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(539885, 19847, '2', 'CH', 127.2, 2, NULL, NULL),
(539886, 19847, '3', 'CH', 146.3, 3, NULL, NULL),
(539887, 19847, '4', 'CH2', 32.2, 4, NULL, NULL),
(539888, 19847, '5', 'C', 77.1, 5, NULL, NULL),
(539889, 19847, '6', 'CH', 81.4, 6, NULL, NULL),
(539890, 19847, '7', 'CH2', 32, 7, NULL, NULL),
(539891, 19847, '8', 'CH', 31.6, 8, NULL, NULL),
(539892, 19847, '9', 'CH', 40.9, 9, NULL, NULL);
INSERT INTO `carbons` (`id`, `molecularId`, `numeration`, `carbonType`, `shift`, `num2`, `created_at`, `updated_at`) VALUES
(539893, 19847, '10', 'C', 50, 10, NULL, NULL),
(539894, 19847, '11', 'CH2', 37.3, 11, NULL, NULL),
(539895, 19847, '12', 'C', 97.8, 12, NULL, NULL),
(539896, 19847, '13', 'C', 48.4, 13, NULL, NULL),
(539897, 19847, '14', 'CH', 44.9, 14, NULL, NULL),
(539898, 19847, '15', 'CH2', 22.3, 15, NULL, NULL),
(539899, 19847, '16', 'CH2', 34.2, 16, NULL, NULL),
(539900, 19847, '17', 'C', 79.7, 17, NULL, NULL),
(539901, 19847, '18', 'CH3', 12, 18, NULL, NULL),
(539902, 19847, '19', 'CH2', 66.8, 19, NULL, NULL),
(539903, 19847, '20', 'CH', 35.3, 20, NULL, NULL),
(539904, 19847, '21', 'CH3', 9.9, 21, NULL, NULL),
(539905, 19847, '22', 'CH', 68.6, 22, NULL, NULL),
(539906, 19847, '23', 'CH', 82.2, 23, NULL, NULL),
(539907, 19847, '24', 'C', 157.3, 24, NULL, NULL),
(539908, 19847, '25', 'C', 123.4, 25, NULL, NULL),
(539909, 19847, '26', 'C', 174.9, 26, NULL, NULL),
(539910, 19847, '27', 'CH3', 8.2, 27, NULL, NULL),
(539911, 19847, '28', 'CH3', 11.7, 28, NULL, NULL),
(539912, 19848, '1', 'C', 200.5, 1, NULL, NULL),
(539913, 19848, '2', 'CH', 128.5, 2, NULL, NULL),
(539914, 19848, '3', 'CH', 141.2, 3, NULL, NULL),
(539915, 19848, '4', 'CH2', 37.1, 4, NULL, NULL),
(539916, 19848, '5', 'C', 78.6, 5, NULL, NULL),
(539917, 19848, '6', 'CH', 74.5, 6, NULL, NULL),
(539918, 19848, '7', 'CH2', 32.7, 7, NULL, NULL),
(539919, 19848, '8', 'CH', 29.7, 8, NULL, NULL),
(539920, 19848, '9', 'CH', 39, 9, NULL, NULL),
(539921, 19848, '10', 'C', 52.1, 10, NULL, NULL),
(539922, 19848, '11', 'CH2', 36.3, 11, NULL, NULL),
(539923, 19848, '12', 'C', 99.2, 12, NULL, NULL),
(539924, 19848, '13', 'C', 47.7, 13, NULL, NULL),
(539925, 19848, '14', 'CH', 45.5, 14, NULL, NULL),
(539926, 19848, '15', 'CH2', 22.9, 15, NULL, NULL),
(539927, 19848, '16', 'CH2', 34.1, 16, NULL, NULL),
(539928, 19848, '17', 'C', 80.6, 17, NULL, NULL),
(539929, 19848, '18', 'CH3', 12.2, 18, NULL, NULL),
(539930, 19848, '19', 'CH3', 16.1, 19, NULL, NULL),
(539931, 19848, '20', 'CH', 35.6, 20, NULL, NULL),
(539932, 19848, '21', 'CH3', 9.9, 21, NULL, NULL),
(539933, 19848, '22', 'CH', 68.8, 22, NULL, NULL),
(539934, 19848, '23', 'CH', 82.5, 23, NULL, NULL),
(539935, 19848, '24', 'C', 156.8, 24, NULL, NULL),
(539936, 19848, '25', 'C', 124.1, 25, NULL, NULL),
(539937, 19848, '26', 'C', 174.8, 26, NULL, NULL),
(539938, 19848, '27', 'CH3', 8.3, 27, NULL, NULL),
(539939, 19848, '28', 'CH3', 12, 28, NULL, NULL),
(539940, 19849, '1', 'C', 211.3, 1, NULL, NULL),
(539941, 19849, '2', 'CH2', 49.1, 2, NULL, NULL),
(539942, 19849, '3', 'CH', 68.8, 3, NULL, NULL),
(539943, 19849, '4', 'CH2', 41.8, 4, NULL, NULL),
(539944, 19849, '5', 'C', 136.2, 5, NULL, NULL),
(539945, 19849, '6', 'CH', 124.2, 6, NULL, NULL),
(539946, 19849, '7', 'CH2', 25.9, 7, NULL, NULL),
(539947, 19849, '8', 'CH', 40.3, 8, NULL, NULL),
(539948, 19849, '9', 'CH', 34.4, 9, NULL, NULL),
(539949, 19849, '10', 'C', 56, 10, NULL, NULL),
(539950, 19849, '11', 'CH2', 24.6, 11, NULL, NULL),
(539951, 19849, '12', 'CH2', 26.6, 12, NULL, NULL),
(539952, 19849, '13', 'C', 79.9, 13, NULL, NULL),
(539953, 19849, '14', 'C', 107.8, 14, NULL, NULL),
(539954, 19849, '15', 'C', 209.5, 15, NULL, NULL),
(539955, 19849, '16', 'CH', 55.7, 16, NULL, NULL),
(539956, 19849, '17', 'C', 81.7, 17, NULL, NULL),
(539957, 19849, '18', 'C', 173.6, 18, NULL, NULL),
(539958, 19849, '19', 'CH3', 17.5, 19, NULL, NULL),
(539959, 19849, '20', 'C', 81.4, 20, NULL, NULL),
(539960, 19849, '21', 'CH3', 22.5, 21, NULL, NULL),
(539961, 19849, '22', 'CH', 77.6, 22, NULL, NULL),
(539962, 19849, '23', 'CH2', 32.9, 23, NULL, NULL),
(539963, 19849, '24', 'C', 31.5, 24, NULL, NULL),
(539964, 19849, '25', 'CH', 51, 25, NULL, NULL),
(539965, 19849, '26', 'C', 167.5, 26, NULL, NULL),
(539966, 19849, '27', 'CH2', 61.6, 27, NULL, NULL),
(539967, 19849, '28', 'CH3', 25.7, 28, NULL, NULL),
(539968, 19850, '1', 'C', 212.9, 1, NULL, NULL),
(539969, 19850, '2', 'CH2', 48, 2, NULL, NULL),
(539970, 19850, '3', 'CH', 69.2, 3, NULL, NULL),
(539971, 19850, '4', 'CH2', 40.7, 4, NULL, NULL),
(539972, 19850, '5', 'C', 132.9, 5, NULL, NULL),
(539973, 19850, '6', 'CH', 125.9, 6, NULL, NULL),
(539974, 19850, '7', 'CH2', 24.7, 7, NULL, NULL),
(539975, 19850, '8', 'CH', 39.1, 8, NULL, NULL),
(539976, 19850, '9', 'CH', 33.4, 9, NULL, NULL),
(539977, 19850, '10', 'C', 55.2, 10, NULL, NULL),
(539978, 19850, '11', 'CH2', 24.9, 11, NULL, NULL),
(539979, 19850, '12', 'CH2', 25.9, 12, NULL, NULL),
(539980, 19850, '13', 'C', 79.6, 13, NULL, NULL),
(539981, 19850, '14', 'C', 107.5, 14, NULL, NULL),
(539982, 19850, '15', 'C', 208.1, 15, NULL, NULL),
(539983, 19850, '16', 'CH', 56.3, 16, NULL, NULL),
(539984, 19850, '17', 'C', 80.2, 17, NULL, NULL),
(539985, 19850, '18', 'C', 172.3, 18, NULL, NULL),
(539986, 19850, '19', 'CH3', 18.7, 19, NULL, NULL),
(539987, 19850, '20', 'C', 80.2, 20, NULL, NULL),
(539988, 19850, '21', 'CH3', 21.6, 21, NULL, NULL),
(539989, 19850, '22', 'CH', 77, 22, NULL, NULL),
(539990, 19850, '23', 'CH2', 32.9, 23, NULL, NULL),
(539991, 19850, '24', 'C', 31.1, 24, NULL, NULL),
(539992, 19850, '25', 'CH', 50.9, 25, NULL, NULL),
(539993, 19850, '26', 'C', 166.7, 26, NULL, NULL),
(539994, 19850, '27', 'CH2', 60.7, 27, NULL, NULL),
(539995, 19850, '28', 'CH3', 26.5, 28, NULL, NULL),
(539996, 19851, '1', 'C', 212.9, 1, NULL, NULL),
(539997, 19851, '2', 'CH2', 48.2, 2, NULL, NULL),
(539998, 19851, '3', 'CH', 66.3, 3, NULL, NULL),
(539999, 19851, '4', 'CH', 129.8, 4, NULL, NULL),
(540000, 19851, '5', 'C', 140.7, 5, NULL, NULL),
(540001, 19851, '6', 'CH', 129, 6, NULL, NULL),
(540002, 19851, '7', 'CH', 125.2, 7, NULL, NULL),
(540003, 19851, '8', 'CH', 45, 8, NULL, NULL),
(540004, 19851, '9', 'CH', 34.1, 9, NULL, NULL),
(540005, 19851, '10', 'C', 49.9, 10, NULL, NULL),
(540006, 19851, '11', 'CH2', 21.7, 11, NULL, NULL),
(540007, 19851, '12', 'CH2', 24.4, 12, NULL, NULL),
(540008, 19851, '13', 'C', 78.8, 13, NULL, NULL),
(540009, 19851, '14', 'C', 105.8, 14, NULL, NULL),
(540010, 19851, '15', 'C', 208.6, 15, NULL, NULL),
(540011, 19851, '16', 'CH', 53.7, 16, NULL, NULL),
(540012, 19851, '17', 'C', 80.9, 17, NULL, NULL),
(540013, 19851, '18', 'C', 171.6, 18, NULL, NULL),
(540014, 19851, '19', 'CH3', 16.2, 19, NULL, NULL),
(540015, 19851, '20', 'C', 80.4, 20, NULL, NULL),
(540016, 19851, '21', 'CH3', 21.7, 21, NULL, NULL),
(540017, 19851, '22', 'CH', 76.5, 22, NULL, NULL),
(540018, 19851, '23', 'CH2', 31.2, 23, NULL, NULL),
(540019, 19851, '24', 'C', 30.7, 24, NULL, NULL),
(540020, 19851, '25', 'CH', 49.3, 25, NULL, NULL),
(540021, 19851, '26', 'C', 167.3, 26, NULL, NULL),
(540022, 19851, '27', 'CH2', 61.4, 27, NULL, NULL),
(540023, 19851, '28', 'CH3', 24.4, 28, NULL, NULL),
(540024, 19852, '1', 'C', 216.1, 1, NULL, NULL),
(540025, 19852, '2', 'CH2', 44.5, 2, NULL, NULL),
(540026, 19852, '3', 'CH', 69.7, 3, NULL, NULL),
(540027, 19852, '4', 'CH', 125.4, 4, NULL, NULL),
(540028, 19852, '5', 'C', 143.2, 5, NULL, NULL),
(540029, 19852, '6', 'CH', 127.8, 6, NULL, NULL),
(540030, 19852, '7', 'CH', 127.3, 7, NULL, NULL),
(540031, 19852, '8', 'CH', 44.2, 8, NULL, NULL),
(540032, 19852, '9', 'CH', 32.3, 9, NULL, NULL),
(540033, 19852, '10', 'C', 51.6, 10, NULL, NULL),
(540034, 19852, '11', 'CH2', 25.3, 11, NULL, NULL),
(540035, 19852, '12', 'CH2', 25.8, 12, NULL, NULL),
(540036, 19852, '13', 'C', 80, 13, NULL, NULL),
(540037, 19852, '14', 'C', 106.3, 14, NULL, NULL),
(540038, 19852, '15', 'C', 207.8, 15, NULL, NULL),
(540039, 19852, '16', 'CH', 55.6, 16, NULL, NULL),
(540040, 19852, '17', 'C', 81, 17, NULL, NULL),
(540041, 19852, '18', 'C', 171.9, 18, NULL, NULL),
(540042, 19852, '19', 'CH3', 19.3, 19, NULL, NULL),
(540043, 19852, '20', 'C', 80.7, 20, NULL, NULL),
(540044, 19852, '21', 'CH3', 21.5, 21, NULL, NULL),
(540045, 19852, '22', 'CH', 77, 22, NULL, NULL),
(540046, 19852, '23', 'CH2', 32.9, 23, NULL, NULL),
(540047, 19852, '24', 'C', 31.2, 24, NULL, NULL),
(540048, 19852, '25', 'CH', 50.9, 25, NULL, NULL),
(540049, 19852, '26', 'C', 166.5, 26, NULL, NULL),
(540050, 19852, '27', 'CH2', 61.2, 27, NULL, NULL),
(540051, 19852, '28', 'CH3', 26.5, 28, NULL, NULL),
(540052, 19853, '1', 'C', 211.3, 1, NULL, NULL),
(540053, 19853, '2', 'CH2', 46.6, 2, NULL, NULL),
(540054, 19853, '3', 'CH', 66.1, 3, NULL, NULL),
(540055, 19853, '4', 'CH', 126.5, 4, NULL, NULL),
(540056, 19853, '5', 'C', 142.5, 5, NULL, NULL),
(540057, 19853, '6', 'CH', 129.1, 6, NULL, NULL),
(540058, 19853, '7', 'CH', 125.7, 7, NULL, NULL),
(540059, 19853, '8', 'CH', 45, 8, NULL, NULL),
(540060, 19853, '9', 'CH', 33.3, 9, NULL, NULL),
(540061, 19853, '10', 'C', 50.2, 10, NULL, NULL),
(540062, 19853, '11', 'CH2', 22.3, 11, NULL, NULL),
(540063, 19853, '12', 'CH2', 24.7, 12, NULL, NULL),
(540064, 19853, '13', 'C', 78.8, 13, NULL, NULL),
(540065, 19853, '14', 'C', 105.8, 14, NULL, NULL),
(540066, 19853, '15', 'C', 208.7, 15, NULL, NULL),
(540067, 19853, '16', 'CH', 53.6, 16, NULL, NULL),
(540068, 19853, '17', 'C', 81, 17, NULL, NULL),
(540069, 19853, '18', 'C', 171.6, 18, NULL, NULL),
(540070, 19853, '19', 'CH3', 17.8, 19, NULL, NULL),
(540071, 19853, '20', 'C', 80.4, 20, NULL, NULL),
(540072, 19853, '21', 'CH3', 21.7, 21, NULL, NULL),
(540073, 19853, '22', 'CH', 76.5, 22, NULL, NULL),
(540074, 19853, '23', 'CH2', 31.3, 23, NULL, NULL),
(540075, 19853, '24', 'C', 30.7, 24, NULL, NULL),
(540076, 19853, '25', 'CH', 49.3, 25, NULL, NULL),
(540077, 19853, '26', 'C', 167.3, 26, NULL, NULL),
(540078, 19853, '27', 'CH2', 61.4, 27, NULL, NULL),
(540079, 19853, '28', 'CH3', 24.5, 28, NULL, NULL),
(540080, 19854, '1', 'C', 213.1, 1, NULL, NULL),
(540081, 19854, '2', 'CH2', 44.8, 2, NULL, NULL),
(540082, 19854, '3', 'CH', 69.6, 3, NULL, NULL),
(540083, 19854, '4', 'CH', 126.3, 4, NULL, NULL),
(540084, 19854, '5', 'C', 141.5, 5, NULL, NULL),
(540085, 19854, '6', 'CH', 127.9, 6, NULL, NULL),
(540086, 19854, '7', 'CH', 126.6, 7, NULL, NULL),
(540087, 19854, '8', 'CH', 44.3, 8, NULL, NULL),
(540088, 19854, '9', 'CH', 32.1, 9, NULL, NULL),
(540089, 19854, '10', 'C', 51.3, 10, NULL, NULL),
(540090, 19854, '11', 'CH2', 25.3, 11, NULL, NULL),
(540091, 19854, '12', 'CH2', 25.8, 12, NULL, NULL),
(540092, 19854, '13', 'C', 80, 13, NULL, NULL),
(540093, 19854, '14', 'C', 106.4, 14, NULL, NULL),
(540094, 19854, '15', 'C', 207.8, 15, NULL, NULL),
(540095, 19854, '16', 'CH', 55.6, 16, NULL, NULL),
(540096, 19854, '17', 'C', 81, 17, NULL, NULL),
(540097, 19854, '18', 'C', 172, 18, NULL, NULL),
(540098, 19854, '19', 'CH3', 20.9, 19, NULL, NULL),
(540099, 19854, '20', 'C', 80.6, 20, NULL, NULL),
(540100, 19854, '21', 'CH3', 21.5, 21, NULL, NULL),
(540101, 19854, '22', 'CH', 77, 22, NULL, NULL),
(540102, 19854, '23', 'CH2', 32.9, 23, NULL, NULL),
(540103, 19854, '24', 'C', 31.2, 24, NULL, NULL),
(540104, 19854, '25', 'CH', 50.8, 25, NULL, NULL),
(540105, 19854, '26', 'C', 166.5, 26, NULL, NULL),
(540106, 19854, '27', 'CH2', 61.2, 27, NULL, NULL),
(540107, 19854, '28', 'CH3', 26.5, 28, NULL, NULL),
(540108, 19855, '1', 'C', 211.5, 1, NULL, NULL),
(540109, 19855, '2', 'CH2', 46.9, 2, NULL, NULL),
(540110, 19855, '3', 'CH', 66.6, 3, NULL, NULL),
(540111, 19855, '4', 'CH', 127.7, 4, NULL, NULL),
(540112, 19855, '5', 'C', 139.6, 5, NULL, NULL),
(540113, 19855, '6', 'CH', 126.8, 6, NULL, NULL),
(540114, 19855, '7', 'CH', 127.7, 7, NULL, NULL),
(540115, 19855, '8', 'CH', 47.9, 8, NULL, NULL),
(540116, 19855, '9', 'CH', 36.7, 9, NULL, NULL),
(540117, 19855, '10', 'C', 50.7, 10, NULL, NULL),
(540118, 19855, '11', 'CH2', 21.5, 11, NULL, NULL),
(540119, 19855, '12', 'CH2', 28.7, 12, NULL, NULL),
(540120, 19855, '13', 'C', 78.4, 13, NULL, NULL),
(540121, 19855, '14', 'C', 81.4, 14, NULL, NULL),
(540122, 19855, '15', 'C', 171.1, 15, NULL, NULL),
(540123, 19855, '16', 'CH', 47.4, 16, NULL, NULL),
(540124, 19855, '17', 'C', 82.8, 17, NULL, NULL),
(540125, 19855, '18', 'C', 173, 18, NULL, NULL),
(540126, 19855, '19', 'CH3', 17.7, 19, NULL, NULL),
(540127, 19855, '20', 'C', 82.5, 20, NULL, NULL),
(540128, 19855, '21', 'CH3', 21.5, 21, NULL, NULL),
(540129, 19855, '22', 'CH', 76.1, 22, NULL, NULL),
(540130, 19855, '23', 'CH2', 29.8, 23, NULL, NULL),
(540131, 19855, '24', 'C', 28.4, 24, NULL, NULL),
(540132, 19855, '25', 'CH', 40.4, 25, NULL, NULL),
(540133, 19855, '26', 'C', 170.7, 26, NULL, NULL),
(540134, 19855, '27', 'CH2', 60.7, 27, NULL, NULL),
(540135, 19855, '28', 'CH3', 29.6, 28, NULL, NULL),
(540136, 19856, '1', 'C', 210.2, 1, NULL, NULL),
(540137, 19856, '2', 'CH2', 45.8, 2, NULL, NULL),
(540138, 19856, '3', 'CH', 66.5, 3, NULL, NULL),
(540139, 19856, '4', 'CH', 125.1, 4, NULL, NULL),
(540140, 19856, '5', 'C', 141, 5, NULL, NULL),
(540141, 19856, '6', 'CH', 126.7, 6, NULL, NULL),
(540142, 19856, '7', 'CH', 127.7, 7, NULL, NULL),
(540143, 19856, '8', 'CH', 47.4, 8, NULL, NULL),
(540144, 19856, '9', 'CH', 36, 9, NULL, NULL),
(540145, 19856, '10', 'C', 50.9, 10, NULL, NULL),
(540146, 19856, '11', 'CH2', 21.6, 11, NULL, NULL),
(540147, 19856, '12', 'CH2', 28.1, 12, NULL, NULL),
(540148, 19856, '13', 'C', 78.4, 13, NULL, NULL),
(540149, 19856, '14', 'C', 81.5, 14, NULL, NULL),
(540150, 19856, '15', 'C', 171.2, 15, NULL, NULL),
(540151, 19856, '16', 'CH', 47.6, 16, NULL, NULL),
(540152, 19856, '17', 'C', 82.9, 17, NULL, NULL),
(540153, 19856, '18', 'C', 172.9, 18, NULL, NULL),
(540154, 19856, '19', 'CH3', 19.2, 19, NULL, NULL),
(540155, 19856, '20', 'C', 82.3, 20, NULL, NULL),
(540156, 19856, '21', 'CH3', 21.5, 21, NULL, NULL),
(540157, 19856, '22', 'CH', 76.2, 22, NULL, NULL),
(540158, 19856, '23', 'CH2', 29.8, 23, NULL, NULL),
(540159, 19856, '24', 'C', 28, 24, NULL, NULL),
(540160, 19856, '25', 'CH', 40.1, 25, NULL, NULL),
(540161, 19856, '26', 'C', 170.7, 26, NULL, NULL),
(540162, 19856, '27', 'CH2', 60.7, 27, NULL, NULL),
(540163, 19856, '28', 'CH3', 29.6, 28, NULL, NULL),
(540164, 19857, '1', 'C', 212.1, 1, NULL, NULL),
(540165, 19857, '2', 'CH2', 45, 2, NULL, NULL),
(540166, 19857, '3', 'CH', 69.6, 3, NULL, NULL),
(540167, 19857, '4', 'CH', 125.7, 4, NULL, NULL),
(540168, 19857, '5', 'C', 139.6, 5, NULL, NULL),
(540169, 19857, '6', 'CH', 127.3, 6, NULL, NULL),
(540170, 19857, '7', 'CH', 127.3, 7, NULL, NULL),
(540171, 19857, '8', 'CH', 51.2, 8, NULL, NULL),
(540172, 19857, '9', 'CH', 32.7, 9, NULL, NULL),
(540173, 19857, '10', 'C', 50.4, 10, NULL, NULL),
(540174, 19857, '11', 'CH2', 28, 11, NULL, NULL),
(540175, 19857, '12', 'CH2', 31.6, 12, NULL, NULL),
(540176, 19857, '13', 'C', 80.7, 13, NULL, NULL),
(540177, 19857, '14', 'C', 82.3, 14, NULL, NULL),
(540178, 19857, '15', 'C', 169.3, 15, NULL, NULL),
(540179, 19857, '16', 'CH', 47.7, 16, NULL, NULL),
(540180, 19857, '17', 'C', 83.8, 17, NULL, NULL),
(540181, 19857, '18', 'C', 173, 18, NULL, NULL),
(540182, 19857, '19', 'CH3', 21.9, 19, NULL, NULL),
(540183, 19857, '20', 'C', 82.1, 20, NULL, NULL),
(540184, 19857, '21', 'CH3', 22.1, 21, NULL, NULL),
(540185, 19857, '22', 'CH', 75.8, 22, NULL, NULL),
(540186, 19857, '23', 'CH2', 32.7, 23, NULL, NULL),
(540187, 19857, '24', 'C', 31.6, 24, NULL, NULL),
(540188, 19857, '25', 'CH', 41.8, 25, NULL, NULL),
(540189, 19857, '26', 'C', 169.1, 26, NULL, NULL),
(540190, 19857, '27', 'CH2', 61.1, 27, NULL, NULL),
(540191, 19857, '28', 'CH3', 31.7, 28, NULL, NULL),
(540192, 19858, '1', 'C', 210.6, 1, NULL, NULL),
(540193, 19858, '2', 'CH2', 42.5, 2, NULL, NULL),
(540194, 19858, '3', 'CH', 75.5, 3, NULL, NULL),
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