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(269715, 8459, '17', 'CH3', 17.3, 17, NULL, NULL),
(269716, 8459, '18', 'CH3', 24.6, 18, NULL, NULL),
(269717, 8459, '19', 'CH3', 25.5, 19, NULL, NULL),
(269718, 8459, '20', 'C', 177, 20, NULL, NULL),
(269719, 8459, '16a', 'CH3', 51.4, 16001, NULL, NULL),
(269720, 8459, '20a', 'CH3', 51.5, 20001, NULL, NULL),
(269721, 8460, '1', 'C', 54.6, 1, NULL, NULL),
(269722, 8460, '2', 'CH', 41.6, 2, NULL, NULL),
(269723, 8460, '3', 'CH2', 35.9, 3, NULL, NULL),
(269724, 8460, '4', 'CH2', 23.3, 4, NULL, NULL),
(269725, 8460, '5', 'CH', 60.6, 5, NULL, NULL),
(269726, 8460, '6', 'C', 51.5, 6, NULL, NULL),
(269727, 8460, '7', 'CH', 48.2, 7, NULL, NULL),
(269728, 8460, '8', 'C', 141, 8, NULL, NULL),
(269729, 8460, '9', 'CH', 120.4, 9, NULL, NULL),
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(269733, 8460, '13', 'CH2', 22.9, 13, NULL, NULL),
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(269735, 8460, '15', 'CH', 28.1, 15, NULL, NULL),
(269736, 8460, '16', 'CH3', 22.8, 16, NULL, NULL),
(269737, 8460, '17', 'CH3', 22.8, 17, NULL, NULL),
(269738, 8460, '18', 'CH3', 24.4, 18, NULL, NULL),
(269739, 8460, '19', 'CH3', 24.6, 19, NULL, NULL),
(269740, 8460, '20', 'CH3', 13.8, 20, NULL, NULL),
(269741, 8461, '1', 'C', 67.8, 1, NULL, NULL),
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(269744, 8461, '4', 'CH2', 23.9, 4, NULL, NULL),
(269745, 8461, '5', 'CH', 56.8, 5, NULL, NULL),
(269746, 8461, '6', 'C', 46.9, 6, NULL, NULL),
(269747, 8461, '7', 'CH', 51.8, 7, NULL, NULL),
(269748, 8461, '8', 'C', 167.4, 8, NULL, NULL),
(269749, 8461, '9', 'CH', 125.1, 9, NULL, NULL),
(269750, 8461, '10', 'C', 204, 10, NULL, NULL),
(269751, 8461, '11', 'CH2', 37.2, 11, NULL, NULL),
(269752, 8461, '12', 'CH2', 34.9, 12, NULL, NULL),
(269753, 8461, '13', 'CH2', 23, 13, NULL, NULL),
(269754, 8461, '14', 'CH2', 40.1, 14, NULL, NULL),
(269755, 8461, '15', 'CH', 28.1, 15, NULL, NULL),
(269756, 8461, '16', 'CH3', 22.7, 16, NULL, NULL),
(269757, 8461, '17', 'CH3', 22.7, 17, NULL, NULL),
(269758, 8461, '18', 'CH3', 25.1, 18, NULL, NULL),
(269759, 8461, '19', 'CH3', 25.5, 19, NULL, NULL),
(269760, 8461, '20', 'CH3', 14.4, 20, NULL, NULL),
(269761, 8462, '1', 'CH', 72.8, 1, NULL, NULL),
(269762, 8462, '2', 'CH2', 22.6, 2, NULL, NULL),
(269763, 8462, '3', 'CH2', 34.9, 3, NULL, NULL),
(269764, 8462, '4', 'C', 33, 4, NULL, NULL),
(269765, 8462, '5', 'CH', 47.3, 5, NULL, NULL),
(269766, 8462, '6', 'CH2', 24.3, 6, NULL, NULL),
(269767, 8462, '7', 'CH', 73.8, 7, NULL, NULL),
(269768, 8462, '8', 'C', 60.9, 8, NULL, NULL),
(269769, 8462, '9', 'CH', 48.5, 9, NULL, NULL),
(269770, 8462, '10', 'C', 43, 10, NULL, NULL),
(269771, 8462, '11', 'CH2', 16.5, 11, NULL, NULL),
(269772, 8462, '12', 'CH2', 32.5, 12, NULL, NULL),
(269773, 8462, '13', 'CH', 44.2, 13, NULL, NULL),
(269774, 8462, '14', 'CH', 74.9, 14, NULL, NULL),
(269775, 8462, '15', 'C', 204.2, 15, NULL, NULL),
(269776, 8462, '16', 'C', 145.6, 16, NULL, NULL),
(269777, 8462, '17', 'CH2', 117.8, 17, NULL, NULL),
(269778, 8462, '18', 'CH3', 33.1, 18, NULL, NULL),
(269779, 8462, '19', 'CH3', 21.2, 19, NULL, NULL),
(269780, 8462, '20', 'CH3', 18.6, 20, NULL, NULL),
(269781, 8462, '1a', 'C', 169.6, 1001, NULL, NULL),
(269782, 8462, '1b', 'CH3', 21.4, 1002, NULL, NULL),
(269783, 8462, '7a', 'C', 170.3, 7001, NULL, NULL),
(269784, 8462, '7b', 'CH3', 21.4, 7002, NULL, NULL),
(269785, 8462, '14a', 'C', 170.8, 14001, NULL, NULL),
(269786, 8462, '14b', 'CH3', 21.4, 14002, NULL, NULL),
(269787, 8463, '1', 'CH2', 39.3, 1, NULL, NULL),
(269788, 8463, '2', 'CH2', 18.6, 2, NULL, NULL),
(269789, 8463, '3', 'CH2', 37.5, 3, NULL, NULL),
(269790, 8463, '4', 'C', 43.6, 4, NULL, NULL),
(269791, 8463, '5', 'CH', 55.9, 5, NULL, NULL),
(269792, 8463, '6', 'CH2', 19.9, 6, NULL, NULL),
(269793, 8463, '7', 'CH2', 33.1, 7, NULL, NULL),
(269794, 8463, '8', 'C', 50.1, 8, NULL, NULL),
(269795, 8463, '9', 'CH', 62.6, 9, NULL, NULL),
(269796, 8463, '10', 'C', 38.6, 10, NULL, NULL),
(269797, 8463, '11', 'CH', 65.2, 11, NULL, NULL),
(269798, 8463, '12', 'CH2', 34.4, 12, NULL, NULL),
(269799, 8463, '13', 'CH', 34.7, 13, NULL, NULL),
(269800, 8463, '14', 'CH2', 37.1, 14, NULL, NULL),
(269801, 8463, '15', 'C', 223, 15, NULL, NULL),
(269802, 8463, '16', 'CH', 49.6, 16, NULL, NULL),
(269803, 8463, '17', 'CH3', 11.1, 17, NULL, NULL),
(269804, 8463, '18', 'CH3', 28.8, 18, NULL, NULL),
(269805, 8463, '19', 'C', 183.4, 19, NULL, NULL),
(269806, 8463, '20', 'CH3', 15.6, 20, NULL, NULL),
(269807, 8464, '1', 'CH2', 39.6, 1, NULL, NULL),
(269808, 8464, '2', 'CH2', 18.7, 2, NULL, NULL),
(269809, 8464, '3', 'CH2', 37.6, 3, NULL, NULL),
(269810, 8464, '4', 'C', 43.6, 4, NULL, NULL),
(269811, 8464, '5', 'CH', 55.9, 5, NULL, NULL),
(269812, 8464, '6', 'CH2', 20.1, 6, NULL, NULL),
(269813, 8464, '7', 'CH2', 33.9, 7, NULL, NULL),
(269814, 8464, '8', 'C', 53.4, 8, NULL, NULL),
(269815, 8464, '9', 'CH', 51.5, 9, NULL, NULL),
(269816, 8464, '10', 'C', 39.9, 10, NULL, NULL),
(269817, 8464, '11', 'CH2', 18.5, 11, NULL, NULL),
(269818, 8464, '12', 'CH2', 25.3, 12, NULL, NULL),
(269819, 8464, '13', 'CH', 32.9, 13, NULL, NULL),
(269820, 8464, '14', 'CH2', 37.4, 14, NULL, NULL),
(269821, 8464, '15', 'C', 225.6, 15, NULL, NULL),
(269822, 8464, '16', 'CH', 54.6, 16, NULL, NULL),
(269823, 8464, '17', 'CH2', 60.6, 17, NULL, NULL),
(269824, 8464, '18', 'CH3', 28.9, 18, NULL, NULL),
(269825, 8464, '19', 'C', 183.1, 19, NULL, NULL),
(269826, 8464, '20', 'CH3', 15.5, 20, NULL, NULL),
(269827, 8465, '1', 'CH2', 70.3, 1, NULL, NULL),
(269828, 8465, '2', 'CH', 120.4, 2, NULL, NULL),
(269829, 8465, '3', 'C', 142.4, 3, NULL, NULL),
(269830, 8465, '4', 'CH2', 35.6, 4, NULL, NULL),
(269831, 8465, '5', 'CH2', 28.8, 5, NULL, NULL),
(269832, 8465, '6', 'CH', 89.1, 6, NULL, NULL),
(269833, 8465, '7', 'C', 144.1, 7, NULL, NULL),
(269834, 8465, '8', 'CH2', 114.6, 8, NULL, NULL),
(269835, 8465, '9', 'CH3', 17.3, 9, NULL, NULL),
(269836, 8465, '10', 'CH3', 16.7, 10, NULL, NULL),
(269837, 8465, '2''', 'C', 160.8, 102, NULL, NULL),
(269838, 8465, '3''', 'CH', 115, 103, NULL, NULL),
(269839, 8465, '4''', 'CH', 144.6, 104, NULL, NULL),
(269840, 8465, '5''', 'CH', 113.2, 105, NULL, NULL),
(269841, 8465, '6''', 'C', 126.1, 106, NULL, NULL),
(269842, 8465, '7''', 'C', 148.9, 107, NULL, NULL),
(269843, 8465, '8''', 'C', 131.6, 108, NULL, NULL),
(269844, 8465, '9''', 'C', 143.7, 109, NULL, NULL),
(269845, 8465, '10''', 'C', 116.7, 110, NULL, NULL),
(269846, 8465, '11''', 'CH', 107, 111, NULL, NULL),
(269847, 8465, '12''', 'CH', 146.9, 112, NULL, NULL),
(269848, 8466, '1', 'CH2', 28.6, 1, NULL, NULL),
(269849, 8466, '2', 'CH', 121.7, 2, NULL, NULL),
(269850, 8466, '3', 'C', 137.9, 3, NULL, NULL),
(269851, 8466, '4', 'CH2', 35.8, 4, NULL, NULL),
(269852, 8466, '5', 'CH2', 32.9, 5, NULL, NULL),
(269853, 8466, '6', 'CH', 75.9, 6, NULL, NULL),
(269854, 8466, '7', 'C', 147.1, 7, NULL, NULL),
(269855, 8466, '8', 'CH2', 111.3, 8, NULL, NULL),
(269856, 8466, '9', 'CH3', 16.7, 9, NULL, NULL),
(269857, 8466, '10', 'CH3', 16.2, 10, NULL, NULL),
(269858, 8466, '2''', 'C', 162.2, 102, NULL, NULL),
(269859, 8466, '3''', 'CH', 112.3, 103, NULL, NULL),
(269860, 8466, '4''', 'CH', 144.1, 104, NULL, NULL),
(269861, 8466, '5''', 'CH', 128.4, 105, NULL, NULL),
(269862, 8466, '6''', 'C', 125.6, 106, NULL, NULL),
(269863, 8466, '7''', 'C', 158.5, 107, NULL, NULL),
(269864, 8466, '8''', 'CH', 103.1, 108, NULL, NULL),
(269865, 8466, '9''', 'C', 154.2, 109, NULL, NULL),
(269866, 8466, '10''', 'C', 112.2, 110, NULL, NULL),
(269867, 8467, '1', 'CH2', 36.2, 1, NULL, NULL),
(269868, 8467, '2', 'CH2', 29.1, 2, NULL, NULL),
(269869, 8467, '3', 'CH', 79.9, 3, NULL, NULL),
(269870, 8467, '4', 'C', 40.8, 4, NULL, NULL),
(269871, 8467, '5', 'CH', 54.7, 5, NULL, NULL),
(269872, 8467, '6', 'CH2', 20.4, 6, NULL, NULL),
(269873, 8467, '7', 'CH2', 34.3, 7, NULL, NULL),
(269874, 8467, '8', 'C', 135.4, 8, NULL, NULL),
(269875, 8467, '9', 'C', 134.8, 9, NULL, NULL),
(269876, 8467, '10', 'C', 40.8, 10, NULL, NULL),
(269877, 8467, '11', 'C', 149.4, 11, NULL, NULL),
(269878, 8467, '12', 'C', 143.4, 12, NULL, NULL),
(269879, 8467, '13', 'C', 136.7, 13, NULL, NULL),
(269880, 8467, '14', 'CH', 118.5, 14, NULL, NULL),
(269881, 8467, '15', 'CH', 35.1, 15, NULL, NULL),
(269882, 8467, '16', 'CH3', 18.6, 16, NULL, NULL),
(269883, 8467, '17', 'CH2', 69.4, 17, NULL, NULL),
(269884, 8467, '18', 'CH3', 29.5, 18, NULL, NULL),
(269885, 8467, '19', 'CH3', 17, 19, NULL, NULL),
(269886, 8467, '20', 'CH3', 20.1, 20, NULL, NULL),
(269887, 8467, '1''', 'CH', 108, 101, NULL, NULL),
(269888, 8467, '2''', 'CH', 75.9, 102, NULL, NULL),
(269889, 8467, '3''', 'CH', 79.2, 103, NULL, NULL),
(269890, 8467, '4''', 'CH', 71.8, 104, NULL, NULL),
(269891, 8467, '5''', 'CH', 78.2, 105, NULL, NULL),
(269892, 8467, '6''', 'CH2', 63.2, 106, NULL, NULL),
(269893, 8468, '1', 'CH2', 26, 1, NULL, NULL),
(269894, 8468, '2', 'CH2', 27.8, 2, NULL, NULL),
(269895, 8468, '3', 'C', 132.7, 3, NULL, NULL),
(269896, 8468, '4', 'CH', 119.4, 4, NULL, NULL),
(269897, 8468, '5', 'CH2', 30.2, 5, NULL, NULL),
(269898, 8468, '6', 'C', 46.9, 6, NULL, NULL),
(269899, 8468, '7', 'C', 141, 7, NULL, NULL),
(269900, 8468, '8', 'CH2', 36.7, 8, NULL, NULL),
(269901, 8468, '9', 'CH', 74, 9, NULL, NULL),
(269902, 8468, '10', 'CH', 64, 10, NULL, NULL),
(269903, 8468, '11', 'C', 43.5, 11, NULL, NULL),
(269904, 8468, '12', 'CH3', 20.1, 12, NULL, NULL),
(269905, 8468, '13', 'CH3', 24.3, 13, NULL, NULL),
(269906, 8468, '14', 'CH2', 115.7, 14, NULL, NULL),
(269907, 8468, '15', 'CH3', 23.1, 15, NULL, NULL),
(269908, 8468, '9a', 'C', 170.2, 9001, NULL, NULL),
(269909, 8468, '9b', 'CH3', 21, 9002, NULL, NULL),
(269910, 8469, '1', 'CH2', 37.7, 1, NULL, NULL),
(269911, 8469, '2', 'CH2', 19.2, 2, NULL, NULL),
(269912, 8469, '3', 'CH2', 37.5, 3, NULL, NULL),
(269913, 8469, '4', 'C', 42.9, 4, NULL, NULL),
(269914, 8469, '5', 'CH', 51.7, 5, NULL, NULL),
(269915, 8469, '6', 'CH', 134.4, 6, NULL, NULL),
(269916, 8469, '7', 'CH', 122.7, 7, NULL, NULL),
(269917, 8469, '8', 'C', 84.2, 8, NULL, NULL),
(269918, 8469, '9', 'CH', 49.7, 9, NULL, NULL),
(269919, 8469, '10', 'C', 36.5, 10, NULL, NULL),
(269920, 8469, '11', 'CH2', 31.7, 11, NULL, NULL),
(269921, 8469, '12', 'C', 176.4, 12, NULL, NULL),
(269922, 8469, '13', 'CH2', 69, 13, NULL, NULL);
INSERT INTO `carbons` (`id`, `molecularId`, `numeration`, `carbonType`, `shift`, `num2`, `created_at`, `updated_at`) VALUES
(269923, 8469, '14', 'CH3', 28, 14, NULL, NULL),
(269924, 8469, '15', 'C', 177.9, 15, NULL, NULL),
(269925, 8469, '16', 'CH3', 12.1, 16, NULL, NULL),
(269926, 8470, '1', 'CH2', 30.1, 1, NULL, NULL),
(269927, 8470, '2', 'CH2', 19.4, 2, NULL, NULL),
(269928, 8470, '3', 'CH2', 38.3, 3, NULL, NULL),
(269929, 8470, '4', 'C', 43.9, 4, NULL, NULL),
(269930, 8470, '5', 'CH', 43.2, 5, NULL, NULL),
(269931, 8470, '6', 'CH2', 24.6, 6, NULL, NULL),
(269932, 8470, '7', 'CH', 126.2, 7, NULL, NULL),
(269933, 8470, '8', 'C', 130.9, 8, NULL, NULL),
(269934, 8470, '9', 'C', 72.9, 9, NULL, NULL),
(269935, 8470, '10', 'C', 40.3, 10, NULL, NULL),
(269936, 8470, '11', 'CH2', 37.3, 11, NULL, NULL),
(269937, 8470, '12', 'C', 174.7, 12, NULL, NULL),
(269938, 8470, '13', 'CH2', 69.8, 13, NULL, NULL),
(269939, 8470, '14', 'CH3', 28.2, 14, NULL, NULL),
(269940, 8470, '15', 'C', 180.2, 15, NULL, NULL),
(269941, 8470, '16', 'CH3', 15.1, 16, NULL, NULL),
(269942, 8471, '1', 'CH', 73.6, 1, NULL, NULL),
(269943, 8471, '2', 'CH', 61.9, 2, NULL, NULL),
(269944, 8471, '3', 'CH2', 36.1, 3, NULL, NULL),
(269945, 8471, '4', 'C', 45, 4, NULL, NULL),
(269946, 8471, '5', 'C', 91, 5, NULL, NULL),
(269947, 8471, '6', 'CH', 100.6, 6, NULL, NULL),
(269948, 8471, '7', 'C', 172.9, 7, NULL, NULL),
(269949, 8471, '8', 'CH', 48.8, 8, NULL, NULL),
(269950, 8471, '9', 'C', 71.7, 9, NULL, NULL),
(269951, 8471, '10', 'C', 40.4, 10, NULL, NULL),
(269952, 8471, '11', 'CH2', 41.4, 11, NULL, NULL),
(269953, 8471, '12', 'C', 108.4, 12, NULL, NULL),
(269954, 8471, '13', 'CH', 125.9, 13, NULL, NULL),
(269955, 8471, '14', 'CH', 109.5, 14, NULL, NULL),
(269956, 8471, '15', 'CH', 144.8, 15, NULL, NULL),
(269957, 8471, '16', 'C', 142.6, 16, NULL, NULL),
(269958, 8471, '17', 'CH3', 15.6, 17, NULL, NULL),
(269959, 8471, '18', 'CH3', 18.4, 18, NULL, NULL),
(269960, 8471, '19', 'C', 177.4, 19, NULL, NULL),
(269961, 8471, '20', 'CH3', 17.5, 20, NULL, NULL),
(269962, 8472, '1', 'CH2', 31.7, 1, NULL, NULL),
(269963, 8472, '2', 'CH', 29.6, 2, NULL, NULL),
(269964, 8472, '3', 'CH', 76.7, 3, NULL, NULL),
(269965, 8472, '4', 'C', 73.4, 4, NULL, NULL),
(269966, 8472, '5', 'CH', 116.5, 5, NULL, NULL),
(269967, 8472, '6', 'C', 140.2, 6, NULL, NULL),
(269968, 8472, '7', 'CH', 76.4, 7, NULL, NULL),
(269969, 8472, '8', 'CH', 71.3, 8, NULL, NULL),
(269970, 8472, '9', 'CH', 24.9, 9, NULL, NULL),
(269971, 8472, '10', 'C', 25.3, 10, NULL, NULL),
(269972, 8472, '11', 'CH', 31.1, 11, NULL, NULL),
(269973, 8472, '12', 'CH', 70.5, 12, NULL, NULL),
(269974, 8472, '13', 'CH', 43.6, 13, NULL, NULL),
(269975, 8472, '14', 'C', 207.2, 14, NULL, NULL),
(269976, 8472, '15', 'C', 71.2, 15, NULL, NULL),
(269977, 8472, '16', 'CH3', 17, 16, NULL, NULL),
(269978, 8472, '17', 'CH3', 17.4, 17, NULL, NULL),
(269979, 8472, '18', 'CH3', 24.5, 18, NULL, NULL),
(269980, 8472, '19', 'CH2', 62.6, 19, NULL, NULL),
(269981, 8472, '20', 'CH3', 13.3, 20, NULL, NULL),
(269982, 8472, '3a', 'C', 172.2, 3001, NULL, NULL),
(269983, 8472, '3b', 'CH3', 21.2, 3002, NULL, NULL),
(269984, 8472, '7a', 'C', 166.8, 7001, NULL, NULL),
(269985, 8472, '7b', 'C', 138.5, 7002, NULL, NULL),
(269986, 8472, '7c', 'CH', 128.4, 7003, NULL, NULL),
(269987, 8472, '7d', 'CH3', 14.6, 7004, NULL, NULL),
(269988, 8472, '7ba', 'CH3', 12.2, 7201, NULL, NULL),
(269989, 8472, '8a', 'C', 166.4, 8001, NULL, NULL),
(269990, 8472, '8b', 'C', 138, 8002, NULL, NULL),
(269991, 8472, '8c', 'CH', 128.1, 8003, NULL, NULL),
(269992, 8472, '8d', 'CH3', 14.5, 8004, NULL, NULL),
(269993, 8472, '8ba', 'CH3', 12, 8201, NULL, NULL),
(269994, 8472, '12a', 'C', 170.6, 12001, NULL, NULL),
(269995, 8472, '12b', 'CH3', 20.6, 12002, NULL, NULL),
(269996, 8473, '1', 'CH2', 31.7, 1, NULL, NULL),
(269997, 8473, '2', 'CH', 29.7, 2, NULL, NULL),
(269998, 8473, '3', 'CH', 77.6, 3, NULL, NULL),
(269999, 8473, '4', 'C', 73.7, 4, NULL, NULL),
(270000, 8473, '5', 'CH', 116.5, 5, NULL, NULL),
(270001, 8473, '6', 'C', 141.5, 6, NULL, NULL),
(270002, 8473, '7', 'CH', 76, 7, NULL, NULL),
(270003, 8473, '8', 'CH', 73.6, 8, NULL, NULL),
(270004, 8473, '9', 'CH', 23.8, 9, NULL, NULL),
(270005, 8473, '10', 'C', 22, 10, NULL, NULL),
(270006, 8473, '11', 'CH', 31.2, 11, NULL, NULL),
(270007, 8473, '12', 'CH', 69.4, 12, NULL, NULL),
(270008, 8473, '13', 'CH', 43.5, 13, NULL, NULL),
(270009, 8473, '14', 'C', 207.4, 14, NULL, NULL),
(270010, 8473, '15', 'C', 71.5, 15, NULL, NULL),
(270011, 8473, '16', 'CH3', 17, 16, NULL, NULL),
(270012, 8473, '17', 'CH3', 17.4, 17, NULL, NULL),
(270013, 8473, '18', 'CH3', 24.4, 18, NULL, NULL),
(270014, 8473, '19', 'CH2', 64.9, 19, NULL, NULL),
(270015, 8473, '20', 'CH3', 13.4, 20, NULL, NULL),
(270016, 8473, '3a', 'C', 170.7, 3001, NULL, NULL),
(270017, 8473, '3b', 'CH3', 21.2, 3002, NULL, NULL),
(270018, 8473, '8a', 'C', 167.3, 8001, NULL, NULL),
(270019, 8473, '8b', 'C', 138.9, 8002, NULL, NULL),
(270020, 8473, '8c', 'CH', 128.2, 8003, NULL, NULL),
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