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(392573, 14043, '6''''', 'CH3', 17.52, 206, NULL, NULL),
(392574, 14043, '3''a', 'CH3', 42.5, 103001, NULL, NULL),
(392575, 14043, '3''b', 'CH3', 42.5, 103002, NULL, NULL),
(392576, 14044, '1', 'C', 198.6, 1, NULL, NULL),
(392577, 14044, '2', 'CH2', 42, 2, NULL, NULL),
(392578, 14044, '3', 'CH', 37.7, 3, NULL, NULL),
(392579, 14044, '4', 'CH2', 32.8, 4, NULL, NULL),
(392580, 14044, '4a', 'C', 149.7, 4001, NULL, NULL),
(392581, 14044, '5', 'CH', 133.2, 5, NULL, NULL),
(392582, 14044, '6', 'CH', 129.1, 6, NULL, NULL),
(392583, 14044, '6a', 'C', 133.6, 6001, NULL, NULL),
(392584, 14044, '7', 'C', 187.5, 7, NULL, NULL),
(392585, 14044, '7a', 'C', 115.5, 7001, NULL, NULL),
(392586, 14044, '8', 'C', 162.2, 8, NULL, NULL),
(392587, 14044, '9', 'CH', 123.7, 9, NULL, NULL),
(392588, 14044, '10', 'CH', 137.1, 10, NULL, NULL),
(392589, 14044, '11', 'CH', 119.6, 11, NULL, NULL),
(392590, 14044, '11a', 'C', 135.1, 11001, NULL, NULL),
(392591, 14044, '12', 'C', 182.9, 12, NULL, NULL),
(392592, 14044, '12a', 'C', 135.7, 12001, NULL, NULL),
(392593, 14044, '12b', 'C', 136.9, 12002, NULL, NULL),
(392594, 14044, '13', 'CH2', 65.9, 13, NULL, NULL),
(392595, 14045, '2', 'C', 172.7, 2, NULL, NULL),
(392596, 14045, '3', 'CH', 109.5, 3, NULL, NULL),
(392597, 14045, '4', 'C', 180.3, 4, NULL, NULL),
(392598, 14045, '4a', 'C', 122.5, 4001, NULL, NULL),
(392599, 14045, '5', 'C', 142.6, 5, NULL, NULL),
(392600, 14045, '6', 'CH', 122.1, 6, NULL, NULL),
(392601, 14045, '6a', 'C', 132.4, 6001, NULL, NULL),
(392602, 14045, '7', 'C', 152, 7, NULL, NULL),
(392603, 14045, '7a', 'C', 110, 7001, NULL, NULL),
(392604, 14045, '8', 'C', 201, 8, NULL, NULL),
(392605, 14045, '9', 'CH2', 35.8, 9, NULL, NULL),
(392606, 14045, '10', 'CH2', 36, 10, NULL, NULL),
(392607, 14045, '11', 'C', 201.6, 11, NULL, NULL),
(392608, 14045, '11a', 'C', 108.5, 11001, NULL, NULL),
(392609, 14045, '12', 'C', 156.7, 12, NULL, NULL),
(392610, 14045, '12a', 'C', 117.4, 12001, NULL, NULL),
(392611, 14045, '12b', 'C', 156.5, 12002, NULL, NULL),
(392612, 14045, '13', 'CH3', 23.7, 13, NULL, NULL),
(392613, 14045, '14', 'C', 73.6, 14, NULL, NULL),
(392614, 14045, '15', 'CH3', 25.7, 15, NULL, NULL),
(392615, 14045, '16', 'CH2', 33, 16, NULL, NULL),
(392616, 14045, '17', 'CH3', 7.7, 17, NULL, NULL),
(392617, 14046, '1', 'C', 157.1, 1, NULL, NULL),
(392618, 14046, '2', 'C', 115.7, 2, NULL, NULL),
(392619, 14046, '3', 'C', 157.1, 3, NULL, NULL),
(392620, 14046, '4', 'CH', 103.4, 4, NULL, NULL),
(392621, 14046, '4a', 'C', 132.3, 4001, NULL, NULL),
(392622, 14046, '5', 'CH', 113.7, 5, NULL, NULL),
(392623, 14046, '6', 'C', 158.6, 6, NULL, NULL),
(392624, 14046, '7', 'CH', 105.6, 7, NULL, NULL),
(392625, 14046, '8', 'C', 164.4, 8, NULL, NULL),
(392626, 14046, '8a', 'C', 105.6, 8001, NULL, NULL),
(392627, 14046, '9', 'C', 182.2, 9, NULL, NULL),
(392628, 14046, '9a', 'C', 110.3, 9001, NULL, NULL),
(392629, 14046, '10', 'C', 183.8, 10, NULL, NULL),
(392630, 14046, '10a', 'C', 135.9, 10001, NULL, NULL),
(392631, 14046, '1''', 'CH', 66.1, 101, NULL, NULL),
(392632, 14046, '2''', 'CH2', 26.9, 102, NULL, NULL),
(392633, 14046, '3''', 'CH2', 15.3, 103, NULL, NULL),
(392634, 14046, '4''', 'CH2', 35.3, 104, NULL, NULL),
(392635, 14046, '5''', 'C', 99.9, 105, NULL, NULL),
(392636, 14046, '6''', 'CH3', 27.5, 106, NULL, NULL),
(392637, 14046, '1''''', 'CH3', 55.1, 201, NULL, NULL),
(392638, 14047, '1', 'C', 165.2, 1, NULL, NULL),
(392639, 14047, '2', 'C', 116.2, 2, NULL, NULL),
(392640, 14047, '3', 'C', 170.6, 3, NULL, NULL),
(392641, 14047, '4', 'CH', 104.6, 4, NULL, NULL),
(392642, 14047, '4a', 'C', 132.9, 4001, NULL, NULL),
(392643, 14047, '5', 'CH', 111.8, 5, NULL, NULL),
(392644, 14047, '6', 'C', 163.2, 6, NULL, NULL),
(392645, 14047, '7', 'CH', 105.1, 7, NULL, NULL),
(392646, 14047, '8', 'C', 162.3, 8, NULL, NULL),
(392647, 14047, '8a', 'C', 107.9, 8001, NULL, NULL),
(392648, 14047, '9', 'C', 185.9, 9, NULL, NULL),
(392649, 14047, '9a', 'C', 111.7, 9001, NULL, NULL),
(392650, 14047, '10', 'C', 183.5, 10, NULL, NULL),
(392651, 14047, '10a', 'C', 138.2, 10001, NULL, NULL),
(392652, 14047, '1''', 'CH3', 56.7, 101, NULL, NULL),
(392653, 14047, '1''''', 'CH', 69.6, 201, NULL, NULL),
(392654, 14047, '2''''', 'CH2', 37.8, 202, NULL, NULL),
(392655, 14047, '3''''', 'CH2', 32.7, 203, NULL, NULL),
(392656, 14047, '4''''', 'CH2', 26.3, 204, NULL, NULL),
(392657, 14047, '5''''', 'CH2', 23.4, 205, NULL, NULL),
(392658, 14047, '6''''', 'CH3', 14.4, 206, NULL, NULL),
(392659, 14047, '1''''''', 'CH3', 56.3, 301, NULL, NULL),
(392660, 14048, '1', 'C', 203.6, 1, NULL, NULL),
(392661, 14048, '2', 'CH2', 48, 2, NULL, NULL),
(392662, 14048, '3', 'C', 78.8, 3, NULL, NULL),
(392663, 14048, '4', 'CH2', 43.3, 4, NULL, NULL),
(392664, 14048, '4a', 'C', 81.2, 4001, NULL, NULL),
(392665, 14048, '5', 'CH', 144.4, 5, NULL, NULL),
(392666, 14048, '6', 'CH', 116.2, 6, NULL, NULL),
(392667, 14048, '6a', 'C', 137.3, 6001, NULL, NULL),
(392668, 14048, '7', 'C', 187.1, 7, NULL, NULL),
(392669, 14048, '7a', 'C', 112.9, 7001, NULL, NULL),
(392670, 14048, '8', 'C', 156.8, 8, NULL, NULL),
(392671, 14048, '9', 'C', 137.6, 9, NULL, NULL),
(392672, 14048, '10', 'CH', 132.5, 10, NULL, NULL),
(392673, 14048, '11', 'CH', 118.4, 11, NULL, NULL),
(392674, 14048, '11a', 'C', 129.3, 11001, NULL, NULL),
(392675, 14048, '12', 'C', 181, 12, NULL, NULL);
INSERT INTO `carbons` (`id`, `molecularId`, `numeration`, `carbonType`, `shift`, `num2`, `created_at`, `updated_at`) VALUES
(392676, 14048, '12a', 'C', 137.8, 12001, NULL, NULL),
(392677, 14048, '12b', 'C', 76.2, 12002, NULL, NULL),
(392678, 14048, '13', 'CH3', 24.4, 13, NULL, NULL),
(392679, 14048, '1''', 'CH', -9999, 101, NULL, NULL),
(392680, 14048, '2''', 'CH2', -9999, 102, NULL, NULL),
(392681, 14048, '3''', 'CH', -9999, 103, NULL, NULL),
(392682, 14048, '4''', 'CH', -9999, 104, NULL, NULL),
(392683, 14048, '5''', 'CH', -9999, 105, NULL, NULL),
(392684, 14048, '6''', 'CH3', -9999, 106, NULL, NULL),
(392685, 14048, '1''''', 'CH', -9999, 201, NULL, NULL),
(392686, 14048, '2''''', 'CH2', -9999, 202, NULL, NULL),
(392687, 14048, '3''''', 'CH2', -9999, 203, NULL, NULL),
(392688, 14048, '4''''', 'CH', -9999, 204, NULL, NULL),
(392689, 14048, '5''''', 'CH', -9999, 205, NULL, NULL),
(392690, 14048, '6''''', 'CH3', -9999, 206, NULL, NULL),
(392691, 14048, '1''''''', 'CH', -9999, 301, NULL, NULL),
(392692, 14048, '2''''''', 'CH', -9999, 302, NULL, NULL),
(392693, 14048, '3''''''', 'CH', -9999, 303, NULL, NULL),
(392694, 14048, '4''''''', 'C', -9999, 304, NULL, NULL),
(392695, 14048, '5''''''', 'CH', -9999, 305, NULL, NULL),
(392696, 14048, '6''''''', 'CH3', -9999, 306, NULL, NULL),
(392697, 14049, '1', 'C', 174, 1, NULL, NULL),
(392698, 14049, '2', 'CH2', 44.4, 2, NULL, NULL),
(392699, 14049, '3', 'C', 77.2, 3, NULL, NULL),
(392700, 14049, '4', 'CH2', 38.6, 4, NULL, NULL),
(392701, 14049, '4a', 'C', 134.9, 4001, NULL, NULL),
(392702, 14049, '5', 'CH', 139.6, 5, NULL, NULL),
(392703, 14049, '6', 'CH', 118.3, 6, NULL, NULL),
(392704, 14049, '6a', 'C', 131.5, 6001, NULL, NULL),
(392705, 14049, '7', 'C', 187.7, 7, NULL, NULL),
(392706, 14049, '7a', 'C', 115.2, 7001, NULL, NULL),
(392707, 14049, '8', 'C', 158.9, 8, NULL, NULL),
(392708, 14049, '9', 'C', 138.4, 9, NULL, NULL),
(392709, 14049, '10', 'CH', 133.2, 10, NULL, NULL),
(392710, 14049, '11', 'CH', 119.3, 11, NULL, NULL),
(392711, 14049, '11a', 'C', 131.7, 11001, NULL, NULL),
(392712, 14049, '12', 'C', 187.7, 12, NULL, NULL),
(392713, 14049, '12a', 'C', 115.2, 12001, NULL, NULL),
(392714, 14049, '12b', 'C', 161.5, 12002, NULL, NULL),
(392715, 14049, '13', 'CH3', 23.2, 13, NULL, NULL),
(392716, 14049, '1''', 'CH', -9999, 101, NULL, NULL),
(392717, 14049, '2''', 'CH2', -9999, 102, NULL, NULL),
(392718, 14049, '3''', 'CH', -9999, 103, NULL, NULL),
(392719, 14049, '4''', 'CH', -9999, 104, NULL, NULL),
(392720, 14049, '5''', 'CH', -9999, 105, NULL, NULL),
(392721, 14049, '6''', 'CH3', -9999, 106, NULL, NULL),
(392722, 14049, '1''''', 'CH', -9999, 201, NULL, NULL),
(392723, 14049, '2''''', 'CH2', -9999, 202, NULL, NULL),
(392724, 14049, '3''''', 'CH2', -9999, 203, NULL, NULL),
(392725, 14049, '4''''', 'CH', -9999, 204, NULL, NULL),
(392726, 14049, '5''''', 'CH', -9999, 205, NULL, NULL),
(392727, 14049, '6''''', 'CH3', -9999, 206, NULL, NULL),
(392728, 14049, '1''''''', 'CH', -9999, 301, NULL, NULL),
(392729, 14049, '2''''''', 'CH', -9999, 302, NULL, NULL),
(392730, 14049, '3''''''', 'CH', -9999, 303, NULL, NULL),
(392731, 14049, '4''''''', 'C', -9999, 304, NULL, NULL),
(392732, 14049, '5''''''', 'CH', -9999, 305, NULL, NULL),
(392733, 14049, '6''''''', 'CH3', -9999, 306, NULL, NULL),
(392734, 14050, '1', 'C', 197.8, 1, NULL, NULL),
(392735, 14050, '2', 'CH2', 53.8, 2, NULL, NULL),
(392736, 14050, '3', 'C', 71.6, 3, NULL, NULL),
(392737, 14050, '4', 'CH2', 44.5, 4, NULL, NULL),
(392738, 14050, '4a', 'C', 151.9, 4001, NULL, NULL),
(392739, 14050, '5', 'CH', 124.3, 5, NULL, NULL),
(392740, 14050, '6', 'C', 163.9, 6, NULL, NULL),
(392741, 14050, '6a', 'C', 115.4, 6001, NULL, NULL),
(392742, 14050, '7', 'C', 192.6, 7, NULL, NULL),
(392743, 14050, '7a', 'C', 117, 7001, NULL, NULL),
(392744, 14050, '8', 'C', 162.1, 8, NULL, NULL),
(392745, 14050, '9', 'CH', 122.3, 9, NULL, NULL),
(392746, 14050, '10', 'CH', 138, 10, NULL, NULL),
(392747, 14050, '11', 'CH', 120, 11, NULL, NULL),
(392748, 14050, '11a', 'C', 129.1, 11001, NULL, NULL),
(392749, 14050, '12', 'C', 183.9, 12, NULL, NULL),
(392750, 14050, '12a', 'C', 135.8, 12001, NULL, NULL),
(392751, 14050, '12b', 'C', 138, 12002, NULL, NULL),
(392752, 14050, '13', 'CH3', 29.4, 13, NULL, NULL),
(392753, 14051, '1', 'C', 202.6, 1, NULL, NULL),
(392754, 14051, '2', 'CH2', 53.4, 2, NULL, NULL),
(392755, 14051, '3', 'C', 75.7, 3, NULL, NULL),
(392756, 14051, '4', 'CH2', 43.2, 4, NULL, NULL),
(392757, 14051, '4a', 'C', 80.6, 4001, NULL, NULL),
(392758, 14051, '5', 'CH', 145.6, 5, NULL, NULL),
(392759, 14051, '6', 'CH', 115.9, 6, NULL, NULL),
(392760, 14051, '6a', 'C', 130.7, 6001, NULL, NULL),
(392761, 14051, '7', 'C', 188.4, 7, NULL, NULL),
(392762, 14051, '7a', 'C', 113.9, 7001, NULL, NULL),
(392763, 14051, '8', 'C', 156.3, 8, NULL, NULL),
(392764, 14051, '9', 'C', 140.3, 9, NULL, NULL),
(392765, 14051, '10', 'CH', 133, 10, NULL, NULL),
(392766, 14051, '11', 'CH', 118.9, 11, NULL, NULL),
(392767, 14051, '11a', 'C', 136.2, 11001, NULL, NULL),
(392768, 14051, '12', 'C', 182.2, 12, NULL, NULL),
(392769, 14051, '12a', 'C', 137.1, 12001, NULL, NULL),
(392770, 14051, '12b', 'C', 81.1, 12002, NULL, NULL),
(392771, 14051, '13', 'CH3', 29.3, 13, NULL, NULL),
(392772, 14051, '1''', 'CH', -9999, 101, NULL, NULL),
(392773, 14051, '2''', 'CH2', -9999, 102, NULL, NULL),
(392774, 14051, '3''', 'CH', -9999, 103, NULL, NULL),
(392775, 14051, '4''', 'CH', -9999, 104, NULL, NULL),
(392776, 14051, '5''', 'CH', -9999, 105, NULL, NULL),
(392777, 14051, '6''', 'CH3', -9999, 106, NULL, NULL),
(392778, 14052, '1', 'C', 196.7, 1, NULL, NULL),
(392779, 14052, '2', 'CH2', 53.1, 2, NULL, NULL),
(392780, 14052, '3', 'C', 71.5, 3, NULL, NULL),
(392781, 14052, '4', 'CH2', 43.4, 4, NULL, NULL),
(392782, 14052, '4a', 'C', 149.3, 4001, NULL, NULL),
(392783, 14052, '5', 'CH', 134.1, 5, NULL, NULL),
(392784, 14052, '6', 'CH', 128.5, 6, NULL, NULL),
(392785, 14052, '6a', 'C', 132.7, 6001, NULL, NULL),
(392786, 14052, '7', 'C', 187.3, 7, NULL, NULL),
(392787, 14052, '7a', 'C', 114.7, 7001, NULL, NULL),
(392788, 14052, '8', 'C', 157.1, 8, NULL, NULL),
(392789, 14052, '9', 'C', 136.4, 9, NULL, NULL),
(392790, 14052, '10', 'CH', 133.4, 10, NULL, NULL),
(392791, 14052, '11', 'CH', 118.4, 11, NULL, NULL),
(392792, 14052, '11a', 'C', 133.7, 11001, NULL, NULL),
(392793, 14052, '12', 'C', 182.5, 12, NULL, NULL),
(392794, 14052, '12a', 'C', 135.4, 12001, NULL, NULL),
(392795, 14052, '12b', 'C', 135.5, 12002, NULL, NULL),
(392796, 14052, '13', 'CH3', 29.6, 13, NULL, NULL),
(392797, 14052, '1''', 'CH', -9999, 101, NULL, NULL),
(392798, 14052, '2''', 'CH2', -9999, 102, NULL, NULL),
(392799, 14052, '3''', 'CH', -9999, 103, NULL, NULL),
(392800, 14052, '4''', 'CH', -9999, 104, NULL, NULL),
(392801, 14052, '5''', 'CH', -9999, 105, NULL, NULL),
(392802, 14052, '6''', 'CH3', -9999, 106, NULL, NULL),
(392803, 14053, '1', 'C', 203.8, 1, NULL, NULL),
(392804, 14053, '2', 'CH2', 54.6, 2, NULL, NULL),
(392805, 14053, '3', 'C', 74.9, 3, NULL, NULL),
(392806, 14053, '4', 'CH2', 44, 4, NULL, NULL),
(392807, 14053, '4a', 'C', 82.2, 4001, NULL, NULL),
(392808, 14053, '5', 'CH', 138.8, 5, NULL, NULL),
(392809, 14053, '6', 'CH', 118.6, 6, NULL, NULL),
(392810, 14053, '6a', 'C', 125.2, 6001, NULL, NULL),
(392811, 14053, '7', 'C', 156.6, 7, NULL, NULL),
(392812, 14053, '7a', 'C', 112.6, 7001, NULL, NULL),
(392813, 14053, '8', 'C', 187.5, 8, NULL, NULL),
(392814, 14053, '9', 'C', 145, 9, NULL, NULL),
(392815, 14053, '10', 'CH', 134.7, 10, NULL, NULL),
(392816, 14053, '11', 'C', 133.9, 11, NULL, NULL),
(392817, 14053, '11a', 'C', 116.2, 11001, NULL, NULL),
(392818, 14053, '12', 'C', 143.7, 12, NULL, NULL),
(392819, 14053, '12a', 'C', 128.9, 12001, NULL, NULL),
(392820, 14053, '12b', 'C', 83.1, 12002, NULL, NULL),
(392821, 14053, '13', 'CH3', 29.4, 13, NULL, NULL),
(392822, 14053, '1''', 'CH', -9999, 101, NULL, NULL),
(392823, 14053, '2''', 'CH2', -9999, 102, NULL, NULL),
(392824, 14053, '3''', 'CH', -9999, 103, NULL, NULL),
(392825, 14053, '4''', 'CH', -9999, 104, NULL, NULL),
(392826, 14053, '5''', 'CH', -9999, 105, NULL, NULL),
(392827, 14053, '6''', 'CH3', -9999, 106, NULL, NULL),
(392828, 14053, '1''''', 'CH2', -9999, 201, NULL, NULL),
(392829, 14053, '2''''', 'C', -9999, 202, NULL, NULL),
(392830, 14053, '1''''''', 'C', -9999, 301, NULL, NULL),
(392831, 14053, '2''''''', 'CH', -9999, 302, NULL, NULL),
(392832, 14053, '3''''''', 'CH', -9999, 303, NULL, NULL),
(392833, 14053, '4''''''', 'C', -9999, 304, NULL, NULL),
(392834, 14053, '5''''''', 'CH', -9999, 305, NULL, NULL),
(392835, 14053, '6''''''', 'CH', -9999, 306, NULL, NULL),
(392836, 14054, '1', 'C', 203.9, 1, NULL, NULL),
(392837, 14054, '2', 'CH2', 54.7, 2, NULL, NULL),
(392838, 14054, '3', 'C', 74.8, 3, NULL, NULL),
(392839, 14054, '4', 'CH2', 44.1, 4, NULL, NULL),
(392840, 14054, '4a', 'C', 82.3, 4001, NULL, NULL),
(392841, 14054, '5', 'CH', 138.3, 5, NULL, NULL),
(392842, 14054, '6', 'CH', 118.8, 6, NULL, NULL),
(392843, 14054, '6a', 'C', 123.9, 6001, NULL, NULL),
(392844, 14054, '7', 'C', 156.7, 7, NULL, NULL),
(392845, 14054, '7a', 'C', 112.9, 7001, NULL, NULL),
(392846, 14054, '8', 'C', 187.5, 8, NULL, NULL),
(392847, 14054, '9', 'C', 143.6, 9, NULL, NULL),
(392848, 14054, '10', 'CH', 136.1, 10, NULL, NULL),
(392849, 14054, '11', 'C', 130.7, 11, NULL, NULL),
(392850, 14054, '11a', 'C', 116.8, 11001, NULL, NULL),
(392851, 14054, '12', 'C', 143.1, 12, NULL, NULL),
(392852, 14054, '12a', 'C', 128.4, 12001, NULL, NULL),
(392853, 14054, '12b', 'C', 83.3, 12002, NULL, NULL),
(392854, 14054, '13', 'CH3', 29.5, 13, NULL, NULL),
(392855, 14054, '1''', 'CH', -9999, 101, NULL, NULL),
(392856, 14054, '2''', 'CH2', -9999, 102, NULL, NULL),
(392857, 14054, '3''', 'CH', -9999, 103, NULL, NULL),
(392858, 14054, '4''', 'CH', -9999, 104, NULL, NULL),
(392859, 14054, '5''', 'CH', -9999, 105, NULL, NULL),
(392860, 14054, '6''', 'CH3', -9999, 106, NULL, NULL),
(392861, 14054, '1''''', 'CH2', -9999, 201, NULL, NULL),
(392862, 14054, '2''''', 'C', -9999, 202, NULL, NULL),
(392863, 14054, '1''''''', 'C', -9999, 301, NULL, NULL),
(392864, 14054, '2''''''', 'C', -9999, 302, NULL, NULL),
(392865, 14054, '3''''''', 'C', -9999, 303, NULL, NULL),
(392866, 14054, '4''''''', 'CH', -9999, 304, NULL, NULL),
(392867, 14054, '5''''''', 'CH', -9999, 305, NULL, NULL),
(392868, 14054, '6''''''', 'CH', -9999, 306, NULL, NULL),
(392869, 14054, '7''''''', 'CH', -9999, 307, NULL, NULL),
(392870, 14054, '8''''''', 'C', -9999, 308, NULL, NULL),
(392871, 14054, '2''''''a', 'CH3', -9999, 302001, NULL, NULL),
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