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(404768, 14551, '1', 'C', 210.4, 1, NULL, NULL),
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(404780, 14551, '13', 'C', 127.45, 13, NULL, NULL),
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(404796, 14552, '8', 'CH', 39.3, 8, NULL, NULL),
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(404817, 14553, '9', 'C', 43.2, 9, NULL, NULL),
(404818, 14553, '10', 'CH', 46.1, 10, NULL, NULL),
(404819, 14553, '11', 'CH2', 37.3, 11, NULL, NULL),
(404820, 14553, '12', 'CH2', 25.9, 12, NULL, NULL),
(404821, 14553, '13', 'CH', 40.1, 13, NULL, NULL),
(404822, 14553, '14', 'CH2', 30.5, 14, NULL, NULL),
(404823, 14553, '15', 'CH2', 68.8, 15, NULL, NULL),
(404824, 14553, '16', 'CH2', 63.6, 16, NULL, NULL),
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(404826, 14553, '18', 'C', 171.3, 18, NULL, NULL),
(404827, 14553, '19', 'CH3', 16.5, 19, NULL, NULL),
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(404830, 14554, '2', 'CH', 66.4, 2, NULL, NULL),
(404831, 14554, '3', 'CH', 121.9, 3, NULL, NULL),
(404832, 14554, '4', 'C', 145.7, 4, NULL, NULL),
(404833, 14554, '5', 'C', 54.3, 5, NULL, NULL),
(404834, 14554, '6', 'CH', 75, 6, NULL, NULL),
(404835, 14554, '7', 'CH', 75.6, 7, NULL, NULL),
(404836, 14554, '8', 'CH', 41.9, 8, NULL, NULL),
(404837, 14554, '9', 'C', 39.1, 9, NULL, NULL),
(404838, 14554, '10', 'CH', 36.4, 10, NULL, NULL),
(404839, 14554, '11', 'CH2', 29.2, 11, NULL, NULL),
(404840, 14554, '12', 'CH2', 24.2, 12, NULL, NULL),
(404841, 14554, '13', 'C', 144.8, 13, NULL, NULL),
(404842, 14554, '14', 'CH', 140.9, 14, NULL, NULL),
(404843, 14554, '15', 'CH2', 112, 15, NULL, NULL),
(404844, 14554, '16', 'CH2', 116.6, 16, NULL, NULL),
(404845, 14554, '17', 'CH3', 11.3, 17, NULL, NULL),
(404846, 14554, '18', 'CH', 96.1, 18, NULL, NULL),
(404847, 14554, '19', 'CH', 98.7, 19, NULL, NULL),
(404848, 14554, '20', 'CH3', 25.6, 20, NULL, NULL),
(404849, 14554, '2a', 'C', 172.5, 2001, NULL, NULL),
(404850, 14554, '2b', 'CH2', 36.2, 2002, NULL, NULL),
(404851, 14554, '2c', 'CH2', 18.8, 2003, NULL, NULL),
(404852, 14554, '2d', 'CH3', 13.5, 2004, NULL, NULL),
(404853, 14554, '7a', 'C', 171.2, 7001, NULL, NULL),
(404854, 14554, '7b', 'CH3', 20.8, 7002, NULL, NULL),
(404855, 14554, '18a', 'C', 169.7, 18001, NULL, NULL),
(404856, 14554, '18b', 'CH3', 20.8, 18002, NULL, NULL),
(404857, 14554, '19a', 'C', 168.9, 19001, NULL, NULL),
(404858, 14554, '19b', 'CH3', 21.4, 19002, NULL, NULL),
(404859, 14555, '1', 'CH2', 27.2, 1, NULL, NULL),
(404860, 14555, '2', 'CH', 66.5, 2, NULL, NULL),
(404861, 14555, '3', 'CH', 122, 3, NULL, NULL),
(404862, 14555, '4', 'C', 145.4, 4, NULL, NULL),
(404863, 14555, '5', 'C', 53.5, 5, NULL, NULL),
(404864, 14555, '6', 'CH', 77.1, 6, NULL, NULL),
(404865, 14555, '7', 'CH', 72.8, 7, NULL, NULL),
(404866, 14555, '8', 'CH', 43.3, 8, NULL, NULL),
(404867, 14555, '9', 'C', 38.8, 9, NULL, NULL),
(404868, 14555, '10', 'CH', 36.5, 10, NULL, NULL),
(404869, 14555, '11', 'CH2', 29.5, 11, NULL, NULL),
(404870, 14555, '12', 'CH2', 24.3, 12, NULL, NULL),
(404871, 14555, '13', 'C', 145.3, 13, NULL, NULL),
(404872, 14555, '14', 'CH', 140.9, 14, NULL, NULL),
(404873, 14555, '15', 'CH2', 112.1, 15, NULL, NULL),
(404874, 14555, '16', 'CH2', 116.2, 16, NULL, NULL),
(404875, 14555, '17', 'CH3', 11.3, 17, NULL, NULL),
(404876, 14555, '18', 'CH', 96.2, 18, NULL, NULL),
(404877, 14555, '19', 'CH', 99, 19, NULL, NULL),
(404878, 14555, '20', 'CH3', 25.7, 20, NULL, NULL),
(404879, 14555, '2a', 'C', 172.4, 2001, NULL, NULL),
(404880, 14555, '2b', 'CH2', 36.2, 2002, NULL, NULL),
(404881, 14555, '2c', 'CH2', 18.8, 2003, NULL, NULL),
(404882, 14555, '2d', 'CH3', 13.5, 2004, NULL, NULL),
(404883, 14555, '18a', 'C', 170.3, 18001, NULL, NULL),
(404884, 14555, '18b', 'CH3', 20.7, 18002, NULL, NULL),
(404885, 14555, '19a', 'C', 169.2, 19001, NULL, NULL),
(404886, 14555, '19b', 'CH3', 21.4, 19002, NULL, NULL),
(404887, 14556, '1', 'CH2', 27.1, 1, NULL, NULL),
(404888, 14556, '2', 'CH', 66.2, 2, NULL, NULL),
(404889, 14556, '3', 'CH', 123.6, 3, NULL, NULL),
(404890, 14556, '4', 'C', 144, 4, NULL, NULL),
(404891, 14556, '5', 'C', 53.1, 5, NULL, NULL),
(404892, 14556, '6', 'CH', 77, 6, NULL, NULL),
(404893, 14556, '7', 'CH', 71.2, 7, NULL, NULL),
(404894, 14556, '8', 'CH', 43.2, 8, NULL, NULL),
(404895, 14556, '9', 'C', 38.6, 9, NULL, NULL),
(404896, 14556, '10', 'CH', 37.3, 10, NULL, NULL),
(404897, 14556, '11', 'CH2', 29.3, 11, NULL, NULL),
(404898, 14556, '12', 'CH2', 24.2, 12, NULL, NULL),
(404899, 14556, '13', 'C', 145.3, 13, NULL, NULL),
(404900, 14556, '14', 'CH', 140.7, 14, NULL, NULL),
(404901, 14556, '15', 'CH2', 112.3, 15, NULL, NULL),
(404902, 14556, '16', 'CH2', 115.9, 16, NULL, NULL),
(404903, 14556, '17', 'CH3', 11.2, 17, NULL, NULL),
(404904, 14556, '18', 'CH', 95.1, 18, NULL, NULL),
(404905, 14556, '19', 'CH', 98.6, 19, NULL, NULL),
(404906, 14556, '20', 'CH3', 25.7, 20, NULL, NULL),
(404907, 14556, '2a', 'C', 172.3, 2001, NULL, NULL),
(404908, 14556, '2b', 'CH2', 36.1, 2002, NULL, NULL),
(404909, 14556, '2c', 'CH2', 18.7, 2003, NULL, NULL),
(404910, 14556, '2d', 'CH3', 13.5, 2004, NULL, NULL),
(404911, 14556, '6a', 'C', 170.6, 6001, NULL, NULL),
(404912, 14556, '6b', 'CH3', 20.9, 6002, NULL, NULL),
(404913, 14556, '18a', 'C', 169.6, 18001, NULL, NULL);
INSERT INTO `carbons` (`id`, `molecularId`, `numeration`, `carbonType`, `shift`, `num2`, `created_at`, `updated_at`) VALUES
(404914, 14556, '18b', 'CH3', 20.6, 18002, NULL, NULL),
(404915, 14556, '19a', 'C', 168.9, 19001, NULL, NULL),
(404916, 14556, '19b', 'CH3', 21.5, 19002, NULL, NULL),
(404917, 14557, '1', 'CH2', 27.1, 1, NULL, NULL),
(404918, 14557, '2', 'CH', 66.5, 2, NULL, NULL),
(404919, 14557, '3', 'CH', 121.4, 3, NULL, NULL),
(404920, 14557, '4', 'C', 146.4, 4, NULL, NULL),
(404921, 14557, '5', 'C', 54.1, 5, NULL, NULL),
(404922, 14557, '6', 'CH', 72.8, 6, NULL, NULL),
(404923, 14557, '7', 'CH2', 36.8, 7, NULL, NULL),
(404924, 14557, '8', 'CH', 36.8, 8, NULL, NULL),
(404925, 14557, '9', 'C', 37.4, 9, NULL, NULL),
(404926, 14557, '10', 'CH', 37.1, 10, NULL, NULL),
(404927, 14557, '11', 'CH2', 28.3, 11, NULL, NULL),
(404928, 14557, '12', 'CH2', 24.2, 12, NULL, NULL),
(404929, 14557, '13', 'C', 145.6, 13, NULL, NULL),
(404930, 14557, '14', 'CH', 140.8, 14, NULL, NULL),
(404931, 14557, '15', 'CH2', 112.2, 15, NULL, NULL),
(404932, 14557, '16', 'CH2', 115.9, 16, NULL, NULL),
(404933, 14557, '17', 'CH3', 15.6, 17, NULL, NULL),
(404934, 14557, '18', 'CH', 96.1, 18, NULL, NULL),
(404935, 14557, '19', 'CH', 98.3, 19, NULL, NULL),
(404936, 14557, '20', 'CH3', 25.2, 20, NULL, NULL),
(404937, 14557, '2a', 'C', 172.4, 2001, NULL, NULL),
(404938, 14557, '2b', 'CH2', 36.2, 2002, NULL, NULL),
(404939, 14557, '2c', 'CH2', 18.8, 2003, NULL, NULL),
(404940, 14557, '2d', 'CH3', 13.5, 2004, NULL, NULL),
(404941, 14557, '18a', 'C', 169.6, 18001, NULL, NULL),
(404942, 14557, '18b', 'CH3', 20.7, 18002, NULL, NULL),
(404943, 14557, '19a', 'C', 169.1, 19001, NULL, NULL),
(404944, 14557, '19b', 'CH3', 21.5, 19002, NULL, NULL),
(404945, 14558, '1', 'CH2', 25.8, 1, NULL, NULL),
(404946, 14558, '2', 'CH', 64.5, 2, NULL, NULL),
(404947, 14558, '3', 'CH', 147.3, 3, NULL, NULL),
(404948, 14558, '4', 'C', 147.1, 4, NULL, NULL),
(404949, 14558, '5', 'C', 56.4, 5, NULL, NULL),
(404950, 14558, '6', 'CH', 74.8, 6, NULL, NULL),
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