INSERT INTO `carbons` (`id`, `molecularId`, `numeration`, `carbonType`, `shift`, `num2`, `created_at`, `updated_at`) VALUES
(155915, 3721, '18', 'C', 51.1, 18, NULL, NULL),
(155916, 3721, '19', 'CH2', 20.2, 19, NULL, NULL),
(155917, 3721, '20', 'CH2', 28, 20, NULL, NULL),
(155918, 3721, '21', 'CH', 59.6, 21, NULL, NULL),
(155919, 3721, '22', 'CH', 30.6, 22, NULL, NULL),
(155920, 3721, '23', 'CH3', 27.4, 23, NULL, NULL),
(155921, 3721, '24', 'CH3', 15, 24, NULL, NULL),
(155922, 3721, '25', 'CH3', 20, 25, NULL, NULL),
(155923, 3721, '26', 'CH3', 23.7, 26, NULL, NULL),
(155924, 3721, '27', 'CH3', 16.9, 27, NULL, NULL),
(155925, 3721, '28', 'CH3', 14.6, 28, NULL, NULL),
(155926, 3721, '29', 'CH3', 22.8, 29, NULL, NULL),
(155927, 3721, '30', 'CH3', 21.9, 30, NULL, NULL),
(155928, 3722, '1', 'CH2', 34.4, 1, NULL, NULL),
(155929, 3722, '2', 'CH2', 27.4, 2, NULL, NULL),
(155930, 3722, '3', 'CH', 78.1, 3, NULL, NULL),
(155931, 3722, '4', 'C', 38.6, 4, NULL, NULL),
(155932, 3722, '5', 'CH', 48, 5, NULL, NULL),
(155933, 3722, '6', 'CH2', 36.7, 6, NULL, NULL),
(155934, 3722, '7', 'C', 199.9, 7, NULL, NULL),
(155935, 3722, '8', 'C', 151.9, 8, NULL, NULL),
(155936, 3722, '9', 'C', 156, 9, NULL, NULL),
(155937, 3722, '10', 'C', 38.2, 10, NULL, NULL),
(155938, 3722, '11', 'C', 201.1, 11, NULL, NULL),
(155939, 3722, '12', 'CH2', 51.1, 12, NULL, NULL),
(155940, 3722, '13', 'C', 38.5, 13, NULL, NULL),
(155941, 3722, '14', 'C', 41.6, 14, NULL, NULL),
(155942, 3722, '15', 'CH2', 26.4, 15, NULL, NULL),
(155943, 3722, '16', 'CH2', 35.8, 16, NULL, NULL),
(155944, 3722, '17', 'C', 42.6, 17, NULL, NULL),
(155945, 3722, '18', 'C', 50.8, 18, NULL, NULL),
(155946, 3722, '19', 'CH2', 20.4, 19, NULL, NULL),
(155947, 3722, '20', 'CH2', 28.9, 20, NULL, NULL),
(155948, 3722, '21', 'CH', 59.5, 21, NULL, NULL),
(155949, 3722, '22', 'CH', 30.7, 22, NULL, NULL),
(155950, 3722, '23', 'CH3', 27.5, 23, NULL, NULL),
(155951, 3722, '24', 'CH3', 14.9, 24, NULL, NULL),
(155952, 3722, '25', 'CH3', 17.9, 25, NULL, NULL),
(155953, 3722, '26', 'CH3', 21.8, 26, NULL, NULL),
(155954, 3722, '27', 'CH3', 20.8, 27, NULL, NULL),
(155955, 3722, '28', 'CH3', 14, 28, NULL, NULL),
(155956, 3722, '29', 'CH3', 22.9, 29, NULL, NULL),
(155957, 3722, '30', 'CH3', 22, 30, NULL, NULL),
(155958, 3723, '1', 'CH2', 41.5, 1, NULL, NULL),
(155959, 3723, '2', 'CH2', 19.6, 2, NULL, NULL),
(155960, 3723, '3', 'CH2', 42.5, 3, NULL, NULL),
(155961, 3723, '4', 'C', 33.6, 4, NULL, NULL),
(155962, 3723, '5', 'CH', 44.9, 5, NULL, NULL),
(155963, 3723, '6', 'CH2', 18, 6, NULL, NULL),
(155964, 3723, '7', 'CH2', 19.6, 7, NULL, NULL),
(155965, 3723, '8', 'CH', 40, 8, NULL, NULL),
(155966, 3723, '9', 'C', 151.7, 9, NULL, NULL),
(155967, 3723, '10', 'C', 37.7, 10, NULL, NULL),
(155968, 3723, '11', 'CH', 115.7, 11, NULL, NULL),
(155969, 3723, '12', 'CH2', 36.8, 12, NULL, NULL),
(155970, 3723, '13', 'C', 36.8, 13, NULL, NULL),
(155971, 3723, '14', 'C', 38.1, 14, NULL, NULL),
(155972, 3723, '15', 'CH2', 29.4, 15, NULL, NULL),
(155973, 3723, '16', 'CH2', 36.3, 16, NULL, NULL),
(155974, 3723, '17', 'C', 43, 17, NULL, NULL),
(155975, 3723, '18', 'CH', 52.1, 18, NULL, NULL),
(155976, 3723, '19', 'CH2', 20.2, 19, NULL, NULL),
(155977, 3723, '20', 'CH2', 28.3, 20, NULL, NULL),
(155978, 3723, '21', 'CH', 59.7, 21, NULL, NULL),
(155979, 3723, '22', 'CH', 30.8, 22, NULL, NULL),
(155980, 3723, '23', 'CH3', 32.8, 23, NULL, NULL),
(155981, 3723, '24', 'CH3', 21.7, 24, NULL, NULL),
(155982, 3723, '25', 'CH3', 25.1, 25, NULL, NULL),
(155983, 3723, '26', 'CH3', 15.9, 26, NULL, NULL),
(155984, 3723, '27', 'CH3', 15.4, 27, NULL, NULL),
(155985, 3723, '28', 'CH3', 14, 28, NULL, NULL),
(155986, 3723, '29', 'CH3', 22.2, 29, NULL, NULL),
(155987, 3723, '30', 'CH3', 23, 30, NULL, NULL),
(155988, 3724, '1', 'CH2', 40.5, 1, NULL, NULL),
(155989, 3724, '2', 'CH2', 20.6, 2, NULL, NULL),
(155990, 3724, '3', 'CH2', 42.2, 3, NULL, NULL),
(155991, 3724, '4', 'C', 34.1, 4, NULL, NULL),
(155992, 3724, '5', 'CH', 45.9, 5, NULL, NULL),
(155993, 3724, '6', 'CH2', 20.7, 6, NULL, NULL),
(155994, 3724, '7', 'CH2', 18.9, 7, NULL, NULL),
(155995, 3724, '8', 'CH', 39.5, 8, NULL, NULL),
(155996, 3724, '9', 'C', 142.9, 9, NULL, NULL),
(155997, 3724, '10', 'C', 48.5, 10, NULL, NULL),
(155998, 3724, '11', 'CH', 121.2, 11, NULL, NULL),
(155999, 3724, '12', 'CH2', 36.6, 12, NULL, NULL),
(156000, 3724, '13', 'C', 36.7, 13, NULL, NULL),
(156001, 3724, '14', 'C', 38, 14, NULL, NULL),
(156002, 3724, '15', 'CH2', 29.3, 15, NULL, NULL),
(156003, 3724, '16', 'CH2', 36, 16, NULL, NULL),
(156004, 3724, '17', 'C', 42.9, 17, NULL, NULL),
(156005, 3724, '18', 'CH', 51.9, 18, NULL, NULL),
(156006, 3724, '19', 'CH2', 20.1, 19, NULL, NULL),
(156007, 3724, '20', 'CH2', 28.2, 20, NULL, NULL),
(156008, 3724, '21', 'CH', 59.6, 21, NULL, NULL),
(156009, 3724, '22', 'CH', 30.8, 22, NULL, NULL),
(156010, 3724, '23', 'CH3', 31.4, 23, NULL, NULL),
(156011, 3724, '24', 'CH3', 19.8, 24, NULL, NULL),
(156012, 3724, '25', 'C', 176.1, 25, NULL, NULL),
(156013, 3724, '26', 'CH3', 15.6, 26, NULL, NULL),
(156014, 3724, '27', 'CH3', 15.5, 27, NULL, NULL),
(156015, 3724, '28', 'CH3', 14, 28, NULL, NULL),
(156016, 3724, '29', 'CH3', 22.1, 29, NULL, NULL),
(156017, 3724, '30', 'CH3', 23, 30, NULL, NULL),
(156018, 3725, '1', 'CH2', 39.1, 1, NULL, NULL),
(156019, 3725, '2', 'CH2', 28, 2, NULL, NULL),
(156020, 3725, '3', 'CH', 79, 3, NULL, NULL),
(156021, 3725, '4', 'C', 39.3, 4, NULL, NULL),
(156022, 3725, '5', 'CH', 44.1, 5, NULL, NULL),
(156023, 3725, '6', 'CH2', 19, 6, NULL, NULL),
(156024, 3725, '7', 'CH2', 17.8, 7, NULL, NULL),
(156025, 3725, '8', 'CH', 39.8, 8, NULL, NULL),
(156026, 3725, '9', 'C', 153.4, 9, NULL, NULL),
(156027, 3725, '10', 'C', 40.6, 10, NULL, NULL),
(156028, 3725, '11', 'CH', 120.9, 11, NULL, NULL),
(156029, 3725, '12', 'CH', 75.9, 12, NULL, NULL),
(156030, 3725, '13', 'C', 42.2, 13, NULL, NULL),
(156031, 3725, '14', 'C', 37.6, 14, NULL, NULL),
(156032, 3725, '15', 'CH2', 29.5, 15, NULL, NULL),
(156033, 3725, '16', 'CH2', 35.9, 16, NULL, NULL),
(156034, 3725, '17', 'C', 43.6, 17, NULL, NULL),
(156035, 3725, '18', 'CH', 51.4, 18, NULL, NULL),
(156036, 3725, '19', 'CH2', 23.6, 19, NULL, NULL),
(156037, 3725, '20', 'CH2', 28.7, 20, NULL, NULL),
(156038, 3725, '21', 'CH', 58.9, 21, NULL, NULL),
(156039, 3725, '22', 'CH', 30.8, 22, NULL, NULL),
(156040, 3725, '23', 'CH3', 27.5, 23, NULL, NULL),
(156041, 3725, '24', 'CH3', 15.7, 24, NULL, NULL),
(156042, 3725, '25', 'CH3', 25.1, 25, NULL, NULL),
(156043, 3725, '26', 'CH3', 15.1, 26, NULL, NULL),
(156044, 3725, '27', 'CH3', 11.3, 27, NULL, NULL),
(156045, 3725, '28', 'CH3', 14.2, 28, NULL, NULL),
(156046, 3725, '29', 'CH3', 22.2, 29, NULL, NULL),
(156047, 3725, '30', 'CH3', 23.1, 30, NULL, NULL),
(156048, 3726, '1', 'CH2', 36.3, 1, NULL, NULL),
(156049, 3726, '2', 'CH2', 28, 2, NULL, NULL),
(156050, 3726, '3', 'CH', 71.4, 3, NULL, NULL),
(156051, 3726, '4', 'C', 36.9, 4, NULL, NULL),
(156052, 3726, '5', 'CH', 52, 5, NULL, NULL),
(156053, 3726, '6', 'CH2', 36.4, 6, NULL, NULL),
(156054, 3726, '7', 'CH', 75.1, 7, NULL, NULL),
(156055, 3726, '8', 'CH', 47.9, 8, NULL, NULL),
(156056, 3726, '9', 'C', 117, 9, NULL, NULL),
(156057, 3726, '10', 'C', 39.2, 10, NULL, NULL),
(156058, 3726, '11', 'CH', 121.1, 11, NULL, NULL),
(156059, 3726, '12', 'CH2', 24.5, 12, NULL, NULL),
(156060, 3726, '13', 'C', 43.9, 13, NULL, NULL),
(156061, 3726, '14', 'C', 57, 14, NULL, NULL),
(156062, 3726, '15', 'CH2', 33, 15, NULL, NULL),
(156063, 3726, '16', 'CH2', 31.9, 16, NULL, NULL),
(156064, 3726, '17', 'C', 40.9, 17, NULL, NULL),
(156065, 3726, '18', 'CH', 39.4, 18, NULL, NULL),
(156066, 3726, '19', 'CH', 74.5, 19, NULL, NULL),
(156067, 3726, '20', 'CH2', 30.3, 20, NULL, NULL),
(156068, 3726, '21', 'CH', 57.3, 21, NULL, NULL),
(156069, 3726, '22', 'CH', 27.8, 22, NULL, NULL),
(156070, 3726, '23', 'CH3', 21.9, 23, NULL, NULL),
(156071, 3726, '24', 'CH3', 15.4, 24, NULL, NULL),
(156072, 3726, '25', 'CH3', 22.9, 25, NULL, NULL),
(156073, 3726, '26', 'CH3', 15.5, 26, NULL, NULL),
(156074, 3726, '27', 'CH3', 21.7, 27, NULL, NULL),
(156075, 3726, '28', 'CH3', 16.8, 28, NULL, NULL),
(156076, 3726, '29', 'CH3', 16.1, 29, NULL, NULL),
(156077, 3726, '30', 'CH3', 16.5, 30, NULL, NULL),
(156078, 3727, '1', 'CH2', 46.9, 1, NULL, NULL),
(156079, 3727, '2', 'CH', 68.7, 2, NULL, NULL),
(156080, 3727, '3', 'CH', 79.9, 3, NULL, NULL),
(156081, 3727, '4', 'C', 53, 4, NULL, NULL),
(156082, 3727, '5', 'CH', 41.8, 5, NULL, NULL),
(156083, 3727, '6', 'CH2', 20.2, 6, NULL, NULL),
(156084, 3727, '7', 'CH2', 17.6, 7, NULL, NULL),
(156085, 3727, '8', 'CH', 39.6, 8, NULL, NULL),
(156086, 3727, '9', 'C', 149.6, 9, NULL, NULL),
(156087, 3727, '10', 'C', 39.3, 10, NULL, NULL),
(156088, 3727, '11', 'CH', 117.3, 11, NULL, NULL),
(156089, 3727, '12', 'CH2', 36.7, 12, NULL, NULL),
(156090, 3727, '13', 'C', 36.8, 13, NULL, NULL),
(156091, 3727, '14', 'C', 37.8, 14, NULL, NULL),
(156092, 3727, '15', 'CH2', 29.3, 15, NULL, NULL),
(156093, 3727, '16', 'CH2', 36.2, 16, NULL, NULL),
(156094, 3727, '17', 'C', 43, 17, NULL, NULL),
(156095, 3727, '18', 'CH', 52, 18, NULL, NULL),
(156096, 3727, '19', 'CH2', 20.2, 19, NULL, NULL),
(156097, 3727, '20', 'CH2', 28.2, 20, NULL, NULL),
(156098, 3727, '21', 'CH', 59.7, 21, NULL, NULL),
(156099, 3727, '22', 'CH', 30.8, 22, NULL, NULL),
(156100, 3727, '23', 'C', 177.1, 23, NULL, NULL),
(156101, 3727, '24', 'CH3', 11.8, 24, NULL, NULL),
(156102, 3727, '25', 'CH3', 26.6, 25, NULL, NULL),
(156103, 3727, '26', 'CH3', 16, 26, NULL, NULL),
(156104, 3727, '27', 'CH3', 15.4, 27, NULL, NULL),
(156105, 3727, '28', 'CH3', 14, 28, NULL, NULL),
(156106, 3727, '29', 'CH3', 22.2, 29, NULL, NULL),
(156107, 3727, '30', 'CH3', 23, 30, NULL, NULL),
(156108, 3727, '23a', 'CH3', -9999, 23001, NULL, NULL),
(156109, 3728, '1', 'CH2', 23.8, 1, NULL, NULL),
(156110, 3728, '2', 'CH2', 21.9, 2, NULL, NULL),
(156111, 3728, '3', 'CH2', 40.9, 3, NULL, NULL),
(156112, 3728, '4', 'C', 34.8, 4, NULL, NULL),
(156113, 3728, '5', 'C', 145.6, 5, NULL, NULL),
(156114, 3728, '6', 'CH', 117.6, 6, NULL, NULL),
(156115, 3728, '7', 'CH2', 34.3, 7, NULL, NULL),
(156116, 3728, '8', 'CH', 51.8, 8, NULL, NULL),
(156117, 3728, '9', 'C', 35.7, 9, NULL, NULL),
(156118, 3728, '10', 'CH', 44.3, 10, NULL, NULL),
(156119, 3728, '11', 'CH2', 25.9, 11, NULL, NULL),
(156120, 3728, '12', 'CH2', 29.2, 12, NULL, NULL),
(156121, 3728, '13', 'C', 38.7, 13, NULL, NULL),
(156122, 3728, '14', 'C', 39.4, 14, NULL, NULL),
(156123, 3728, '15', 'CH2', 29.2, 15, NULL, NULL),
(156124, 3728, '16', 'CH2', 35.5, 16, NULL, NULL),
(156125, 3728, '17', 'C', 42.9, 17, NULL, NULL),
(156126, 3728, '18', 'CH', 51.9, 18, NULL, NULL),
(156127, 3728, '19', 'CH2', 20, 19, NULL, NULL),
(156128, 3728, '20', 'CH2', 28.4, 20, NULL, NULL),
(156129, 3728, '21', 'CH', 60.1, 21, NULL, NULL),
(156130, 3728, '22', 'CH', 30.8, 22, NULL, NULL),
(156131, 3728, '23', 'CH3', 30, 23, NULL, NULL),
(156132, 3728, '24', 'CH3', 29.8, 24, NULL, NULL),
(156133, 3728, '25', 'CH3', 16.1, 25, NULL, NULL),
(156134, 3728, '26', 'CH3', 17.9, 26, NULL, NULL),
(156135, 3728, '27', 'CH3', 15.1, 27, NULL, NULL),
(156136, 3728, '28', 'CH3', 15.8, 28, NULL, NULL),
(156137, 3728, '29', 'CH3', 22, 29, NULL, NULL),
(156138, 3728, '30', 'CH3', 22.9, 30, NULL, NULL),
(156139, 3729, '1', 'CH2', 23.8, 1, NULL, NULL),
(156140, 3729, '2', 'CH2', 21.8, 2, NULL, NULL),
(156141, 3729, '3', 'CH2', 40.8, 3, NULL, NULL),
(156142, 3729, '4', 'C', 34.9, 4, NULL, NULL),
(156143, 3729, '5', 'C', 145.4, 5, NULL, NULL),
(156144, 3729, '6', 'CH', 117.4, 6, NULL, NULL),
(156145, 3729, '7', 'CH2', 34.6, 7, NULL, NULL),
(156146, 3729, '8', 'CH', 51.5, 8, NULL, NULL),
(156147, 3729, '9', 'C', 35.7, 9, NULL, NULL),
(156148, 3729, '10', 'CH', 44.3, 10, NULL, NULL),
(156149, 3729, '11', 'CH2', 26, 11, NULL, NULL),
(156150, 3729, '12', 'CH2', 28.2, 12, NULL, NULL),
(156151, 3729, '13', 'C', 38.8, 13, NULL, NULL),
(156152, 3729, '14', 'C', 39.3, 14, NULL, NULL),
(156153, 3729, '15', 'CH2', 29.9, 15, NULL, NULL),
(156154, 3729, '16', 'CH2', 30.9, 16, NULL, NULL),
(156155, 3729, '17', 'C', 54.1, 17, NULL, NULL),
(156156, 3729, '18', 'CH', 54, 18, NULL, NULL),
(156157, 3729, '19', 'CH2', 21.8, 19, NULL, NULL),
(156158, 3729, '20', 'CH2', 31.8, 20, NULL, NULL),
(156159, 3729, '21', 'CH', 60.7, 21, NULL, NULL),
(156160, 3729, '22', 'CH', 31.7, 22, NULL, NULL),
(156161, 3729, '23', 'CH3', 29.8, 23, NULL, NULL),
(156162, 3729, '24', 'CH3', 29.7, 24, NULL, NULL),
(156163, 3729, '25', 'CH3', 16.2, 25, NULL, NULL),
(156164, 3729, '26', 'CH3', 17.6, 26, NULL, NULL),
(156165, 3729, '27', 'CH3', 13.6, 27, NULL, NULL),
(156166, 3729, '28', 'C', 176.8, 28, NULL, NULL),
(156167, 3729, '29', 'CH3', 22.1, 29, NULL, NULL),
(156168, 3729, '30', 'CH3', 22.9, 30, NULL, NULL),
(156169, 3729, '28a', 'CH3', -9999, 28001, NULL, NULL),
(156170, 3730, '1', 'CH2', 36.6, 1, NULL, NULL),
(156171, 3730, '2', 'CH2', 34.8, 2, NULL, NULL),
(156172, 3730, '3', 'C', 217.1, 3, NULL, NULL),
(156173, 3730, '4', 'C', 47.6, 4, NULL, NULL),
(156174, 3730, '5', 'CH', 53.2, 5, NULL, NULL),
(156175, 3730, '6', 'CH2', 26.3, 6, NULL, NULL),
(156176, 3730, '7', 'CH2', 22.6, 7, NULL, NULL),
(156177, 3730, '8', 'CH', 41, 8, NULL, NULL),
(156178, 3730, '9', 'C', 147.4, 9, NULL, NULL),
(156179, 3730, '10', 'C', 39.3, 10, NULL, NULL),
(156180, 3730, '11', 'CH', 115.6, 11, NULL, NULL),
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(156189, 3730, '20', 'CH2', 28.2, 20, NULL, NULL),
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(156198, 3730, '29', 'CH3', 22.1, 29, NULL, NULL),
(156199, 3730, '30', 'CH3', 23, 30, NULL, NULL),
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(156201, 3731, '2', 'CH', 74.1, 2, NULL, NULL),
(156202, 3731, '3', 'CH', 79.5, 3, NULL, NULL),
(156203, 3731, '4', 'C', 40.2, 4, NULL, NULL),
(156204, 3731, '5', 'CH', 48.9, 5, NULL, NULL),
(156205, 3731, '6', 'CH2', 33.8, 6, NULL, NULL),
(156206, 3731, '7', 'CH2', 71.9, 7, NULL, NULL),
(156207, 3731, '8', 'CH', 49.1, 8, NULL, NULL),
(156208, 3731, '9', 'C', 146.6, 9, NULL, NULL),
(156209, 3731, '10', 'C', 41, 10, NULL, NULL),
(156210, 3731, '11', 'CH', 117.5, 11, NULL, NULL),
(156211, 3731, '12', 'CH2', 37.2, 12, NULL, NULL),
(156212, 3731, '13', 'C', 38.3, 13, NULL, NULL),
(156213, 3731, '14', 'C', 39.9, 14, NULL, NULL),
(156214, 3731, '15', 'CH2', 32.1, 15, NULL, NULL),
(156215, 3731, '16', 'CH2', 37.2, 16, NULL, NULL),
(156216, 3731, '17', 'C', 43.8, 17, NULL, NULL),
(156217, 3731, '18', 'CH', 59.2, 18, NULL, NULL),
(156218, 3731, '19', 'CH', 70.3, 19, NULL, NULL),
(156219, 3731, '20', 'CH2', 41.9, 20, NULL, NULL),
(156220, 3731, '21', 'CH', 57.8, 21, NULL, NULL),
(156221, 3731, '22', 'CH', 30.7, 22, NULL, NULL),
(156222, 3731, '23', 'CH3', 29, 23, NULL, NULL),
(156223, 3731, '24', 'CH3', 17.4, 24, NULL, NULL),
(156224, 3731, '25', 'CH3', 22.6, 25, NULL, NULL),
(156225, 3731, '26', 'CH3', 17.1, 26, NULL, NULL),
(156226, 3731, '27', 'CH3', 17, 27, NULL, NULL),
(156227, 3731, '28', 'CH3', 15.9, 28, NULL, NULL),
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