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(343690, 11923, '8', 'CH', 49.1, 8, NULL, NULL),
(343691, 11923, '9', 'C', 39, 9, NULL, NULL),
(343692, 11923, '10', 'CH', 37.9, 10, NULL, NULL),
(343693, 11923, '11', 'CH', 76.4, 11, NULL, NULL),
(343694, 11923, '12', 'CH', 71.5, 12, NULL, NULL),
(343695, 11923, '13', 'C', 121.6, 13, NULL, NULL),
(343696, 11923, '14', 'CH', 108.6, 14, NULL, NULL),
(343697, 11923, '15', 'CH', 144, 15, NULL, NULL),
(343698, 11923, '16', 'CH', 141.4, 16, NULL, NULL),
(343699, 11923, '17', 'C', 175.4, 17, NULL, NULL),
(343700, 11923, '18', 'C', 169.5, 18, NULL, NULL),
(343701, 11923, '19', 'CH2', 70, 19, NULL, NULL),
(343702, 11923, '20', 'CH3', 19, 20, NULL, NULL),
(343703, 11923, '11a', 'C', 169, 11001, NULL, NULL),
(343704, 11923, '11b', 'CH3', 20.7, 11002, NULL, NULL),
(343705, 11924, '1', 'CH', 66.5, 1, NULL, NULL),
(343706, 11924, '2', 'CH', 128.8, 2, NULL, NULL),
(343707, 11924, '3', 'CH', 122.3, 3, NULL, NULL),
(343708, 11924, '4', 'CH', 51.3, 4, NULL, NULL),
(343709, 11924, '5', 'C', 42.4, 5, NULL, NULL),
(343710, 11924, '6', 'CH2', 31.5, 6, NULL, NULL),
(343711, 11924, '7', 'CH2', 19.5, 7, NULL, NULL),
(343712, 11924, '8', 'CH', 49.7, 8, NULL, NULL),
(343713, 11924, '9', 'C', 39.9, 9, NULL, NULL),
(343714, 11924, '10', 'CH', 41.4, 10, NULL, NULL),
(343715, 11924, '11', 'CH', 76, 11, NULL, NULL),
(343716, 11924, '12', 'CH', 71.1, 12, NULL, NULL),
(343717, 11924, '13', 'C', 134.5, 13, NULL, NULL),
(343718, 11924, '14', 'CH', 148.6, 14, NULL, NULL),
(343719, 11924, '15', 'CH', 97.2, 15, NULL, NULL),
(343720, 11924, '16', 'C', 168.7, 16, NULL, NULL),
(343721, 11924, '17', 'C', 169.2, 17, NULL, NULL),
(343722, 11924, '18', 'C', 174.2, 18, NULL, NULL),
(343723, 11924, '19', 'CH2', 70.6, 19, NULL, NULL),
(343724, 11924, '20', 'CH3', 20.2, 20, NULL, NULL),
(343725, 11924, '1a', 'C', 170.8, 1001, NULL, NULL),
(343726, 11924, '1b', 'CH3', 19.2, 1002, NULL, NULL),
(343727, 11924, '11a', 'C', 170.8, 11001, NULL, NULL),
(343728, 11924, '11b', 'CH3', 21.8, 11002, NULL, NULL),
(343729, 11925, '1', 'CH2', 18.9, 1, NULL, NULL),
(343730, 11925, '2', 'CH', 128.8, 2, NULL, NULL),
(343731, 11925, '3', 'CH', 121.2, 3, NULL, NULL),
(343732, 11925, '4', 'CH', 52.1, 4, NULL, NULL),
(343733, 11925, '5', 'C', 41.4, 5, NULL, NULL),
(343734, 11925, '6', 'CH2', 32.4, 6, NULL, NULL),
(343735, 11925, '7', 'CH2', 21.9, 7, NULL, NULL),
(343736, 11925, '8', 'CH', 49, 8, NULL, NULL),
(343737, 11925, '9', 'C', 35.1, 9, NULL, NULL),
(343738, 11925, '10', 'CH', 38.2, 10, NULL, NULL),
(343739, 11925, '11', 'CH2', 40.8, 11, NULL, NULL),
(343740, 11925, '12', 'CH', 70.5, 12, NULL, NULL),
(343741, 11925, '13', 'C', 124.7, 13, NULL, NULL),
(343742, 11925, '14', 'CH', 108.3, 14, NULL, NULL),
(343743, 11925, '15', 'CH', 143.8, 15, NULL, NULL),
(343744, 11925, '16', 'CH', 139.6, 16, NULL, NULL),
(343745, 11925, '17', 'C', 175.4, 17, NULL, NULL),
(343746, 11925, '18', 'C', 171.4, 18, NULL, NULL),
(343747, 11925, '19', 'CH2', 70, 19, NULL, NULL),
(343748, 11925, '20', 'CH3', 23.7, 20, NULL, NULL),
(343749, 11926, '1', 'CH', 66.8, 1, NULL, NULL),
(343750, 11926, '2', 'CH', 128.7, 2, NULL, NULL),
(343751, 11926, '3', 'CH', 122.1, 3, NULL, NULL),
(343752, 11926, '4', 'CH', 51.2, 4, NULL, NULL),
(343753, 11926, '5', 'C', 42.4, 5, NULL, NULL),
(343754, 11926, '6', 'CH2', 31.7, 6, NULL, NULL),
(343755, 11926, '7', 'CH2', 29, 7, NULL, NULL),
(343756, 11926, '8', 'CH', 50.2, 8, NULL, NULL),
(343757, 11926, '9', 'C', 39.9, 9, NULL, NULL),
(343758, 11926, '10', 'CH', 41.4, 10, NULL, NULL),
(343759, 11926, '11', 'CH', 76, 11, NULL, NULL),
(343760, 11926, '12', 'CH', 71.2, 12, NULL, NULL),
(343761, 11926, '13', 'C', 121.5, 13, NULL, NULL),
(343762, 11926, '14', 'CH', 108.6, 14, NULL, NULL),
(343763, 11926, '15', 'CH', 144.3, 15, NULL, NULL),
(343764, 11926, '16', 'CH', 141.8, 16, NULL, NULL),
(343765, 11926, '17', 'C', 169.2, 17, NULL, NULL),
(343766, 11926, '18', 'C', 174.1, 18, NULL, NULL),
(343767, 11926, '19', 'CH2', 70.4, 19, NULL, NULL),
(343768, 11926, '20', 'CH3', 19, 20, NULL, NULL),
(343769, 11926, '1a', 'C', 170.1, 1001, NULL, NULL),
(343770, 11926, '1b', 'CH3', 21.8, 1002, NULL, NULL),
(343771, 11926, '11a', 'C', 169.8, 11001, NULL, NULL),
(343772, 11926, '11b', 'CH3', 19.9, 11002, NULL, NULL),
(343773, 11927, '1', 'CH2', 17.7, 1, NULL, NULL),
(343774, 11927, '2', 'CH2', 26.6, 2, NULL, NULL),
(343775, 11927, '3', 'CH', 122.3, 3, NULL, NULL),
(343776, 11927, '4', 'C', 143.7, 4, NULL, NULL),
(343777, 11927, '5', 'C', 44, 5, NULL, NULL),
(343778, 11927, '6', 'CH', 75.6, 6, NULL, NULL),
(343779, 11927, '7', 'CH2', 37.8, 7, NULL, NULL),
(343780, 11927, '8', 'CH', 34.4, 8, NULL, NULL);
INSERT INTO `carbons` (`id`, `molecularId`, `numeration`, `carbonType`, `shift`, `num2`, `created_at`, `updated_at`) VALUES
(343781, 11927, '9', 'C', 38, 9, NULL, NULL),
(343782, 11927, '10', 'CH', 45.4, 10, NULL, NULL),
(343783, 11927, '11', 'CH2', 31.8, 11, NULL, NULL),
(343784, 11927, '12', 'CH2', 35, 12, NULL, NULL),
(343785, 11927, '13', 'C', 73.4, 13, NULL, NULL),
(343786, 11927, '14', 'CH', 145.1, 14, NULL, NULL),
(343787, 11927, '15', 'CH2', 112, 15, NULL, NULL),
(343788, 11927, '16', 'CH3', 27.9, 16, NULL, NULL),
(343789, 11927, '17', 'CH3', 15.5, 17, NULL, NULL),
(343790, 11927, '18', 'CH3', 22.4, 18, NULL, NULL),
(343791, 11927, '19', 'CH3', 14.9, 19, NULL, NULL),
(343792, 11927, '20', 'CH3', 18, 20, NULL, NULL),
(343793, 11928, '1', 'CH2', 18.1, 1, NULL, NULL),
(343794, 11928, '2', 'CH2', 26.9, 2, NULL, NULL),
(343795, 11928, '3', 'CH', 123.2, 3, NULL, NULL),
(343796, 11928, '4', 'C', 143.5, 4, NULL, NULL),
(343797, 11928, '5', 'C', 44.2, 5, NULL, NULL),
(343798, 11928, '6', 'CH', 86.6, 6, NULL, NULL),
(343799, 11928, '7', 'CH2', 35.3, 7, NULL, NULL),
(343800, 11928, '8', 'CH', 34.4, 8, NULL, NULL),
(343801, 11928, '9', 'C', 38.3, 9, NULL, NULL),
(343802, 11928, '10', 'CH', 45.9, 10, NULL, NULL),
(343803, 11928, '11', 'CH2', 32.2, 11, NULL, NULL),
(343804, 11928, '12', 'CH2', 35.3, 12, NULL, NULL),
(343805, 11928, '13', 'C', 80.6, 13, NULL, NULL),
(343806, 11928, '14', 'CH', 144.7, 14, NULL, NULL),
(343807, 11928, '15', 'CH2', 115.1, 15, NULL, NULL),
(343808, 11928, '16', 'CH3', 22.9, 16, NULL, NULL),
(343809, 11928, '17', 'CH3', 16, 17, NULL, NULL),
(343810, 11928, '18', 'CH3', 22.9, 18, NULL, NULL),
(343811, 11928, '19', 'CH3', 16.3, 19, NULL, NULL),
(343812, 11928, '20', 'CH3', 18.1, 20, NULL, NULL),
(343813, 11928, '1''', 'CH', 103.2, 101, NULL, NULL),
(343814, 11928, '2''', 'CH', 72.3, 102, NULL, NULL),
(343815, 11928, '3''', 'CH', 72.6, 103, NULL, NULL),
(343816, 11928, '4''', 'CH', 84.7, 104, NULL, NULL),
(343817, 11928, '5''', 'CH', 68.4, 105, NULL, NULL),
(343818, 11928, '6''', 'CH3', 18.1, 106, NULL, NULL),
(343819, 11928, '1''''', 'CH', 106.5, 201, NULL, NULL),
(343820, 11928, '2''''', 'CH', 76.3, 202, NULL, NULL),
(343821, 11928, '3''''', 'CH', 78.3, 203, NULL, NULL),
(343822, 11928, '4''''', 'CH', 71.5, 204, NULL, NULL),
(343823, 11928, '5''''', 'CH', 78.3, 205, NULL, NULL),
(343824, 11928, '6''''', 'CH2', 62.7, 206, NULL, NULL),
(343825, 11928, '1''''''', 'CH', 99.9, 301, NULL, NULL),
(343826, 11928, '2''''''', 'CH', 72.3, 302, NULL, NULL),
(343827, 11928, '3''''''', 'CH', 76, 303, NULL, NULL),
(343828, 11928, '4''''''', 'CH', 78.3, 304, NULL, NULL),
(343829, 11928, '5''''''', 'CH', 70.7, 305, NULL, NULL),
(343830, 11928, '6''''''', 'CH3', 18, 306, NULL, NULL),
(343831, 11928, '1''''''''', 'CH', 103.2, 401, NULL, NULL),
(343832, 11928, '2''''''''', 'CH', 72.3, 402, NULL, NULL),
(343833, 11928, '3''''''''', 'CH', 72.6, 403, NULL, NULL),
(343834, 11928, '4''''''''', 'CH', 73.8, 404, NULL, NULL),
(343835, 11928, '5''''''''', 'CH', 70.2, 405, NULL, NULL),
(343836, 11928, '6''''''''', 'CH3', 18.4, 406, NULL, NULL),
(343837, 11929, '1', 'CH2', 18.2, 1, NULL, NULL),
(343838, 11929, '2', 'CH2', 27.2, 2, NULL, NULL),
(343839, 11929, '3', 'CH', 122.2, 3, NULL, NULL),
(343840, 11929, '4', 'C', 145.2, 4, NULL, NULL),
(343841, 11929, '5', 'C', 44.7, 5, NULL, NULL),
(343842, 11929, '6', 'CH', 85.7, 6, NULL, NULL),
(343843, 11929, '7', 'CH2', 35.8, 7, NULL, NULL),
(343844, 11929, '8', 'CH', 34.6, 8, NULL, NULL),
(343845, 11929, '9', 'C', 38.3, 9, NULL, NULL),
(343846, 11929, '10', 'CH', 46.3, 10, NULL, NULL),
(343847, 11929, '11', 'CH2', 32.2, 11, NULL, NULL),
(343848, 11929, '12', 'CH2', 35.3, 12, NULL, NULL),
(343849, 11929, '13', 'C', 79.8, 13, NULL, NULL),
(343850, 11929, '14', 'CH', 143.2, 14, NULL, NULL),
(343851, 11929, '15', 'CH2', 115.2, 15, NULL, NULL),
(343852, 11929, '16', 'CH3', 23, 16, NULL, NULL),
(343853, 11929, '17', 'CH3', 16, 17, NULL, NULL),
(343854, 11929, '18', 'CH3', 24, 18, NULL, NULL),
(343855, 11929, '19', 'CH3', 16.9, 19, NULL, NULL),
(343856, 11929, '20', 'CH3', 18.3, 20, NULL, NULL),
(343857, 11929, '1''', 'CH', 104.5, 101, NULL, NULL),
(343858, 11929, '2''', 'CH', 75.4, 102, NULL, NULL),
(343859, 11929, '3''', 'CH', 79.3, 103, NULL, NULL),
(343860, 11929, '4''', 'CH', 72.9, 104, NULL, NULL),
(343861, 11929, '5''', 'CH', 78.3, 105, NULL, NULL),
(343862, 11929, '6''', 'CH2', 63.1, 106, NULL, NULL),
(343863, 11929, '1''''', 'CH', 95.8, 201, NULL, NULL),
(343864, 11929, '2''''', 'CH', 83.1, 202, NULL, NULL),
(343865, 11929, '3''''', 'CH', 72.9, 203, NULL, NULL),
(343866, 11929, '4''''', 'CH', 75.7, 204, NULL, NULL),
(343867, 11929, '5''''', 'CH', 69.4, 205, NULL, NULL),
(343868, 11929, '6''''', 'CH3', 18.5, 206, NULL, NULL),
(343869, 11929, '1''''''', 'CH', 107.5, 301, NULL, NULL),
(343870, 11929, '2''''''', 'CH', 72, 302, NULL, NULL),
(343871, 11929, '3''''''', 'CH', 74.7, 303, NULL, NULL),
(343872, 11929, '4''''''', 'CH', 72.8, 304, NULL, NULL),
(343873, 11929, '5''''''', 'CH', 71.7, 305, NULL, NULL),
(343874, 11929, '6''''''', 'CH3', 17.3, 306, NULL, NULL),
(343875, 11930, '1', 'CH2', 28.3, 1, NULL, NULL),
(343876, 11930, '2', 'CH', 67, 2, NULL, NULL),
(343877, 11930, '3', 'CH2', 36.7, 3, NULL, NULL),
(343878, 11930, '4', 'C', 60.4, 4, NULL, NULL),
(343879, 11930, '5', 'C', 41.5, 5, NULL, NULL),
(343880, 11930, '6', 'CH', 68.2, 6, NULL, NULL),
(343881, 11930, '7', 'CH2', 31.3, 7, NULL, NULL),
(343882, 11930, '8', 'CH', 34.6, 8, NULL, NULL),
(343883, 11930, '9', 'C', 41.6, 9, NULL, NULL),
(343884, 11930, '10', 'CH', 41.7, 10, NULL, NULL),
(343885, 11930, '11', 'CH', 83.6, 11, NULL, NULL),
(343886, 11930, '12', 'CH2', 32.3, 12, NULL, NULL),
(343887, 11930, '13', 'CH', 42.4, 13, NULL, NULL),
(343888, 11930, '14', 'CH2', 33.6, 14, NULL, NULL),
(343889, 11930, '15', 'CH2', 66.1, 15, NULL, NULL),
(343890, 11930, '16', 'CH', 107.7, 16, NULL, NULL),
(343891, 11930, '17', 'CH3', 17.3, 17, NULL, NULL),
(343892, 11930, '18', 'CH2', 50.1, 18, NULL, NULL),
(343893, 11930, '19', 'CH', 91.2, 19, NULL, NULL),
(343894, 11930, '20', 'CH3', 12.2, 20, NULL, NULL),
(343895, 11930, '6a', 'C', 169.9, 6001, NULL, NULL),
(343896, 11930, '6b', 'CH3', 20.9, 6002, NULL, NULL),
(343897, 11930, '19a', 'C', 166.2, 19001, NULL, NULL),
(343898, 11930, '19b', 'C', 128.4, 19002, NULL, NULL),
(343899, 11930, '19c', 'CH', 138.4, 19003, NULL, NULL),
(343900, 11930, '19d', 'CH3', 14.5, 19004, NULL, NULL),
(343901, 11930, '19ba', 'CH3', 11.8, 19201, NULL, NULL),
(343902, 11931, '1', 'CH2', 28.4, 1, NULL, NULL),
(343903, 11931, '2', 'CH', 67.2, 2, NULL, NULL),
(343904, 11931, '3', 'CH2', 36.9, 3, NULL, NULL),
(343905, 11931, '4', 'C', 60.6, 4, NULL, NULL),
(343906, 11931, '5', 'C', 41.4, 5, NULL, NULL),
(343907, 11931, '6', 'CH', 68.3, 6, NULL, NULL),
(343908, 11931, '7', 'CH2', 32.6, 7, NULL, NULL),
(343909, 11931, '8', 'CH', 35.1, 8, NULL, NULL),
(343910, 11931, '9', 'C', 41.6, 9, NULL, NULL),
(343911, 11931, '10', 'CH', 40.8, 10, NULL, NULL),
(343912, 11931, '11', 'CH', 86, 11, NULL, NULL),
(343913, 11931, '12', 'CH2', 33.1, 12, NULL, NULL),
(343914, 11931, '13', 'CH', 41.8, 13, NULL, NULL),
(343915, 11931, '14', 'CH2', 33.5, 14, NULL, NULL),
(343916, 11931, '15', 'CH2', 68.3, 15, NULL, NULL),
(343917, 11931, '16', 'CH', 108.2, 16, NULL, NULL),
(343918, 11931, '17', 'CH3', 16.7, 17, NULL, NULL),
(343919, 11931, '18', 'CH2', 50.2, 18, NULL, NULL),
(343920, 11931, '19', 'CH', 91.4, 19, NULL, NULL),
(343921, 11931, '20', 'CH3', 14, 20, NULL, NULL),
(343922, 11931, '6a', 'C', 170, 6001, NULL, NULL),
(343923, 11931, '6b', 'CH3', 21, 6002, NULL, NULL),
(343924, 11931, '19a', 'C', 166.3, 19001, NULL, NULL),
(343925, 11931, '19b', 'C', 128.4, 19002, NULL, NULL),
(343926, 11931, '19c', 'CH', 138.4, 19003, NULL, NULL),
(343927, 11931, '19d', 'CH3', 14.5, 19004, NULL, NULL),
(343928, 11931, '19ba', 'CH3', 11.9, 19201, NULL, NULL),
(343929, 11932, '2', 'C', 163.9, 2, NULL, NULL),
(343930, 11932, '3', 'CH', 104.4, 3, NULL, NULL),
(343931, 11932, '4', 'C', 182.6, 4, NULL, NULL),
(343932, 11932, '5', 'C', 153.2, 5, NULL, NULL),
(343933, 11932, '6', 'C', 132.6, 6, NULL, NULL),
(343934, 11932, '7', 'C', 158.7, 7, NULL, NULL),
(343935, 11932, '8', 'CH', 90.6, 8, NULL, NULL),
(343936, 11932, '9', 'C', 153.1, 9, NULL, NULL),
(343937, 11932, '10', 'C', 106.1, 10, NULL, NULL),
(343938, 11932, '1''', 'C', 123.7, 101, NULL, NULL),
(343939, 11932, '2''', 'CH', 108.7, 102, NULL, NULL),
(343940, 11932, '3''', 'C', 149.3, 103, NULL, NULL),
(343941, 11932, '4''', 'C', 152.3, 104, NULL, NULL),
(343942, 11932, '5''', 'CH', 111.1, 105, NULL, NULL),
(343943, 11932, '6''', 'CH', 120.1, 106, NULL, NULL),
(343944, 11932, '6a', 'CH3', 60.8, 6001, NULL, NULL),
(343945, 11932, '7a', 'CH3', 56.3, 7001, NULL, NULL),
(343946, 11932, '3''a', 'CH3', 56.1, 103001, NULL, NULL),
(343947, 11932, '4''a', 'CH3', 56.1, 104001, NULL, NULL),
(343948, 11933, '2', 'C', 162.8, 2, NULL, NULL),
(343949, 11933, '3', 'CH', 102.9, 3, NULL, NULL),
(343950, 11933, '4', 'C', 181.4, 4, NULL, NULL),
(343951, 11933, '5', 'C', 145.5, 5, NULL, NULL),
(343952, 11933, '6', 'C', 129.3, 6, NULL, NULL),
(343953, 11933, '7', 'C', 153.1, 7, NULL, NULL),
(343954, 11933, '8', 'CH', 89.7, 8, NULL, NULL),
(343955, 11933, '9', 'C', 149.2, 9, NULL, NULL),
(343956, 11933, '10', 'C', 104.7, 10, NULL, NULL),
(343957, 11933, '1''', 'C', 122.8, 101, NULL, NULL),
(343958, 11933, '2''', 'CH', 108.2, 102, NULL, NULL),
(343959, 11933, '3''', 'C', 148.3, 103, NULL, NULL),
(343960, 11933, '4''', 'C', 151.2, 104, NULL, NULL),
(343961, 11933, '5''', 'CH', 110.5, 105, NULL, NULL),
(343962, 11933, '6''', 'CH', 119, 106, NULL, NULL),
(343963, 11933, '7a', 'CH3', 55.3, 7001, NULL, NULL),
(343964, 11933, '3''a', 'CH3', 55.1, 103001, NULL, NULL),
(343965, 11933, '4''a', 'CH3', 55, 104001, NULL, NULL),
(343966, 11934, '2', 'C', 163.4, 2, NULL, NULL),
(343967, 11934, '3', 'CH', 102.4, 3, NULL, NULL),
(343968, 11934, '4', 'C', 181.6, 4, NULL, NULL),
(343969, 11934, '5', 'C', 145.6, 5, NULL, NULL),
(343970, 11934, '6', 'C', 129.3, 6, NULL, NULL),
(343971, 11934, '7', 'C', 153.1, 7, NULL, NULL),
(343972, 11934, '8', 'CH', 89.8, 8, NULL, NULL),
(343973, 11934, '9', 'C', 149.3, 9, NULL, NULL),
(343974, 11934, '10', 'C', 104.8, 10, NULL, NULL),
(343975, 11934, '1''', 'C', 121.6, 101, NULL, NULL),
(343976, 11934, '2''', 'CH', 108.7, 102, NULL, NULL),
(343977, 11934, '3''', 'C', 147.2, 103, NULL, NULL),
(343978, 11934, '4''', 'C', 149.7, 104, NULL, NULL),
(343979, 11934, '5''', 'CH', 115.1, 105, NULL, NULL),
(343980, 11934, '6''', 'CH', 119.5, 106, NULL, NULL),
(343981, 11934, '7a', 'CH3', 55.4, 7001, NULL, NULL),
(343982, 11934, '3''a', 'CH3', 55.3, 103001, NULL, NULL),
(343983, 11935, '2', 'C', 161.9, 2, NULL, NULL),
(343984, 11935, '3', 'CH', 107.2, 3, NULL, NULL),
(343985, 11935, '4', 'C', 176.6, 4, NULL, NULL),
(343986, 11935, '5', 'C', 139.6, 5, NULL, NULL),
(343987, 11935, '6', 'C', 142.2, 6, NULL, NULL),
(343988, 11935, '7', 'C', 157.7, 7, NULL, NULL),
(343989, 11935, '8', 'CH', 98.2, 8, NULL, NULL),
(343990, 11935, '9', 'C', 154.1, 9, NULL, NULL),
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