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(282403, 9074, '1', 'CH', 50.5, 1, NULL, NULL),
(282404, 9074, '2', 'CH2', 22.8, 2, NULL, NULL),
(282405, 9074, '3', 'CH2', 40.1, 3, NULL, NULL),
(282406, 9074, '4', 'C', 78.8, 4, NULL, NULL),
(282407, 9074, '5', 'CH', 52.8, 5, NULL, NULL),
(282408, 9074, '6', 'CH', 72.1, 6, NULL, NULL),
(282409, 9074, '7', 'C', 85.7, 7, NULL, NULL),
(282410, 9074, '8', 'CH2', 30.3, 8, NULL, NULL),
(282411, 9074, '9', 'CH2', 31.4, 9, NULL, NULL),
(282412, 9074, '10', 'C', 83, 10, NULL, NULL),
(282413, 9074, '11', 'CH', 32.9, 11, NULL, NULL),
(282414, 9074, '12', 'CH3', 17.4, 12, NULL, NULL),
(282415, 9074, '13', 'CH3', 18.2, 13, NULL, NULL),
(282416, 9074, '14', 'CH3', 23.6, 14, NULL, NULL),
(282417, 9074, '15', 'CH3', 24.7, 15, NULL, NULL),
(282418, 9074, '6a', 'C', 170.7, 6001, NULL, NULL),
(282419, 9074, '6b', 'CH3', 21.5, 6002, NULL, NULL),
(282420, 9075, '1', 'CH', 57.7, 1, NULL, NULL),
(282421, 9075, '2', 'CH2', 24, 2, NULL, NULL),
(282422, 9075, '3', 'CH2', 39.1, 3, NULL, NULL),
(282423, 9075, '4', 'C', 133.6, 4, NULL, NULL),
(282424, 9075, '5', 'C', 133, 5, NULL, NULL),
(282425, 9075, '6', 'CH', 74, 6, NULL, NULL),
(282426, 9075, '7', 'C', 86.7, 7, NULL, NULL),
(282427, 9075, '8', 'CH2', 28.6, 8, NULL, NULL),
(282428, 9075, '9', 'CH2', 31.7, 9, NULL, NULL),
(282429, 9075, '10', 'C', 84.5, 10, NULL, NULL),
(282430, 9075, '11', 'CH', 31.8, 11, NULL, NULL),
(282431, 9075, '12', 'CH3', 17.3, 12, NULL, NULL),
(282432, 9075, '13', 'CH3', 18.2, 13, NULL, NULL),
(282433, 9075, '14', 'CH3', 24.1, 14, NULL, NULL),
(282434, 9075, '15', 'CH3', 14.7, 15, NULL, NULL),
(282435, 9076, '1', 'CH', 50.9, 1, NULL, NULL),
(282436, 9076, '2', 'CH2', 21.6, 2, NULL, NULL),
(282437, 9076, '3', 'CH2', 40.6, 3, NULL, NULL),
(282438, 9076, '4', 'C', 80.3, 4, NULL, NULL),
(282439, 9076, '5', 'CH', 50, 5, NULL, NULL),
(282440, 9076, '6', 'CH', 121.4, 6, NULL, NULL),
(282441, 9076, '7', 'C', 149.7, 7, NULL, NULL),
(282442, 9076, '8', 'CH2', 25.2, 8, NULL, NULL),
(282443, 9076, '9', 'CH2', 42.5, 9, NULL, NULL),
(282444, 9076, '10', 'C', 76.8, 10, NULL, NULL),
(282445, 9076, '11', 'CH', 37.3, 11, NULL, NULL),
(282446, 9076, '12', 'CH3', 21.2, 12, NULL, NULL),
(282447, 9076, '13', 'CH3', 21.5, 13, NULL, NULL),
(282448, 9076, '14', 'CH3', 21.5, 14, NULL, NULL),
(282449, 9076, '15', 'CH3', 22.7, 15, NULL, NULL),
(282450, 9077, '1', 'CH', 43.6, 1, NULL, NULL),
(282451, 9077, '2', 'CH2', 39.7, 2, NULL, NULL),
(282452, 9077, '3', 'C', 209.3, 3, NULL, NULL),
(282453, 9077, '4', 'C', 137.4, 4, NULL, NULL),
(282454, 9077, '5', 'C', 167.1, 5, NULL, NULL),
(282455, 9077, '6', 'CH', 118.2, 6, NULL, NULL),
(282456, 9077, '7', 'C', 160.4, 7, NULL, NULL),
(282457, 9077, '8', 'CH2', 26.5, 8, NULL, NULL),
(282458, 9077, '9', 'CH2', 35.1, 9, NULL, NULL),
(282459, 9077, '10', 'CH', 32.9, 10, NULL, NULL),
(282460, 9077, '11', 'C', 74.4, 11, NULL, NULL),
(282461, 9077, '12', 'CH3', 28.6, 12, NULL, NULL),
(282462, 9077, '13', 'CH3', 28.8, 13, NULL, NULL),
(282463, 9077, '14', 'CH3', 14.5, 14, NULL, NULL),
(282464, 9077, '15', 'CH3', 8.3, 15, NULL, NULL),
(282465, 9078, '1', 'C', 154.2, 1, NULL, NULL),
(282466, 9078, '2', 'C', 189.3, 2, NULL, NULL),
(282467, 9078, '3', 'C', 152.5, 3, NULL, NULL),
(282468, 9078, '4', 'C', 136.8, 4, NULL, NULL),
(282469, 9078, '5', 'CH', 47.4, 5, NULL, NULL),
(282470, 9078, '6', 'CH', 85.6, 6, NULL, NULL),
(282471, 9078, '7', 'CH', 55.8, 7, NULL, NULL),
(282472, 9078, '8', 'CH2', 25.2, 8, NULL, NULL),
(282473, 9078, '9', 'CH2', 37.3, 9, NULL, NULL),
(282474, 9078, '10', 'C', 128.7, 10, NULL, NULL),
(282475, 9078, '11', 'CH', 41.4, 11, NULL, NULL),
(282476, 9078, '12', 'C', 177.7, 12, NULL, NULL),
(282477, 9078, '13', 'CH3', 12.2, 13, NULL, NULL),
(282478, 9078, '14', 'CH3', 22, 14, NULL, NULL),
(282479, 9078, '15', 'CH3', 14, 15, NULL, NULL),
(282480, 9079, '1', 'C', 153, 1, NULL, NULL),
(282481, 9079, '2', 'C', 188.9, 2, NULL, NULL),
(282482, 9079, '3', 'C', 153.7, 3, NULL, NULL),
(282483, 9079, '4', 'C', 146.1, 4, NULL, NULL),
(282484, 9079, '5', 'CH', 52.4, 5, NULL, NULL),
(282485, 9079, '6', 'CH', 85.1, 6, NULL, NULL),
(282486, 9079, '7', 'CH', 47.9, 7, NULL, NULL),
(282487, 9079, '8', 'CH2', 24.1, 8, NULL, NULL),
(282488, 9079, '9', 'CH2', 36.9, 9, NULL, NULL),
(282489, 9079, '10', 'C', 124.6, 10, NULL, NULL),
(282490, 9079, '11', 'C', 139.5, 11, NULL, NULL),
(282491, 9079, '12', 'C', 169.1, 12, NULL, NULL),
(282492, 9079, '13', 'CH2', 117.9, 13, NULL, NULL),
(282493, 9079, '14', 'CH3', 21.7, 14, NULL, NULL),
(282494, 9079, '15', 'CH3', 14.9, 15, NULL, NULL),
(282495, 9079, '1''', 'CH', 101.6, 101, NULL, NULL),
(282496, 9079, '2''', 'CH', 75.3, 102, NULL, NULL),
(282497, 9079, '3''', 'CH', 78.3, 103, NULL, NULL),
(282498, 9079, '4''', 'CH', 71.1, 104, NULL, NULL),
(282499, 9079, '5''', 'CH', 78.3, 105, NULL, NULL),
(282500, 9079, '6''', 'CH2', 62.3, 106, NULL, NULL),
(282501, 9080, '1', 'C', 135, 1, NULL, NULL),
(282502, 9080, '2', 'CH', 106.5, 2, NULL, NULL),
(282503, 9080, '3', 'C', 147.2, 3, NULL, NULL),
(282504, 9080, '4', 'C', 148, 4, NULL, NULL),
(282505, 9080, '5', 'CH', 108.2, 5, NULL, NULL),
(282506, 9080, '6', 'CH', 119.6, 6, NULL, NULL),
(282507, 9080, '7', 'CH', 82.1, 7, NULL, NULL),
(282508, 9080, '8', 'CH', 50.1, 8, NULL, NULL),
(282509, 9080, '9', 'CH2', 71, 9, NULL, NULL),
(282510, 9080, '1''', 'C', 134.1, 101, NULL, NULL),
(282511, 9080, '2''', 'CH', 102.4, 102, NULL, NULL),
(282512, 9080, '3''', 'C', 153.2, 103, NULL, NULL),
(282513, 9080, '4''', 'C', 136.8, 104, NULL, NULL),
(282514, 9080, '5''', 'C', 153.2, 105, NULL, NULL),
(282515, 9080, '6''', 'CH', 102.4, 106, NULL, NULL),
(282516, 9080, '7''', 'CH', 87.6, 107, NULL, NULL),
(282517, 9080, '8''', 'CH', 54.5, 108, NULL, NULL),
(282518, 9080, '9''', 'CH2', 69.7, 109, NULL, NULL),
(282519, 9080, '1''''''', 'CH2', 60.9, 301, NULL, NULL),
(282520, 9080, '3''a', 'CH3', 56.1, 103001, NULL, NULL),
(282521, 9080, '4''a', 'CH3', 56.1, 104001, NULL, NULL),
(282522, 9080, '5''a', 'CH3', 101.1, 105001, NULL, NULL),
(282523, 9081, '1', 'C', 151.1, 1, NULL, NULL),
(282524, 9081, '2', 'CH', 126.3, 2, NULL, NULL),
(282525, 9081, '3', 'CH', 78.4, 3, NULL, NULL),
(282526, 9081, '4', 'C', 79.1, 4, NULL, NULL),
(282527, 9081, '5', 'CH', 57.3, 5, NULL, NULL);
INSERT INTO `carbons` (`id`, `molecularId`, `numeration`, `carbonType`, `shift`, `num2`, `created_at`, `updated_at`) VALUES
(282528, 9081, '6', 'CH', 76.5, 6, NULL, NULL),
(282529, 9081, '7', 'CH', 54.8, 7, NULL, NULL),
(282530, 9081, '8', 'CH', 71.7, 8, NULL, NULL),
(282531, 9081, '9', 'CH2', 45.2, 9, NULL, NULL),
(282532, 9081, '10', 'C', 68.6, 10, NULL, NULL),
(282533, 9081, '11', 'CH', 40.5, 11, NULL, NULL),
(282534, 9081, '12', 'C', 178.4, 12, NULL, NULL),
(282535, 9081, '13', 'CH3', 14.8, 13, NULL, NULL),
(282536, 9081, '14', 'CH3', 29.5, 14, NULL, NULL),
(282537, 9081, '15', 'CH3', 21.4, 15, NULL, NULL),
(282538, 9081, '8a', 'C', 169.6, 8001, NULL, NULL),
(282539, 9081, '8b', 'CH3', 21.1, 8002, NULL, NULL),
(282540, 9082, '1', 'C', 151.5, 1, NULL, NULL),
(282541, 9082, '2', 'CH', 126.7, 2, NULL, NULL),
(282542, 9082, '3', 'CH', 78.8, 3, NULL, NULL),
(282543, 9082, '4', 'C', 79.2, 4, NULL, NULL),
(282544, 9082, '5', 'CH', 58, 5, NULL, NULL),
(282545, 9082, '6', 'CH', 80.7, 6, NULL, NULL),
(282546, 9082, '7', 'CH', 52.4, 7, NULL, NULL),
(282547, 9082, '8', 'CH2', 22.9, 8, NULL, NULL),
(282548, 9082, '9', 'CH2', 38.7, 9, NULL, NULL),
(282549, 9082, '10', 'C', 69.6, 10, NULL, NULL),
(282550, 9082, '11', 'CH', 41, 11, NULL, NULL),
(282551, 9082, '12', 'C', 178.9, 12, NULL, NULL),
(282552, 9082, '13', 'CH3', 12.5, 13, NULL, NULL),
(282553, 9082, '14', 'CH3', 30, 14, NULL, NULL),
(282554, 9082, '15', 'CH3', 21.6, 15, NULL, NULL),
(282555, 9083, '1', 'C', 140.7, 1, NULL, NULL),
(282556, 9083, '2', 'CH', 129.3, 2, NULL, NULL),
(282557, 9083, '3', 'CH', 77.9, 3, NULL, NULL),
(282558, 9083, '4', 'C', 78.2, 4, NULL, NULL),
(282559, 9083, '5', 'CH', 57.8, 5, NULL, NULL),
(282560, 9083, '6', 'CH', 76.9, 6, NULL, NULL),
(282561, 9083, '7', 'CH', 52.4, 7, NULL, NULL),
(282562, 9083, '8', 'CH', 73.4, 8, NULL, NULL),
(282563, 9083, '9', 'CH', 133.3, 9, NULL, NULL),
(282564, 9083, '10', 'C', 130.2, 10, NULL, NULL),
(282565, 9083, '11', 'CH', 39.9, 11, NULL, NULL),
(282566, 9083, '12', 'C', 178.3, 12, NULL, NULL),
(282567, 9083, '13', 'CH3', 15.3, 13, NULL, NULL),
(282568, 9083, '14', 'CH3', 24.6, 14, NULL, NULL),
(282569, 9083, '15', 'CH3', 21.9, 15, NULL, NULL),
(282570, 9083, '8a', 'C', 168.9, 8001, NULL, NULL),
(282571, 9083, '8b', 'CH3', 21, 8002, NULL, NULL),
(282572, 9084, '1', 'C', 137.8, 1, NULL, NULL),
(282573, 9084, '2', 'CH', 75.9, 2, NULL, NULL),
(282574, 9084, '3', 'CH', 82.4, 3, NULL, NULL),
(282575, 9084, '4', 'C', 79.9, 4, NULL, NULL),
(282576, 9084, '5', 'CH', 56.7, 5, NULL, NULL),
(282577, 9084, '6', 'CH', 78.7, 6, NULL, NULL),
(282578, 9084, '7', 'CH', 53.6, 7, NULL, NULL),
(282579, 9084, '8', 'CH', 71.3, 8, NULL, NULL),
(282580, 9084, '9', 'CH2', 41.7, 9, NULL, NULL),
(282581, 9084, '10', 'C', 131.3, 10, NULL, NULL),
(282582, 9084, '11', 'CH', 39.8, 11, NULL, NULL),
(282583, 9084, '12', 'C', 178.1, 12, NULL, NULL),
(282584, 9084, '13', 'CH3', 15.2, 13, NULL, NULL),
(282585, 9084, '14', 'CH3', 23.2, 14, NULL, NULL),
(282586, 9084, '15', 'CH3', 21.8, 15, NULL, NULL),
(282587, 9084, '3a', 'C', 169.6, 3001, NULL, NULL),
(282588, 9084, '3b', 'CH3', 21, 3002, NULL, NULL),
(282589, 9085, '1', 'CH', 45.7, 1, NULL, NULL),
(282590, 9085, '2', 'CH2', 41.3, 2, NULL, NULL),
(282591, 9085, '3', 'C', 208.8, 3, NULL, NULL),
(282592, 9085, '4', 'C', 137.7, 4, NULL, NULL),
(282593, 9085, '5', 'C', 176.4, 5, NULL, NULL),
(282594, 9085, '6', 'CH2', 33.7, 6, NULL, NULL),
(282595, 9085, '7', 'CH', 41.9, 7, NULL, NULL),
(282596, 9085, '8', 'CH2', 27, 8, NULL, NULL),
(282597, 9085, '9', 'CH2', 36.7, 9, NULL, NULL),
(282598, 9085, '10', 'CH', 35.3, 10, NULL, NULL),
(282599, 9085, '11', 'C', 73.1, 11, NULL, NULL),
(282600, 9085, '12', 'CH3', 27.2, 12, NULL, NULL),
(282601, 9085, '13', 'CH3', 25.9, 13, NULL, NULL),
(282602, 9085, '14', 'CH3', 12.1, 14, NULL, NULL),
(282603, 9085, '15', 'CH3', 7.9, 15, NULL, NULL),
(282604, 9086, '1', 'C', 79.4, 1, NULL, NULL),
(282605, 9086, '2', 'CH2', 50.4, 2, NULL, NULL),
(282606, 9086, '3', 'C', 205.9, 3, NULL, NULL),
(282607, 9086, '4', 'C', 136.5, 4, NULL, NULL),
(282608, 9086, '5', 'C', 174.5, 5, NULL, NULL),
(282609, 9086, '6', 'CH2', 24.3, 6, NULL, NULL),
(282610, 9086, '7', 'CH', 45.1, 7, NULL, NULL),
(282611, 9086, '8', 'CH2', 27.3, 8, NULL, NULL),
(282612, 9086, '9', 'CH2', 27.1, 9, NULL, NULL),
(282613, 9086, '10', 'CH', 44.4, 10, NULL, NULL),
(282614, 9086, '11', 'C', 73.8, 11, NULL, NULL),
(282615, 9086, '12', 'CH3', 27.5, 12, NULL, NULL),
(282616, 9086, '13', 'CH3', 26.2, 13, NULL, NULL),
(282617, 9086, '14', 'CH3', 17.7, 14, NULL, NULL),
(282618, 9086, '15', 'CH3', 7.6, 15, NULL, NULL),
(282619, 9087, '1', 'CH', 42.9, 1, NULL, NULL),
(282620, 9087, '2', 'CH2', 40.4, 2, NULL, NULL),
(282621, 9087, '3', 'C', 210.5, 3, NULL, NULL),
(282622, 9087, '4', 'C', 139.2, 4, NULL, NULL),
(282623, 9087, '5', 'C', 173.9, 5, NULL, NULL),
(282624, 9087, '6', 'CH', 70, 6, NULL, NULL),
(282625, 9087, '7', 'CH', 53.1, 7, NULL, NULL),
(282626, 9087, '8', 'CH2', 21.9, 8, NULL, NULL),
(282627, 9087, '9', 'CH2', 34.2, 9, NULL, NULL),
(282628, 9087, '10', 'CH', 33.6, 10, NULL, NULL),
(282629, 9087, '11', 'C', 74, 11, NULL, NULL),
(282630, 9087, '12', 'CH3', 28.7, 12, NULL, NULL),
(282631, 9087, '13', 'CH3', 23.3, 13, NULL, NULL),
(282632, 9087, '14', 'CH3', 13.7, 14, NULL, NULL),
(282633, 9087, '15', 'CH3', 7.2, 15, NULL, NULL),
(282634, 9088, '1', 'C', 137.1, 1, NULL, NULL),
(282635, 9088, '2', 'C', 195.2, 2, NULL, NULL),
(282636, 9088, '3', 'CH', 136, 3, NULL, NULL),
(282637, 9088, '4', 'C', 171.5, 4, NULL, NULL),
(282638, 9088, '5', 'C', 91, 5, NULL, NULL),
(282639, 9088, '6', 'CH2', 33.4, 6, NULL, NULL),
(282640, 9088, '7', 'CH', 39, 7, NULL, NULL),
(282641, 9088, '8', 'CH2', 35.1, 8, NULL, NULL),
(282642, 9088, '9', 'CH2', 26, 9, NULL, NULL),
(282643, 9088, '10', 'C', 157.9, 10, NULL, NULL),
(282644, 9088, '11', 'C', 138.9, 11, NULL, NULL),
(282645, 9088, '12', 'C', 167.3, 12, NULL, NULL),
(282646, 9088, '13', 'CH2', 131, 13, NULL, NULL),
(282647, 9088, '14', 'CH2', 61.5, 14, NULL, NULL),
(282648, 9088, '15', 'CH3', 13, 15, NULL, NULL),
(282649, 9089, '1', 'C', 136.4, 1, NULL, NULL),
(282650, 9089, '2', 'C', 194.7, 2, NULL, NULL),
(282651, 9089, '3', 'CH', 134.7, 3, NULL, NULL),
(282652, 9089, '4', 'C', 170.6, 4, NULL, NULL),
(282653, 9089, '5', 'C', 89.9, 5, NULL, NULL),
(282654, 9089, '6', 'CH2', 32.6, 6, NULL, NULL),
(282655, 9089, '7', 'CH', 38.2, 7, NULL, NULL),
(282656, 9089, '8', 'CH2', 34.5, 8, NULL, NULL),
(282657, 9089, '9', 'CH2', 25.7, 9, NULL, NULL),
(282658, 9089, '10', 'C', 154.1, 10, NULL, NULL),
(282659, 9089, '11', 'C', 138.3, 11, NULL, NULL),
(282660, 9089, '12', 'C', 165.9, 12, NULL, NULL),
(282661, 9089, '13', 'CH2', 130.9, 13, NULL, NULL),
(282662, 9089, '14', 'CH2', 68.3, 14, NULL, NULL),
(282663, 9089, '15', 'CH3', 11.9, 15, NULL, NULL),
(282664, 9089, '1da', 'CH', 104.5, 1401, NULL, NULL),
(282665, 9089, '1db', 'CH', 74.5, 1402, NULL, NULL),
(282666, 9089, '1dc', 'CH', 78.3, 1403, NULL, NULL),
(282667, 9089, '1dd', 'CH', 71.5, 1404, NULL, NULL),
(282668, 9089, '1de', 'CH', 78.3, 1405, NULL, NULL),
(282669, 9089, '1df', 'CH2', 61.8, 1406, NULL, NULL),
(282670, 9090, '1', 'C', 137.5, 1, NULL, NULL),
(282671, 9090, '2', 'C', 194.7, 2, NULL, NULL),
(282672, 9090, '3', 'CH', 135.6, 3, NULL, NULL),
(282673, 9090, '4', 'C', 171.1, 4, NULL, NULL),
(282674, 9090, '5', 'C', 90.7, 5, NULL, NULL),
(282675, 9090, '6', 'CH2', 32.7, 6, NULL, NULL),
(282676, 9090, '7', 'CH', 38.6, 7, NULL, NULL),
(282677, 9090, '8', 'CH2', 34.4, 8, NULL, NULL),
(282678, 9090, '9', 'CH2', 25.8, 9, NULL, NULL),
(282679, 9090, '10', 'C', 154.6, 10, NULL, NULL),
(282680, 9090, '11', 'C', 138.7, 11, NULL, NULL),
(282681, 9090, '12', 'C', 166.9, 12, NULL, NULL),
(282682, 9090, '13', 'CH2', 130.5, 13, NULL, NULL),
(282683, 9090, '14', 'CH2', 68.3, 14, NULL, NULL),
(282684, 9090, '15', 'CH3', 12.7, 15, NULL, NULL),
(282685, 9090, '1''', 'CH', 104.7, 101, NULL, NULL),
(282686, 9090, '2''', 'CH', 76, 102, NULL, NULL),
(282687, 9090, '3''', 'CH', 75.7, 103, NULL, NULL),
(282688, 9090, '4''', 'CH', 72.7, 104, NULL, NULL),
(282689, 9090, '5''', 'CH', 75.3, 105, NULL, NULL),
(282690, 9090, '6''', 'CH2', 62.4, 106, NULL, NULL),
(282691, 9090, '1''''', 'C', 136.2, 201, NULL, NULL),
(282692, 9090, '2''''', 'C', 197.6, 202, NULL, NULL),
(282693, 9090, '3''''', 'CH', 131.8, 203, NULL, NULL),
(282694, 9090, '4''''', 'C', 177.7, 204, NULL, NULL),
(282695, 9090, '5''''', 'C', 79.9, 205, NULL, NULL),
(282696, 9090, '6''''', 'CH2', 40.4, 206, NULL, NULL),
(282697, 9090, '7''''', 'CH', 37.3, 207, NULL, NULL),
(282698, 9090, '8''''', 'CH2', 28.8, 208, NULL, NULL),
(282699, 9090, '9''''', 'CH2', 28.9, 209, NULL, NULL),
(282700, 9090, '10''''', 'C', 153.4, 210, NULL, NULL),
(282701, 9090, '11''''', 'C', 146.5, 211, NULL, NULL),
(282702, 9090, '12''''', 'C', 167.8, 212, NULL, NULL),
(282703, 9090, '13''''', 'CH2', 124.9, 213, NULL, NULL),
(282704, 9090, '14''''', 'CH2', 61.9, 214, NULL, NULL),
(282705, 9090, '15''''', 'CH3', 12.9, 215, NULL, NULL),
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