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(143280, 3311, '21', 'CH2', 23, 21, NULL, NULL),
(143281, 3311, '22', 'CH2', 39.7, 22, NULL, NULL),
(143282, 3311, '23', 'CH3', 28, 23, NULL, NULL),
(143283, 3311, '24', 'CH3', 16.6, 24, NULL, NULL);
INSERT INTO `carbons` (`id`, `molecularId`, `numeration`, `carbonType`, `shift`, `num2`, `created_at`, `updated_at`) VALUES
(143284, 3311, '25', 'CH3', 16.2, 25, NULL, NULL),
(143285, 3311, '26', 'CH3', 16, 26, NULL, NULL),
(143286, 3311, '27', 'CH3', 14.4, 27, NULL, NULL),
(143287, 3311, '28', 'CH3', 17.8, 28, NULL, NULL),
(143288, 3311, '29', 'C', -9999, 29, NULL, NULL),
(143289, 3311, '30', 'CH3', 17.2, 30, NULL, NULL),
(143290, 3311, '3a', '', 171, 3001, NULL, NULL),
(143291, 3311, '3b', '', 21.3, 3002, NULL, NULL),
(143292, 3312, '1', 'CH2', 38.1, 1, NULL, NULL),
(143293, 3312, '2', 'CH2', 23.4, 2, NULL, NULL),
(143294, 3312, '3', 'CH', 80.3, 3, NULL, NULL),
(143295, 3312, '4', 'C', 37.4, 4, NULL, NULL),
(143296, 3312, '5', 'CH', 55, 5, NULL, NULL),
(143297, 3312, '6', 'CH2', 17.8, 6, NULL, NULL),
(143298, 3312, '7', 'CH2', 33.8, 7, NULL, NULL),
(143299, 3312, '8', 'C', 40.7, 8, NULL, NULL),
(143300, 3312, '9', 'CH', 49.4, 9, NULL, NULL),
(143301, 3312, '10', 'C', 36.7, 10, NULL, NULL),
(143302, 3312, '11', 'CH2', 20.4, 11, NULL, NULL),
(143303, 3312, '12', 'CH2', 24.5, 12, NULL, NULL),
(143304, 3312, '13', 'CH', 36.5, 13, NULL, NULL),
(143305, 3312, '14', 'C', 43.9, 14, NULL, NULL),
(143306, 3312, '15', 'CH2', 33.6, 15, NULL, NULL),
(143307, 3312, '16', 'CH', 77.9, 16, NULL, NULL),
(143308, 3312, '17', 'C', 50.1, 17, NULL, NULL),
(143309, 3312, '18', 'CH', 48.1, 18, NULL, NULL),
(143310, 3312, '19', 'CH', 47.1, 19, NULL, NULL),
(143311, 3312, '20', 'C', 148.6, 20, NULL, NULL),
(143312, 3312, '21', 'CH2', 29.8, 21, NULL, NULL),
(143313, 3312, '22', 'CH2', 32.7, 22, NULL, NULL),
(143314, 3312, '23', 'CH3', 27.6, 23, NULL, NULL),
(143315, 3312, '24', 'CH3', 16.2, 24, NULL, NULL),
(143316, 3312, '25', 'CH3', 15.9, 25, NULL, NULL),
(143317, 3312, '26', 'CH3', 15.9, 26, NULL, NULL),
(143318, 3312, '27', 'CH3', 15.5, 27, NULL, NULL),
(143319, 3312, '28', 'CH2', 61.1, 28, NULL, NULL),
(143320, 3312, '29', 'CH2', 110, 29, NULL, NULL),
(143321, 3312, '30', 'CH3', 19, 30, NULL, NULL),
(143322, 3312, '3a', 'C', 170.4, 3001, NULL, NULL),
(143323, 3312, '3b', 'CH3', 21, 3002, NULL, NULL),
(143324, 3312, '16a', 'C', 170.4, 16001, NULL, NULL),
(143325, 3312, '16b', 'CH3', 21, 16002, NULL, NULL),
(143326, 3312, '28a', 'C', 170.4, 28001, NULL, NULL),
(143327, 3312, '28b', 'CH3', 21, 28002, NULL, NULL),
(143328, 3313, '1', 'CH', 66.6, 1, NULL, NULL),
(143329, 3313, '2', 'CH2', 36.2, 2, NULL, NULL),
(143330, 3313, '3', 'CH', 75.1, 3, NULL, NULL),
(143331, 3313, '4', 'C', 40, 4, NULL, NULL),
(143332, 3313, '5', 'CH', 58.2, 5, NULL, NULL),
(143333, 3313, '6', 'CH2', 18.8, 6, NULL, NULL),
(143334, 3313, '7', 'CH2', 35.8, 7, NULL, NULL),
(143335, 3313, '8', 'C', 42.7, 8, NULL, NULL),
(143336, 3313, '9', 'CH', 53.5, 9, NULL, NULL),
(143337, 3313, '10', 'C', 46.3, 10, NULL, NULL),
(143338, 3313, '11', 'CH', 76.5, 11, NULL, NULL),
(143339, 3313, '12', 'CH2', 35.1, 12, NULL, NULL),
(143340, 3313, '13', 'CH', 36.2, 13, NULL, NULL),
(143341, 3313, '14', 'C', 43.1, 14, NULL, NULL),
(143342, 3313, '15', 'CH2', 30.2, 15, NULL, NULL),
(143343, 3313, '16', 'CH2', 37.9, 16, NULL, NULL),
(143344, 3313, '17', 'C', 43.2, 17, NULL, NULL),
(143345, 3313, '18', 'CH', 48.7, 18, NULL, NULL),
(143346, 3313, '19', 'CH', 48.2, 19, NULL, NULL),
(143347, 3313, '20', 'C', 150.6, 20, NULL, NULL),
(143348, 3313, '21', 'CH2', 28, 21, NULL, NULL),
(143349, 3313, '22', 'CH2', 40.1, 22, NULL, NULL),
(143350, 3313, '23', 'CH3', 28.7, 23, NULL, NULL),
(143351, 3313, '24', 'CH3', 14.4, 24, NULL, NULL),
(143352, 3313, '25', 'CH3', 15.7, 25, NULL, NULL),
(143353, 3313, '26', 'CH3', 17.7, 26, NULL, NULL),
(143354, 3313, '27', 'CH3', 14.2, 27, NULL, NULL),
(143355, 3313, '28', 'CH3', 18.3, 28, NULL, NULL),
(143356, 3313, '29', 'CH2', 110.3, 29, NULL, NULL),
(143357, 3313, '30', 'CH3', 19.4, 30, NULL, NULL),
(143358, 3314, '1', 'CH2', 38.8, 1, NULL, NULL),
(143359, 3314, '2', 'CH2', 27.5, 2, NULL, NULL),
(143360, 3314, '3', 'CH', 78.7, 3, NULL, NULL),
(143361, 3314, '4', 'C', 38.6, 4, NULL, NULL),
(143362, 3314, '5', 'CH', 52.1, 5, NULL, NULL),
(143363, 3314, '6', 'CH2', 28.3, 6, NULL, NULL),
(143364, 3314, '7', 'CH', 72.7, 7, NULL, NULL),
(143365, 3314, '8', 'C', 47.9, 8, NULL, NULL),
(143366, 3314, '9', 'CH', 50.4, 9, NULL, NULL),
(143367, 3314, '10', 'C', 37.4, 10, NULL, NULL),
(143368, 3314, '11', 'CH2', 20.7, 11, NULL, NULL),
(143369, 3314, '12', 'CH2', 25, 12, NULL, NULL),
(143370, 3314, '13', 'CH', 37.6, 13, NULL, NULL),
(143371, 3314, '14', 'C', 49.1, 14, NULL, NULL),
(143372, 3314, '15', 'CH', 67.8, 15, NULL, NULL),
(143373, 3314, '16', 'CH2', 45.6, 16, NULL, NULL),
(143374, 3314, '17', 'C', 42.6, 17, NULL, NULL),
(143375, 3314, '18', 'CH', 47.6, 18, NULL, NULL),
(143376, 3314, '19', 'CH', 48.2, 19, NULL, NULL),
(143377, 3314, '20', 'C', 150.4, 20, NULL, NULL),
(143378, 3314, '21', 'CH2', 30.2, 21, NULL, NULL),
(143379, 3314, '22', 'CH2', 39.9, 22, NULL, NULL),
(143380, 3314, '23', 'CH3', 28, 23, NULL, NULL),
(143381, 3314, '24', 'CH3', 15.3, 24, NULL, NULL),
(143382, 3314, '25', 'CH3', 15.9, 25, NULL, NULL),
(143383, 3314, '26', 'CH3', 10.9, 26, NULL, NULL),
(143384, 3314, '27', 'CH3', 8.5, 27, NULL, NULL),
(143385, 3314, '28', 'CH3', 18.9, 28, NULL, NULL),
(143386, 3314, '29', 'CH2', 109.6, 29, NULL, NULL),
(143387, 3314, '30', 'CH3', 19.5, 30, NULL, NULL),
(143388, 3315, '1', 'CH2', 38.5, 1, NULL, NULL),
(143389, 3315, '2', 'CH2', 23.8, 2, NULL, NULL),
(143390, 3315, '3', 'CH', 81, 3, NULL, NULL),
(143391, 3315, '4', 'C', 37.9, 4, NULL, NULL),
(143392, 3315, '5', 'CH', 55.4, 5, NULL, NULL),
(143393, 3315, '6', 'CH2', 18.2, 6, NULL, NULL),
(143394, 3315, '7', 'CH2', 34.4, 7, NULL, NULL),
(143395, 3315, '8', 'C', 40.9, 8, NULL, NULL),
(143396, 3315, '9', 'CH', 50, 9, NULL, NULL),
(143397, 3315, '10', 'C', 37.1, 10, NULL, NULL),
(143398, 3315, '11', 'CH2', 20.9, 11, NULL, NULL),
(143399, 3315, '12', 'CH2', 26, 12, NULL, NULL),
(143400, 3315, '13', 'CH', 37.9, 13, NULL, NULL),
(143401, 3315, '14', 'C', 43.1, 14, NULL, NULL),
(143402, 3315, '15', 'CH2', 27.4, 15, NULL, NULL),
(143403, 3315, '16', 'CH2', 35.5, 16, NULL, NULL),
(143404, 3315, '17', 'C', 43.1, 17, NULL, NULL),
(143405, 3315, '18', 'CH', 47.3, 18, NULL, NULL),
(143406, 3315, '19', 'CH', 40.2, 19, NULL, NULL),
(143407, 3315, '20', 'CH', 41, 20, NULL, NULL),
(143408, 3315, '21', 'CH2', 23.8, 21, NULL, NULL),
(143409, 3315, '22', 'CH2', 40.5, 22, NULL, NULL),
(143410, 3315, '23', 'CH3', 28, 23, NULL, NULL),
(143411, 3315, '24', 'CH3', 16.6, 24, NULL, NULL),
(143412, 3315, '25', 'CH3', 16.2, 25, NULL, NULL),
(143413, 3315, '26', 'CH3', 16, 26, NULL, NULL),
(143414, 3315, '27', 'CH3', 14.4, 27, NULL, NULL),
(143415, 3315, '28', 'CH3', 18, 28, NULL, NULL),
(143416, 3315, '29', 'C', -9999, 29, NULL, NULL),
(143417, 3315, '30', 'CH3', 9.6, 30, NULL, NULL),
(143418, 3315, '3a', 'C', 171, 3001, NULL, NULL),
(143419, 3315, '3b', 'CH3', 21.3, 3002, NULL, NULL),
(143420, 3316, '1', 'CH', 66.4, 1, NULL, NULL),
(143421, 3316, '2', 'CH2', 35.2, 2, NULL, NULL),
(143422, 3316, '3', 'CH', 75, 3, NULL, NULL),
(143423, 3316, '4', 'C', 39.9, 4, NULL, NULL),
(143424, 3316, '5', 'CH', 58.2, 5, NULL, NULL),
(143425, 3316, '6', 'CH2', 18.7, 6, NULL, NULL),
(143426, 3316, '7', 'CH2', 35.2, 7, NULL, NULL),
(143427, 3316, '8', 'C', 42.7, 8, NULL, NULL),
(143428, 3316, '9', 'CH', 52.1, 9, NULL, NULL),
(143429, 3316, '10', 'C', 46.3, 10, NULL, NULL),
(143430, 3316, '11', 'CH', 76.5, 11, NULL, NULL),
(143431, 3316, '12', 'CH2', 34.9, 12, NULL, NULL),
(143432, 3316, '13', 'CH', 35.2, 13, NULL, NULL),
(143433, 3316, '14', 'C', 42.7, 14, NULL, NULL),
(143434, 3316, '15', 'CH2', 28, 15, NULL, NULL),
(143435, 3316, '16', 'CH2', 38, 16, NULL, NULL),
(143436, 3316, '17', 'C', 43.1, 17, NULL, NULL),
(143437, 3316, '18', 'CH', 49.4, 18, NULL, NULL),
(143438, 3316, '19', 'CH', 53.4, 19, NULL, NULL),
(143439, 3316, '20', 'C', 211.3, 20, NULL, NULL),
(143440, 3316, '21', 'CH2', 27.8, 21, NULL, NULL),
(143441, 3316, '22', 'CH2', 39.9, 22, NULL, NULL),
(143442, 3316, '23', 'CH3', 29.4, 23, NULL, NULL),
(143443, 3316, '24', 'CH3', 14.2, 24, NULL, NULL),
(143444, 3316, '25', 'CH3', 15.6, 25, NULL, NULL),
(143445, 3316, '26', 'CH3', 17.6, 26, NULL, NULL),
(143446, 3316, '27', 'CH3', 14.2, 27, NULL, NULL),
(143447, 3316, '28', 'CH3', 18.2, 28, NULL, NULL),
(143448, 3316, '29', 'CH3', 28.6, 29, NULL, NULL),
(143449, 3317, '1', 'CH2', 39.6, 1, NULL, NULL),
(143450, 3317, '2', 'CH2', 34.1, 2, NULL, NULL),
(143451, 3317, '3', 'C', 217.9, 3, NULL, NULL),
(143452, 3317, '4', 'C', 47.3, 4, NULL, NULL),
(143453, 3317, '5', 'CH', 55, 5, NULL, NULL),
(143454, 3317, '6', 'CH2', 19.6, 6, NULL, NULL),
(143455, 3317, '7', 'CH2', 33.6, 7, NULL, NULL),
(143456, 3317, '8', 'C', 40.6, 8, NULL, NULL),
(143457, 3317, '9', 'CH', 49.9, 9, NULL, NULL),
(143458, 3317, '10', 'C', 36.9, 10, NULL, NULL),
(143459, 3317, '11', 'CH2', 21.4, 11, NULL, NULL),
(143460, 3317, '12', 'CH2', 25.5, 12, NULL, NULL),
(143461, 3317, '13', 'CH', 38.2, 13, NULL, NULL),
(143462, 3317, '14', 'C', 42.4, 14, NULL, NULL),
(143463, 3317, '15', 'CH2', 29.6, 15, NULL, NULL),
(143464, 3317, '16', 'CH2', 32.1, 16, NULL, NULL),
(143465, 3317, '17', 'C', 56.5, 17, NULL, NULL),
(143466, 3317, '18', 'CH', 46.9, 18, NULL, NULL),
(143467, 3317, '19', 'CH', 49.4, 19, NULL, NULL),
(143468, 3317, '20', 'C', 150.4, 20, NULL, NULL),
(143469, 3317, '21', 'CH2', 30.6, 21, NULL, NULL),
(143470, 3317, '22', 'CH2', 36.8, 22, NULL, NULL),
(143471, 3317, '23', 'CH3', 26.6, 23, NULL, NULL),
(143472, 3317, '24', 'CH3', 21, 24, NULL, NULL),
(143473, 3317, '25', 'CH3', 15.7, 25, NULL, NULL),
(143474, 3317, '26', 'CH3', 15.9, 26, NULL, NULL),
(143475, 3317, '27', 'CH3', 14.6, 27, NULL, NULL),
(143476, 3317, '28', 'C', 176.3, 28, NULL, NULL),
(143477, 3317, '29', 'CH2', 109.6, 29, NULL, NULL),
(143478, 3317, '30', 'CH3', 19.3, 30, NULL, NULL),
(143479, 3317, '28a', 'CH3', -9999, 28001, NULL, NULL),
(143480, 3318, '1', 'CH2', 39.7, 1, NULL, NULL),
(143481, 3318, '2', 'CH2', 33.2, 2, NULL, NULL),
(143482, 3318, '3', 'C', 217, 3, NULL, NULL),
(143483, 3318, '4', 'C', 42.3, 4, NULL, NULL),
(143484, 3318, '5', 'CH', 58.6, 5, NULL, NULL),
(143485, 3318, '6', 'CH', 67.5, 6, NULL, NULL),
(143486, 3318, '7', 'CH2', 44.2, 7, NULL, NULL),
(143487, 3318, '8', 'C', 38.4, 8, NULL, NULL),
(143488, 3318, '9', 'CH', 49.2, 9, NULL, NULL),
(143489, 3318, '10', 'C', 32.2, 10, NULL, NULL),
(143490, 3318, '11', 'CH2', 21.9, 11, NULL, NULL),
(143491, 3318, '12', 'CH2', 25.6, 12, NULL, NULL),
(143492, 3318, '13', 'CH', 38, 13, NULL, NULL),
(143493, 3318, '14', 'C', 41.4, 14, NULL, NULL),
(143494, 3318, '15', 'CH2', 29.8, 15, NULL, NULL),
(143495, 3318, '16', 'CH2', 32.9, 16, NULL, NULL),
(143496, 3318, '17', 'C', 56.2, 17, NULL, NULL),
(143497, 3318, '18', 'CH', 49, 18, NULL, NULL),
(143498, 3318, '19', 'CH', 47.4, 19, NULL, NULL),
(143499, 3318, '20', 'C', 150.5, 20, NULL, NULL),
(143500, 3318, '21', 'CH2', 30.6, 21, NULL, NULL),
(143501, 3318, '22', 'CH2', 37.1, 22, NULL, NULL),
(143502, 3318, '23', 'CH3', 25.6, 23, NULL, NULL),
(143503, 3318, '24', 'CH3', 19.4, 24, NULL, NULL),
(143504, 3318, '25', 'CH3', 16.4, 25, NULL, NULL),
(143505, 3318, '26', 'CH3', 17.7, 26, NULL, NULL),
(143506, 3318, '27', 'CH3', 14.6, 27, NULL, NULL),
(143507, 3318, '28', 'C', 179.2, 28, NULL, NULL),
(143508, 3318, '29', 'CH2', 109.7, 29, NULL, NULL),
(143509, 3318, '30', 'CH3', 19.4, 30, NULL, NULL),
(143510, 3319, '1', 'CH2', 40.1, 1, NULL, NULL),
(143511, 3319, '2', 'CH2', 34.5, 2, NULL, NULL),
(143512, 3319, '3', 'C', 216.3, 3, NULL, NULL),
(143513, 3319, '4', 'C', 42.2, 4, NULL, NULL),
(143514, 3319, '5', 'CH', 56.5, 5, NULL, NULL),
(143515, 3319, '6', 'CH', 69.8, 6, NULL, NULL),
(143516, 3319, '7', 'CH2', 41.9, 7, NULL, NULL),
(143517, 3319, '8', 'C', 37.5, 8, NULL, NULL),
(143518, 3319, '9', 'CH', 50.9, 9, NULL, NULL),
(143519, 3319, '10', 'C', 34.5, 10, NULL, NULL),
(143520, 3319, '11', 'CH2', 21.3, 11, NULL, NULL),
(143521, 3319, '12', 'CH2', 25.2, 12, NULL, NULL),
(143522, 3319, '13', 'CH', 37.5, 13, NULL, NULL),
(143523, 3319, '14', 'C', 42.9, 14, NULL, NULL),
(143524, 3319, '15', 'CH2', 29.9, 15, NULL, NULL),
(143525, 3319, '16', 'CH2', 32.2, 16, NULL, NULL),
(143526, 3319, '17', 'C', 56.9, 17, NULL, NULL),
(143527, 3319, '18', 'CH', 49.5, 18, NULL, NULL),
(143528, 3319, '19', 'CH', 47, 19, NULL, NULL),
(143529, 3319, '20', 'C', 150.3, 20, NULL, NULL),
(143530, 3319, '21', 'CH2', 30.7, 21, NULL, NULL),
(143531, 3319, '22', 'CH2', 37, 22, NULL, NULL),
(143532, 3319, '23', 'CH3', 25.7, 23, NULL, NULL),
(143533, 3319, '24', 'CH3', 21.3, 24, NULL, NULL),
(143534, 3319, '25', 'CH3', 17.3, 25, NULL, NULL),
(143535, 3319, '26', 'CH3', 17.1, 26, NULL, NULL),
(143536, 3319, '27', 'CH3', 15, 27, NULL, NULL),
(143537, 3319, '28', 'C', 181.9, 28, NULL, NULL),
(143538, 3319, '29', 'CH2', 109.8, 29, NULL, NULL),
(143539, 3319, '30', 'CH3', 19.5, 30, NULL, NULL),
(143540, 3320, '1', 'CH2', 30.5, 1, NULL, NULL),
(143541, 3320, '2', 'CH2', 35.9, 2, NULL, NULL),
(143542, 3320, '3', 'C', 97.9, 3, NULL, NULL),
(143543, 3320, '4', 'C', 35.6, 4, NULL, NULL),
(143544, 3320, '5', 'CH', 49.8, 5, NULL, NULL),
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(143547, 3320, '8', 'C', 40, 8, NULL, NULL),
(143548, 3320, '9', 'CH', 45.6, 9, NULL, NULL),
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(143550, 3320, '11', 'CH2', 22.4, 11, NULL, NULL),
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(143568, 3320, '29', 'CH2', 109.8, 29, NULL, NULL),
(143569, 3320, '30', 'CH3', 19.5, 30, NULL, NULL),
(143570, 3321, '1', 'CH', 80.9, 1, NULL, NULL),
(143571, 3321, '2', 'CH', 206.2, 2, NULL, NULL),
(143572, 3321, '3', 'CH', 73.7, 3, NULL, NULL),
(143573, 3321, '4', 'C', 48.3, 4, NULL, NULL),
(143574, 3321, '5', 'CH', 63, 5, NULL, NULL),
(143575, 3321, '6', 'CH2', 18.6, 6, NULL, NULL),
(143576, 3321, '7', 'CH2', 34.7, 7, NULL, NULL),
(143577, 3321, '8', 'C', 43.1, 8, NULL, NULL),
(143578, 3321, '9', 'CH', 49.8, 9, NULL, NULL),
(143579, 3321, '10', 'C', 41.2, 10, NULL, NULL),
(143580, 3321, '11', 'CH2', 24.9, 11, NULL, NULL),
(143581, 3321, '12', 'CH2', 25.7, 12, NULL, NULL),
(143582, 3321, '13', 'CH', 38.5, 13, NULL, NULL),
(143583, 3321, '14', 'C', 42.4, 14, NULL, NULL),
(143584, 3321, '15', 'CH2', 32.9, 15, NULL, NULL),
(143585, 3321, '16', 'CH2', 31.3, 16, NULL, NULL),
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