 'C', 46.1, 14, NULL, NULL),
(515626, 18842, '15', 'CH2', 46.7, 15, NULL, NULL),
(515627, 18842, '16', 'CH', 73.5, 16, NULL, NULL),
(515628, 18842, '17', 'CH', 58.4, 17, NULL, NULL),
(515629, 18842, '18', 'CH3', 21.5, 18, NULL, NULL),
(515630, 18842, '19', 'CH2', 30.6, 19, NULL, NULL),
(515631, 18842, '20', 'C', 87.3, 20, NULL, NULL),
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(515633, 18842, '22', 'CH2', 34.9, 22, NULL, NULL),
(515634, 18842, '23', 'CH2', 26.5, 23, NULL, NULL),
(515635, 18842, '24', 'CH', 81.7, 24, NULL, NULL),
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(515648, 18842, '2''a', 'C', 170.1, 102001, NULL, NULL),
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(515654, 18843, '5', 'CH', 54, 5, NULL, NULL),
(515655, 18843, '6', 'CH', 67.9, 6, NULL, NULL),
(515656, 18843, '7', 'CH2', 38.6, 7, NULL, NULL),
(515657, 18843, '8', 'CH', 47, 8, NULL, NULL),
(515658, 18843, '9', 'C', 20.9, 9, NULL, NULL),
(515659, 18843, '10', 'C', 29.5, 10, NULL, NULL),
(515660, 18843, '11', 'CH2', 26.2, 11, NULL, NULL),
(515661, 18843, '12', 'CH2', 33.3, 12, NULL, NULL),
(515662, 18843, '13', 'C', 45, 13, NULL, NULL),
(515663, 18843, '14', 'C', 46.1, 14, NULL, NULL),
(515664, 18843, '15', 'CH2', 46.6, 15, NULL, NULL),
(515665, 18843, '16', 'CH', 73.7, 16, NULL, NULL),
(515666, 18843, '17', 'CH', 58.3, 17, NULL, NULL),
(515667, 18843, '18', 'CH3', 21.5, 18, NULL, NULL),
(515668, 18843, '19', 'CH2', 30.5, 19, NULL, NULL),
(515669, 18843, '20', 'C', 87.2, 20, NULL, NULL),
(515670, 18843, '21', 'CH3', 27.1, 21, NULL, NULL),
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