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(79740, 1108, '15', 'C', 223.8, 15, NULL, NULL),
(79741, 1108, '16', 'CH', 57.4, 16, NULL, NULL),
(79742, 1108, '17', 'CH2', 68, 17, NULL, NULL),
(79743, 1108, '18', 'CH3', 63.4, 18, NULL, NULL),
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(79745, 1108, '20', 'CH2', 21.6, 20, NULL, NULL),
(79746, 1108, '1a', 'C', 169.9, 1001, NULL, NULL),
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(79748, 1108, '17a', 'CH3', 58.6, 17001, NULL, NULL),
(79749, 1109, '1', 'CH', 76.7, 1, NULL, NULL),
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(79759, 1109, '11', 'CH', 70.1, 11, NULL, NULL),
(79760, 1109, '12', 'CH2', 41, 12, NULL, NULL),
(79761, 1109, '13', 'CH', 35.4, 13, NULL, NULL),
(79762, 1109, '14', 'CH2', 27, 14, NULL, NULL),
(79763, 1109, '15', 'CH', 75, 15, NULL, NULL),
(79764, 1109, '16', 'C', 160.9, 16, NULL, NULL),
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(79766, 1109, '18', 'CH3', 32.5, 18, NULL, NULL),
(79767, 1109, '19', 'CH3', 22.3, 19, NULL, NULL),
(79768, 1109, '20', 'CH2', 65.3, 20, NULL, NULL),
(79769, 1109, '1a', 'C', 170.3, 1001, NULL, NULL),
(79770, 1109, '1b', 'CH3', 21.1, 1002, NULL, NULL),
(79771, 1109, '6a', 'C', 170.1, 6001, NULL, NULL),
(79772, 1109, '6b', 'CH3', 21.4, 6002, NULL, NULL),
(79773, 1109, '11a', 'C', 169.7, 11001, NULL, NULL),
(79774, 1109, '11b', 'CH3', 22.1, 11002, NULL, NULL),
(79775, 1110, '1', 'CH', 78.4, 1, NULL, NULL),
(79776, 1110, '2', 'CH2', 24, 2, NULL, NULL),
(79777, 1110, '3', 'CH2', 37.4, 3, NULL, NULL),
(79778, 1110, '4', 'C', 31.5, 4, NULL, NULL),
(79779, 1110, '5', 'CH', 55.6, 5, NULL, NULL),
(79780, 1110, '6', 'CH', 101.9, 6, NULL, NULL),
(79781, 1110, '7', 'C', 172, 7, NULL, NULL),
(79782, 1110, '8', 'C', 56.5, 8, NULL, NULL),
(79783, 1110, '9', 'CH', 48.5, 9, NULL, NULL),
(79784, 1110, '10', 'C', 49.9, 10, NULL, NULL),
(79785, 1110, '11', 'CH', 65.9, 11, NULL, NULL),
(79786, 1110, '12', 'CH2', 41.3, 12, NULL, NULL),
(79787, 1110, '13', 'CH', 35.4, 13, NULL, NULL),
(79788, 1110, '14', 'CH2', 34.1, 14, NULL, NULL),
(79789, 1110, '15', 'C', 200.9, 15, NULL, NULL),
(79790, 1110, '16', 'C', 151, 16, NULL, NULL),
(79791, 1110, '17', 'CH2', 117, 17, NULL, NULL),
(79792, 1110, '18', 'CH3', 33, 18, NULL, NULL),
(79793, 1110, '19', 'CH3', 23, 19, NULL, NULL),
(79794, 1110, '20', 'CH2', 73.9, 20, NULL, NULL),
(79795, 1111, '1', 'CH', 77.9, 1, NULL, NULL),
(79796, 1111, '2', 'CH2', 24, 2, NULL, NULL),
(79797, 1111, '3', 'CH2', 35.4, 3, NULL, NULL),
(79798, 1111, '4', 'C', 39.2, 4, NULL, NULL),
(79799, 1111, '5', 'CH', 61.5, 5, NULL, NULL),
(79800, 1111, '6', 'CH', 201.6, 6, NULL, NULL),
(79801, 1111, '7', 'C', 170.8, 7, NULL, NULL),
(79802, 1111, '8', 'C', 58.6, 8, NULL, NULL),
(79803, 1111, '9', 'CH', 47.2, 9, NULL, NULL),
(79804, 1111, '10', 'C', 44.6, 10, NULL, NULL),
(79805, 1111, '11', 'CH', 63.6, 11, NULL, NULL),
(79806, 1111, '12', 'CH2', 42.4, 12, NULL, NULL),
(79807, 1111, '13', 'CH', 34.9, 13, NULL, NULL),
(79808, 1111, '14', 'CH2', 29.9, 14, NULL, NULL),
(79809, 1111, '15', 'C', 202.1, 15, NULL, NULL),
(79810, 1111, '16', 'C', 150.8, 16, NULL, NULL),
(79811, 1111, '17', 'CH2', 118.7, 17, NULL, NULL),
(79812, 1111, '18', 'CH3', 28.4, 18, NULL, NULL),
(79813, 1111, '19', 'CH2', 69, 19, NULL, NULL),
(79814, 1111, '20', 'CH2', 67.8, 20, NULL, NULL),
(79815, 1111, '1a', 'C', 170.2, 1001, NULL, NULL),
(79816, 1111, '1b', 'CH3', 20.4, 1002, NULL, NULL),
(79817, 1111, '19a', 'C', 170.1, 19001, NULL, NULL),
(79818, 1111, '19b', 'CH3', 21.4, 19002, NULL, NULL),
(79819, 1112, '1', 'CH', 73.2, 1, NULL, NULL),
(79820, 1112, '2', 'CH2', 29, 2, NULL, NULL),
(79821, 1112, '3', 'CH2', 33.8, 3, NULL, NULL),
(79822, 1112, '4', 'C', 37.6, 4, NULL, NULL),
(79823, 1112, '5', 'CH', 62.3, 5, NULL, NULL),
(79824, 1112, '6', 'CH', 74.2, 6, NULL, NULL),
(79825, 1112, '7', 'C', 96.4, 7, NULL, NULL),
(79826, 1112, '8', 'C', 59.9, 8, NULL, NULL),
(79827, 1112, '9', 'CH', 54.8, 9, NULL, NULL),
(79828, 1112, '10', 'C', 43.1, 10, NULL, NULL),
(79829, 1112, '11', 'CH', 67, 11, NULL, NULL),
(79830, 1112, '12', 'CH2', 39.4, 12, NULL, NULL),
(79831, 1112, '13', 'CH', 34.8, 13, NULL, NULL),
(79832, 1112, '14', 'CH2', 27.2, 14, NULL, NULL),
(79833, 1112, '15', 'C', 211.4, 15, NULL, NULL),
(79834, 1112, '16', 'C', 154.3, 16, NULL, NULL),
(79835, 1112, '17', 'CH2', 115.7, 17, NULL, NULL),
(79836, 1112, '18', 'CH3', 27.9, 18, NULL, NULL),
(79837, 1112, '19', 'CH2', 66.6, 19, NULL, NULL),
(79838, 1112, '20', 'CH2', 66.4, 20, NULL, NULL),
(79839, 1112, '19a', 'C', 170.8, 19001, NULL, NULL),
(79840, 1112, '19b', 'CH3', 20.8, 19002, NULL, NULL),
(79841, 1113, '1', 'CH2', 30.9, 1, NULL, NULL),
(79842, 1113, '2', 'CH2', 18.5, 2, NULL, NULL),
(79843, 1113, '3', 'CH2', 36, 3, NULL, NULL),
(79844, 1113, '4', 'C', 37.2, 4, NULL, NULL),
(79845, 1113, '5', 'CH', 60.9, 5, NULL, NULL),
(79846, 1113, '6', 'CH', 74, 6, NULL, NULL),
(79847, 1113, '7', 'C', 96.3, 7, NULL, NULL),
(79848, 1113, '8', 'C', 59.1, 8, NULL, NULL),
(79849, 1113, '9', 'CH', 53.2, 9, NULL, NULL),
(79850, 1113, '10', 'C', 37.3, 10, NULL, NULL),
(79851, 1113, '11', 'CH', 69.4, 11, NULL, NULL),
(79852, 1113, '12', 'CH2', 37.9, 12, NULL, NULL),
(79853, 1113, '13', 'CH', 34.2, 13, NULL, NULL),
(79854, 1113, '14', 'CH2', 27.7, 14, NULL, NULL),
(79855, 1113, '15', 'C', 209.7, 15, NULL, NULL),
(79856, 1113, '16', 'C', 153, 16, NULL, NULL),
(79857, 1113, '17', 'CH2', 117.6, 17, NULL, NULL),
(79858, 1113, '18', 'CH3', 28.6, 18, NULL, NULL),
(79859, 1113, '19', 'CH2', 67, 19, NULL, NULL),
(79860, 1113, '20', 'CH2', 68.6, 20, NULL, NULL),
(79861, 1113, '11a', 'C', 169.9, 11001, NULL, NULL),
(79862, 1113, '11b', 'CH3', 21.7, 11002, NULL, NULL),
(79863, 1113, '19a', 'C', 170.9, 19001, NULL, NULL),
(79864, 1113, '19b', 'CH3', 20.8, 19002, NULL, NULL),
(79865, 1114, '1', 'CH2', 25.7, 1, NULL, NULL),
(79866, 1114, '2', 'CH2', 23.6, 2, NULL, NULL),
(79867, 1114, '3', 'CH', 74.4, 3, NULL, NULL),
(79868, 1114, '4', 'C', 39.8, 4, NULL, NULL),
(79869, 1114, '5', 'CH', 53.5, 5, NULL, NULL),
(79870, 1114, '6', 'CH', 70, 6, NULL, NULL),
(79871, 1114, '7', 'CH', 70, 7, NULL, NULL),
(79872, 1114, '8', 'C', 62.9, 8, NULL, NULL),
(79873, 1114, '9', 'CH', 52.1, 9, NULL, NULL),
(79874, 1114, '10', 'C', 39.8, 10, NULL, NULL),
(79875, 1114, '11', 'CH2', 20.1, 11, NULL, NULL),
(79876, 1114, '12', 'CH2', 31.8, 12, NULL, NULL),
(79877, 1114, '13', 'CH', 44.6, 13, NULL, NULL),
(79878, 1114, '14', 'CH', 71, 14, NULL, NULL),
(79879, 1114, '15', 'C', 212.1, 15, NULL, NULL),
(79880, 1114, '16', 'C', 153.8, 16, NULL, NULL),
(79881, 1114, '17', 'CH2', 118.5, 17, NULL, NULL),
(79882, 1114, '18', 'CH3', 29.9, 18, NULL, NULL),
(79883, 1114, '19', 'CH3', 23.3, 19, NULL, NULL),
(79884, 1114, '20', 'CH', 94.2, 20, NULL, NULL),
(79885, 1115, '1', 'CH2', 30.4, 1, NULL, NULL),
(79886, 1115, '2', 'CH2', 35.1, 2, NULL, NULL),
(79887, 1115, '3', 'C', 98, 3, NULL, NULL),
(79888, 1115, '4', 'C', 40.7, 4, NULL, NULL),
(79889, 1115, '5', 'CH', 48.7, 5, NULL, NULL),
(79890, 1115, '6', 'CH2', 31, 6, NULL, NULL),
(79891, 1115, '7', 'CH', 72.8, 7, NULL, NULL),
(79892, 1115, '8', 'C', 61.2, 8, NULL, NULL),
(79893, 1115, '9', 'CH', 48.5, 9, NULL, NULL),
(79894, 1115, '10', 'C', 37.2, 10, NULL, NULL),
(79895, 1115, '11', 'CH2', 18.4, 11, NULL, NULL),
(79896, 1115, '12', 'CH2', 30.9, 12, NULL, NULL),
(79897, 1115, '13', 'CH', 46.4, 13, NULL, NULL),
(79898, 1115, '14', 'CH', 76.5, 14, NULL, NULL),
(79899, 1115, '15', 'C', 207.5, 15, NULL, NULL),
(79900, 1115, '16', 'C', 149.7, 16, NULL, NULL),
(79901, 1115, '17', 'CH2', 116.5, 17, NULL, NULL),
(79902, 1115, '18', 'CH3', 27.3, 18, NULL, NULL),
(79903, 1115, '19', 'CH3', 19.5, 19, NULL, NULL),
(79904, 1115, '20', 'CH2', 68.1, 20, NULL, NULL),
(79905, 1116, '1', 'CH2', 28.7, 1, NULL, NULL),
(79906, 1116, '2', 'CH2', 26.8, 2, NULL, NULL),
(79907, 1116, '3', 'CH', 74.8, 3, NULL, NULL),
(79908, 1116, '4', 'C', 43.7, 4, NULL, NULL),
(79909, 1116, '5', 'CH', 47.6, 5, NULL, NULL),
(79910, 1116, '6', 'CH2', 29.8, 6, NULL, NULL),
(79911, 1116, '7', 'CH', 75.3, 7, NULL, NULL),
(79912, 1116, '8', 'C', 62.1, 8, NULL, NULL),
(79913, 1116, '9', 'CH', 55.7, 9, NULL, NULL),
(79914, 1116, '10', 'C', 38, 10, NULL, NULL),
(79915, 1116, '11', 'CH2', 18.9, 11, NULL, NULL),
(79916, 1116, '12', 'CH2', 31.1, 12, NULL, NULL),
(79917, 1116, '13', 'CH', 47.4, 13, NULL, NULL),
(79918, 1116, '14', 'CH', 76.7, 14, NULL, NULL),
(79919, 1116, '15', 'C', 209, 15, NULL, NULL),
(79920, 1116, '16', 'C', 150.7, 16, NULL, NULL),
(79921, 1116, '17', 'CH2', 115.8, 17, NULL, NULL),
(79922, 1116, '18', 'CH3', 29.6, 18, NULL, NULL),
(79923, 1116, '19', 'CH3', 23.2, 19, NULL, NULL),
(79924, 1116, '20', 'CH2', 60.3, 20, NULL, NULL),
(79925, 1117, '1', 'CH2', 32.4, 1, NULL, NULL),
(79926, 1117, '2', 'CH2', 27.5, 2, NULL, NULL),
(79927, 1117, '3', 'CH', 79.2, 3, NULL, NULL),
(79928, 1117, '4', 'C', 39.8, 4, NULL, NULL),
(79929, 1117, '5', 'CH', 50.4, 5, NULL, NULL),
(79930, 1117, '6', 'CH', 70.3, 6, NULL, NULL),
(79931, 1117, '7', 'CH2', 35.9, 7, NULL, NULL),
(79932, 1117, '8', 'CH', 35.8, 8, NULL, NULL),
(79933, 1117, '9', 'C', 53.1, 9, NULL, NULL),
(79934, 1117, '10', 'C', 39.2, 10, NULL, NULL),
(79935, 1117, '11', 'CH2', 45.6, 11, NULL, NULL),
(79936, 1117, '12', 'C', 52.5, 12, NULL, NULL),
(79937, 1117, '13', 'C', 213.5, 13, NULL, NULL),
(79938, 1117, '14', 'CH2', 42.7, 14, NULL, NULL),
(79939, 1117, '15', 'CH2', 36.8, 15, NULL, NULL),
(79940, 1117, '16', 'CH2', 23.9, 16, NULL, NULL),
(79941, 1117, '17', 'CH3', 19.9, 17, NULL, NULL),
(79942, 1117, '18', 'CH3', 28.5, 18, NULL, NULL),
(79943, 1117, '19', 'CH3', 16.8, 19, NULL, NULL),
(79944, 1117, '20', 'CH3', 21.4, 20, NULL, NULL),
(79945, 1117, '6a', 'C', 166.3, 6001, NULL, NULL),
(79946, 1117, '6b', 'C', 130.8, 6002, NULL, NULL),
(79947, 1117, '6c', 'CH', 129.8, 6003, NULL, NULL),
(79948, 1117, '6d', 'CH', 128.8, 6004, NULL, NULL),
(79949, 1117, '6e', 'CH', 133.3, 6005, NULL, NULL),
(79950, 1117, '6f', 'CH', 128.8, 6006, NULL, NULL),
(79951, 1117, '6g', 'CH', 129.8, 6007, NULL, NULL),
(79952, 1118, '1', 'CH2', 34.5, 1, NULL, NULL),
(79953, 1118, '2', 'CH2', 19.4, 2, NULL, NULL),
(79954, 1118, '3', 'CH2', 38.9, 3, NULL, NULL),
(79955, 1118, '4', 'C', 42.5, 4, NULL, NULL),
(79956, 1118, '5', 'CH', 52.4, 5, NULL, NULL),
(79957, 1118, '6', 'CH', 69.1, 6, NULL, NULL),
(79958, 1118, '7', 'CH2', 34.9, 7, NULL, NULL),
(79959, 1118, '8', 'CH', 35.9, 8, NULL, NULL),
(79960, 1118, '9', 'C', 52.9, 9, NULL, NULL),
(79961, 1118, '10', 'C', 39.5, 10, NULL, NULL),
(79962, 1118, '11', 'CH2', 45.5, 11, NULL, NULL),
(79963, 1118, '12', 'C', 52.5, 12, NULL, NULL),
(79964, 1118, '13', 'C', 213.4, 13, NULL, NULL),
(79965, 1118, '14', 'CH2', 42.6, 14, NULL, NULL),
(79966, 1118, '15', 'CH2', 36.8, 15, NULL, NULL),
(79967, 1118, '16', 'CH2', 23.6, 16, NULL, NULL),
(79968, 1118, '17', 'CH3', 19.9, 17, NULL, NULL),
(79969, 1118, '18', 'CH3', 29.6, 18, NULL, NULL),
(79970, 1118, '19', 'C', 181.8, 19, NULL, NULL),
(79971, 1118, '20', 'CH3', 20.5, 20, NULL, NULL),
(79972, 1118, '6a', 'C', 166, 6001, NULL, NULL),
(79973, 1118, '6b', 'C', 130.6, 6002, NULL, NULL),
(79974, 1118, '6c', 'CH', 129.8, 6003, NULL, NULL),
(79975, 1118, '6d', 'CH', 128.7, 6004, NULL, NULL),
(79976, 1118, '6e', 'CH', 133.1, 6005, NULL, NULL),
(79977, 1118, '6f', 'CH', 128.7, 6006, NULL, NULL),
(79978, 1118, '6g', 'CH', 129.8, 6007, NULL, NULL),
(79979, 1119, '1', 'CH2', 34.4, 1, NULL, NULL),
(79980, 1119, '2', 'CH2', 18.4, 2, NULL, NULL),
(79981, 1119, '3', 'CH2', 38, 3, NULL, NULL),
(79982, 1119, '4', 'C', 38.7, 4, NULL, NULL),
(79983, 1119, '5', 'CH', 43.5, 5, NULL, NULL),
(79984, 1119, '6', 'CH', 70.8, 6, NULL, NULL),
(79985, 1119, '7', 'CH2', 35.6, 7, NULL, NULL),
(79986, 1119, '8', 'CH', 29.6, 8, NULL, NULL),
(79987, 1119, '9', 'C', 53.5, 9, NULL, NULL),
(79988, 1119, '10', 'C', 39, 10, NULL, NULL),
(79989, 1119, '11', 'CH2', 38.1, 11, NULL, NULL),
(79990, 1119, '12', 'C', 43.8, 12, NULL, NULL);
INSERT INTO `carbons` (`id`, `molecularId`, `numeration`, `carbonType`, `shift`, `num2`, `created_at`, `updated_at`) VALUES
(79991, 1119, '13', 'CH', 75.1, 13, NULL, NULL),
(79992, 1119, '14', 'CH2', 36.6, 14, NULL, NULL),
(79993, 1119, '15', 'CH2', 36.5, 15, NULL, NULL),
(79994, 1119, '16', 'CH2', 22.6, 16, NULL, NULL),
(79995, 1119, '17', 'CH3', 24.2, 17, NULL, NULL),
(79996, 1119, '18', 'CH2', 71.7, 18, NULL, NULL),
(79997, 1119, '19', 'CH3', 20.7, 19, NULL, NULL),
(79998, 1119, '20', 'CH3', 22.5, 20, NULL, NULL),
(79999, 1119, '6a', 'C', 166.7, 6001, NULL, NULL),
(80000, 1119, '6b', 'C', 131.1, 6002, NULL, NULL),
(80001, 1119, '6c', 'CH', 129.9, 6003, NULL, NULL),
(80002, 1119, '6d', 'CH', 128.6, 6004, NULL, NULL),
(80003, 1119, '6e', 'CH', 133, 6005, NULL, NULL),
(80004, 1119, '6f', 'CH', 128.6, 6006, NULL, NULL),
(80005, 1119, '6g', 'CH', 129.9, 6007, NULL, NULL),
(80006, 1120, '1', 'CH2', 38.6, 1, NULL, NULL),
(80007, 1120, '2', 'CH2', 18.7, 2, NULL, NULL),
(80008, 1120, '3', 'CH2', 38.3, 3, NULL, NULL),
(80009, 1120, '4', 'C', 38.7, 4, NULL, NULL),
(80010, 1120, '5', 'CH', 41.5, 5, NULL, NULL),
(80011, 1120, '6', 'CH', 71.6, 6, NULL, NULL),
(80012, 1120, '7', 'CH2', 37.1, 7, NULL, NULL),
(80013, 1120, '8', 'C', 144, 8, NULL, NULL),
(80014, 1120, '9', 'CH', 57.3, 9, NULL, NULL),
(80015, 1120, '10', 'C', 38.9, 10, NULL, NULL),
(80016, 1120, '11', 'CH2', 23.9, 11, NULL, NULL),
(80017, 1120, '12', 'CH2', 39.4, 12, NULL, NULL),
(80018, 1120, '13', 'C', 164.6, 13, NULL, NULL),
(80019, 1120, '14', 'CH', 127.5, 14, NULL, NULL),
(80020, 1120, '15', 'CH', 191.5, 15, NULL, NULL),
(80021, 1120, '16', 'CH3', 18.1, 16, NULL, NULL),
(80022, 1120, '17', 'CH2', 113.9, 17, NULL, NULL),
(80023, 1120, '18', 'CH2', 71.4, 18, NULL, NULL),
(80024, 1120, '19', 'CH3', 20.5, 19, NULL, NULL),
(80025, 1120, '20', 'CH3', 26.1, 20, NULL, NULL),
(80026, 1120, '6a', 'C', 166.4, 6001, NULL, NULL),
(80027, 1120, '6b', 'C', 131, 6002, NULL, NULL),
(80028, 1120, '6c', 'CH', 129.9, 6003, NULL, NULL),
(80029, 1120, '6d', 'CH', 128.7, 6004, NULL, NULL),
(80030, 1120, '6e', 'CH', 133.1, 6005, NULL, NULL),
(80031, 1120, '6f', 'CH', 128.7, 6006, NULL, NULL),
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