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(218562, 6253, '6a', 'C', 169.9, 6001, NULL, NULL),
(218563, 6253, '6b', 'CH3', 20.7, 6002, NULL, NULL),
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(218570, 6254, '7', 'CH', 80.8, 7, NULL, NULL),
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(218598, 6255, '11', 'CH2', 29, 11, NULL, NULL),
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(218601, 6255, '14', 'CH2', 26.8, 14, NULL, NULL),
(218602, 6255, '15', 'CH', 77.4, 15, NULL, NULL),
(218603, 6255, '16', 'C', 155.4, 16, NULL, NULL),
(218604, 6255, '17', 'CH2', 109.9, 17, NULL, NULL),
(218605, 6255, '18', 'CH3', 23.6, 18, NULL, NULL),
(218606, 6255, '19', 'C', 175.7, 19, NULL, NULL),
(218607, 6255, '20', 'CH2', 74.1, 20, NULL, NULL),
(218608, 6256, '1', 'CH2', 53.3, 1, NULL, NULL),
(218609, 6256, '2', 'CH2', 42.8, 2, NULL, NULL),
(218610, 6256, '3', 'CH2', 38.2, 3, NULL, NULL),
(218611, 6256, '4', 'C', 47.2, 4, NULL, NULL),
(218612, 6256, '5', 'CH', 47.9, 5, NULL, NULL),
(218613, 6256, '6', 'CH2', 23, 6, NULL, NULL),
(218614, 6256, '7', 'CH', 82.2, 7, NULL, NULL),
(218615, 6256, '8', 'C', 39.4, 8, NULL, NULL),
(218616, 6256, '9', 'CH', 39.3, 9, NULL, NULL),
(218617, 6256, '10', 'C', 34.4, 10, NULL, NULL),
(218618, 6256, '11', 'CH2', 22, 11, NULL, NULL),
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(218621, 6256, '14', 'CH2', 20.4, 14, NULL, NULL),
(218622, 6256, '15', 'CH', 71, 15, NULL, NULL),
(218623, 6256, '16', 'C', 70.3, 16, NULL, NULL),
(218624, 6256, '17', 'CH3', 31, 17, NULL, NULL),
(218625, 6256, '18', 'CH3', 27, 18, NULL, NULL),
(218626, 6256, '19', 'C', 174.7, 19, NULL, NULL),
(218627, 6256, '20', 'CH2', 76.3, 20, NULL, NULL),
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(218644, 6257, '17', 'CH', 55.7, 17, NULL, NULL),
(218645, 6257, '18', 'CH2', 65.7, 18, NULL, NULL),
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(218647, 6257, '20', 'C', 86.4, 20, NULL, NULL),
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(218649, 6257, '22', 'CH2', 36.8, 22, NULL, NULL),
(218650, 6257, '23', 'CH2', 24.6, 23, NULL, NULL),
(218651, 6257, '24', 'CH', 85.3, 24, NULL, NULL),
(218652, 6257, '25', 'C', 70.8, 25, NULL, NULL),
(218653, 6257, '26', 'CH3', 28.2, 26, NULL, NULL),
(218654, 6257, '27', 'CH3', 26.5, 27, NULL, NULL),
(218655, 6257, '28', 'CH3', 25.8, 28, NULL, NULL),
(218656, 6257, '29', 'CH3', 15.4, 29, NULL, NULL),
(218657, 6257, '30', 'CH3', 22.6, 30, NULL, NULL),
(218658, 6257, '1''', 'CH', 106.8, 101, NULL, NULL),
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(218661, 6257, '4''', 'CH', 71.9, 104, NULL, NULL),
(218662, 6257, '5''', 'CH', 78.8, 105, NULL, NULL),
(218663, 6257, '6''', 'CH2', 63.1, 106, NULL, NULL),
(218664, 6258, '1', 'CH2', 32.2, 1, NULL, NULL),
(218665, 6258, '2', 'CH2', 30, 2, NULL, NULL),
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(218673, 6258, '10', 'C', 26.5, 10, NULL, NULL),
(218674, 6258, '11', 'CH2', 26.7, 11, NULL, NULL),
(218675, 6258, '12', 'CH2', 29.1, 12, NULL, NULL),
(218676, 6258, '13', 'C', 51.7, 13, NULL, NULL),
(218677, 6258, '14', 'C', 46.9, 14, NULL, NULL),
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(218683, 6258, '20', 'C', 86.4, 20, NULL, NULL),
(218684, 6258, '21', 'CH3', 26, 21, NULL, NULL),
(218685, 6258, '22', 'CH2', 36.8, 22, NULL, NULL),
(218686, 6258, '23', 'CH2', 24.5, 23, NULL, NULL),
(218687, 6258, '24', 'CH', 85.2, 24, NULL, NULL),
(218688, 6258, '25', 'C', 70.8, 25, NULL, NULL),
(218689, 6258, '26', 'CH3', 28.2, 26, NULL, NULL),
(218690, 6258, '27', 'CH3', 26.4, 27, NULL, NULL),
(218691, 6258, '28', 'CH3', 25.7, 28, NULL, NULL),
(218692, 6258, '29', 'CH3', 15.4, 29, NULL, NULL),
(218693, 6258, '30', 'CH3', 22.6, 30, NULL, NULL),
(218694, 6258, '1''', 'CH', 106.7, 101, NULL, NULL),
(218695, 6258, '2''', 'CH', 75.6, 102, NULL, NULL),
(218696, 6258, '3''', 'CH', 78.3, 103, NULL, NULL),
(218697, 6258, '4''', 'CH', 71.7, 104, NULL, NULL),
(218698, 6258, '5''', 'CH', 77.1, 105, NULL, NULL),
(218699, 6258, '6''', 'CH2', 70.3, 106, NULL, NULL),
(218700, 6258, '1''''', 'CH', 105.3, 201, NULL, NULL),
(218701, 6258, '2''''', 'CH', 75.2, 202, NULL, NULL),
(218702, 6258, '3''''', 'CH', 78.5, 203, NULL, NULL),
(218703, 6258, '4''''', 'CH', 71.7, 204, NULL, NULL),
(218704, 6258, '5''''', 'CH', 78.3, 205, NULL, NULL),
(218705, 6258, '6''''', 'CH2', 62.8, 206, NULL, NULL),
(218706, 6259, '1', 'CH2', 32.2, 1, NULL, NULL),
(218707, 6259, '2', 'CH2', 30.3, 2, NULL, NULL),
(218708, 6259, '3', 'CH', 88.3, 3, NULL, NULL),
(218709, 6259, '4', 'C', 41.2, 4, NULL, NULL),
(218710, 6259, '5', 'CH', 46.8, 5, NULL, NULL),
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(218712, 6259, '7', 'CH2', 26.6, 7, NULL, NULL),
(218713, 6259, '8', 'CH', 47.4, 8, NULL, NULL),
(218714, 6259, '9', 'C', 19.8, 9, NULL, NULL),
(218715, 6259, '10', 'C', 26.2, 10, NULL, NULL),
(218716, 6259, '11', 'CH2', 26, 11, NULL, NULL),
(218717, 6259, '12', 'CH2', 29.6, 12, NULL, NULL),
(218718, 6259, '13', 'C', 52.7, 13, NULL, NULL),
(218719, 6259, '14', 'C', 48.6, 14, NULL, NULL),
(218720, 6259, '15', 'CH', 84.8, 15, NULL, NULL),
(218721, 6259, '16', 'CH', 79.2, 16, NULL, NULL),
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(218724, 6259, '19', 'CH2', 29.9, 19, NULL, NULL),
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(218731, 6259, '26', 'CH3', 27.6, 26, NULL, NULL),
(218732, 6259, '27', 'CH3', 28, 27, NULL, NULL),
(218733, 6259, '28', 'CH3', 25.7, 28, NULL, NULL),
(218734, 6259, '29', 'CH3', 15.3, 29, NULL, NULL),
(218735, 6259, '30', 'CH3', 14.3, 30, NULL, NULL),
(218736, 6259, '1''', 'CH', 107.3, 101, NULL, NULL),
(218737, 6259, '2''', 'CH', 75.3, 102, NULL, NULL),
(218738, 6259, '3''', 'CH', 78.4, 103, NULL, NULL),
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(218741, 6259, '15a', 'C', 171.5, 15001, NULL, NULL),
(218742, 6259, '15b', 'CH3', 21.7, 15002, NULL, NULL),
(218743, 6259, '16a', 'C', 170.8, 16001, NULL, NULL),
(218744, 6259, '16b', 'CH3', 21.4, 16002, NULL, NULL),
(218745, 6260, '1', 'CH2', 32.5, 1, NULL, NULL),
(218746, 6260, '2', 'CH2', 30.9, 2, NULL, NULL),
(218747, 6260, '3', 'CH', 88.5, 3, NULL, NULL),
(218748, 6260, '4', 'C', 41.4, 4, NULL, NULL),
(218749, 6260, '5', 'CH', 47.5, 5, NULL, NULL),
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(218751, 6260, '7', 'CH2', 26.6, 7, NULL, NULL),
(218752, 6260, '8', 'CH', 48.6, 8, NULL, NULL),
(218753, 6260, '9', 'C', 19.7, 9, NULL, NULL),
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(218756, 6260, '12', 'CH2', 28.3, 12, NULL, NULL),
(218757, 6260, '13', 'C', 46.3, 13, NULL, NULL),
(218758, 6260, '14', 'C', 51.4, 14, NULL, NULL),
(218759, 6260, '15', 'CH', 81.6, 15, NULL, NULL),
(218760, 6260, '16', 'CH', 78.5, 16, NULL, NULL),
(218761, 6260, '17', 'CH', 56.9, 17, NULL, NULL),
(218762, 6260, '18', 'CH2', 66.9, 18, NULL, NULL),
(218763, 6260, '19', 'CH2', 31.9, 19, NULL, NULL),
(218764, 6260, '20', 'C', 87, 20, NULL, NULL),
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(218766, 6260, '22', 'CH2', 38, 22, NULL, NULL),
(218767, 6260, '23', 'CH2', 30.1, 23, NULL, NULL);
INSERT INTO `carbons` (`id`, `molecularId`, `numeration`, `carbonType`, `shift`, `num2`, `created_at`, `updated_at`) VALUES
(218768, 6260, '24', 'C', 114.1, 24, NULL, NULL),
(218769, 6260, '25', 'C', 72.8, 25, NULL, NULL),
(218770, 6260, '26', 'CH3', 25.7, 26, NULL, NULL),
(218771, 6260, '27', 'CH3', 25.7, 27, NULL, NULL),
(218772, 6260, '28', 'CH3', 25.7, 28, NULL, NULL),
(218773, 6260, '29', 'CH3', 15.4, 29, NULL, NULL),
(218774, 6260, '30', 'CH3', 14.6, 30, NULL, NULL),
(218775, 6260, '1''', 'CH', 107.5, 101, NULL, NULL),
(218776, 6260, '2''', 'CH', 75.6, 102, NULL, NULL),
(218777, 6260, '3''', 'CH', 78.5, 103, NULL, NULL),
(218778, 6260, '4''', 'CH', 71.3, 104, NULL, NULL),
(218779, 6260, '5''', 'CH2', 67.1, 105, NULL, NULL),
(218780, 6260, '16a', 'C', 171, 16001, NULL, NULL),
(218781, 6260, '16b', 'CH3', 21.4, 16002, NULL, NULL),
(218782, 6261, '1', 'CH2', 32.5, 1, NULL, NULL),
(218783, 6261, '2', 'CH2', 30.9, 2, NULL, NULL),
(218784, 6261, '3', 'CH', 88.5, 3, NULL, NULL),
(218785, 6261, '4', 'C', 41.3, 4, NULL, NULL),
(218786, 6261, '5', 'CH', 47.6, 5, NULL, NULL),
(218787, 6261, '6', 'CH2', 20.9, 6, NULL, NULL),
(218788, 6261, '7', 'CH2', 26.8, 7, NULL, NULL),
(218789, 6261, '8', 'CH', 48.8, 8, NULL, NULL),
(218790, 6261, '9', 'C', 19.8, 9, NULL, NULL),
(218791, 6261, '10', 'C', 27.7, 10, NULL, NULL),
(218792, 6261, '11', 'CH2', 26.6, 11, NULL, NULL),
(218793, 6261, '12', 'CH2', 28.5, 12, NULL, NULL),
(218794, 6261, '13', 'C', -9999, 13, NULL, NULL),
(218795, 6261, '14', 'C', 50.8, 14, NULL, NULL),
(218796, 6261, '15', 'CH', 84.2, 15, NULL, NULL),
(218797, 6261, '16', 'CH', 76.8, 16, NULL, NULL),
(218798, 6261, '17', 'CH', 58.2, 17, NULL, NULL),
(218799, 6261, '18', 'CH2', 67, 18, NULL, NULL),
(218800, 6261, '19', 'CH2', 31.9, 19, NULL, NULL),
(218801, 6261, '20', 'C', 88.1, 20, NULL, NULL),
(218802, 6261, '21', 'CH3', 33.2, 21, NULL, NULL),
(218803, 6261, '22', 'CH2', 38.5, 22, NULL, NULL),
(218804, 6261, '23', 'CH2', 30.1, 23, NULL, NULL),
(218805, 6261, '24', 'C', 113.7, 24, NULL, NULL),
(218806, 6261, '25', 'C', 72.9, 25, NULL, NULL),
(218807, 6261, '26', 'CH3', 25.8, 26, NULL, NULL),
(218808, 6261, '27', 'CH3', 25.7, 27, NULL, NULL),
(218809, 6261, '28', 'CH3', 25.7, 28, NULL, NULL),
(218810, 6261, '29', 'CH3', 15.4, 29, NULL, NULL),
(218811, 6261, '30', 'CH3', 14.8, 30, NULL, NULL),
(218812, 6261, '1''', 'CH', 107.5, 101, NULL, NULL),
(218813, 6261, '2''', 'CH', 75.5, 102, NULL, NULL),
(218814, 6261, '3''', 'CH', 78.5, 103, NULL, NULL),
(218815, 6261, '4''', 'CH', 71.2, 104, NULL, NULL),
(218816, 6261, '5''', 'CH2', 67, 105, NULL, NULL),
(218817, 6262, '1', 'CH2', 32.1, 1, NULL, NULL),
(218818, 6262, '2', 'CH2', 30.9, 2, NULL, NULL),
(218819, 6262, '3', 'CH', 88.3, 3, NULL, NULL),
(218820, 6262, '4', 'C', 41.3, 4, NULL, NULL),
(218821, 6262, '5', 'CH', 47.4, 5, NULL, NULL),
(218822, 6262, '6', 'CH2', 20.5, 6, NULL, NULL),
(218823, 6262, '7', 'CH2', 26.5, 7, NULL, NULL),
(218824, 6262, '8', 'CH', 46.9, 8, NULL, NULL),
(218825, 6262, '9', 'C', 18.9, 9, NULL, NULL),
(218826, 6262, '10', 'C', 27.5, 10, NULL, NULL),
(218827, 6262, '11', 'CH2', 26.5, 11, NULL, NULL),
(218828, 6262, '12', 'CH2', 28.3, 12, NULL, NULL),
(218829, 6262, '13', 'C', 44.3, 13, NULL, NULL),
(218830, 6262, '14', 'C', 52.6, 14, NULL, NULL),
(218831, 6262, '15', 'CH2', 43, 15, NULL, NULL),
(218832, 6262, '16', 'CH', 73.2, 16, NULL, NULL),
(218833, 6262, '17', 'CH', 59.3, 17, NULL, NULL),
(218834, 6262, '18', 'CH2', 66.7, 18, NULL, NULL),
(218835, 6262, '19', 'CH2', 31.1, 19, NULL, NULL),
(218836, 6262, '20', 'C', 87.2, 20, NULL, NULL),
(218837, 6262, '21', 'CH3', 32.6, 21, NULL, NULL),
(218838, 6262, '22', 'CH2', 37.8, 22, NULL, NULL),
(218839, 6262, '23', 'CH2', 30, 23, NULL, NULL),
(218840, 6262, '24', 'C', 114.1, 24, NULL, NULL),
(218841, 6262, '25', 'C', 72.8, 25, NULL, NULL),
(218842, 6262, '26', 'CH3', 25.7, 26, NULL, NULL),
(218843, 6262, '27', 'CH3', 25.7, 27, NULL, NULL),
(218844, 6262, '28', 'CH3', 25.8, 28, NULL, NULL),
(218845, 6262, '29', 'CH3', 15.4, 29, NULL, NULL),
(218846, 6262, '30', 'CH3', 22.2, 30, NULL, NULL),
(218847, 6262, '1''', 'CH', 107.6, 101, NULL, NULL),
(218848, 6262, '2''', 'CH', 75.6, 102, NULL, NULL),
(218849, 6262, '3''', 'CH', 78.6, 103, NULL, NULL),
(218850, 6262, '4''', 'CH', 71.2, 104, NULL, NULL),
(218851, 6262, '5''', 'CH2', 67.1, 105, NULL, NULL),
(218852, 6262, '16a', 'C', 170.3, 16001, NULL, NULL),
(218853, 6262, '16b', 'CH3', 21.4, 16002, NULL, NULL),
(218854, 6263, '1', 'CH2', 32.4, 1, NULL, NULL),
(218855, 6263, '2', 'CH2', 30.1, 2, NULL, NULL),
(218856, 6263, '3', 'CH', 88.5, 3, NULL, NULL),
(218857, 6263, '4', 'C', 41.3, 4, NULL, NULL),
(218858, 6263, '5', 'CH', 47.5, 5, NULL, NULL),
(218859, 6263, '6', 'CH2', 21.1, 6, NULL, NULL),
(218860, 6263, '7', 'CH2', 26.1, 7, NULL, NULL),
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